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1.
Yong Jiang Zhenbang Wei Wenzhou Sun Limeng Liu Zhenkun Huang 《Ceramics International》2021,47(6):7588-7592
Samples in Si–Al-R-O-N (R = Y, Gd, Yb) systems were prepared by solid-state reactions using R2O3, Al2O3, SiO2 and Si3N4 powders as starting materials. X-ray diffraction was done to investigate RAM-J(R) solid solutions [RAM = R4Al2O9, J(R) = R4Si2N2O7] formation and their equilibrium with RSO (R4Si2O10). Phase relations between RAM, J(R) and RSO at 1700 °C were summarized in a phase diagram. It was determined that a limited solid solution of RAM and RSO could be formed along RAM-RSO tie-line, while RAM and J(R) form a continuous solid solution along RAM-J(R) tie-line. In RAM-J(R)-RSO ternary systems, the RAM-J(R) tie-lines were extended towards the RSO corner to form a continuous solid solution area of JRAMss (R = Y, Gd, Yb). The established phase relations in the Si–Al-R-O-N (R = Y, Gd, Yb) systems may facilitate compositional selections for developing JRAMss as monolithic ceramics or for SiC/Si3N4 based composites using the solid-solutions as a second refractory phase. 相似文献
2.
针对移动机器人使用超声波传感器检测环境时存在干扰与数据不确定性问题,在分析超声波传感器工作原理和相邻位置检测数据的关联特性后,提出了基于三位置超声波检测的环境轮廓构建方法,利用超声波对室内环境进行建图;再使用改进强跟踪UKF-SLAM将超声波测量数据和移动机器人驱动模型进行滤波融合,得到更准确的位姿信息与地图特征。搭建仿真环境,并通过搭载有超声波传感器的全向轮移动机器人在实验环境内验证。仿真结果表明改进方法与其他算法相比,定位和地图构建的误差降低58.058%。室内实验中,获取环境特征的平均误差降低了50.286 3%,进一步验证了提出算法的可行性与有效性。该方法对机器人同步定位与地图构建有一定参考价值。 相似文献
3.
氢的安全、经济和高效储运是制约燃料电池-氢能推广应用的重大障碍.金属化合物固态储氢因理论质量储氢密度高、体积占比小、储氢压力低和安全性高,是以潜艇为代表的密闭空间场合用燃料电池的首选氢源,但热力学稳定和动力学释放氢缓慢等问题限制了其性能的发挥.碳材料因强结构设计性、独特的电子性质和高导热性,在金属化合物储氢中的研究日益广泛.基于此,从纳米结构约束、催化剂和添加剂三个角度,对金属化合物储氢中碳材料的应用进行了归纳,阐述了金属化合物/碳复合材料的制备和结构以及碳发挥有益效果的作用机制. 相似文献
4.
某飞机用30CrMnSiA钢沉头螺栓在拆卸过程中发生断裂,同炉批未曾使用的螺栓经磁粉检测也存在裂纹。为查找失效分析原因,通过对断裂件和同炉批开裂的螺栓外观检查、断口宏微观分析、能谱分析、硬度检测、金相分析等方法对断裂和开裂的螺栓进行了分析。结果表明:断裂螺栓和开裂螺栓断裂类型为氢脆,螺栓氢脆断裂主要与抗拉强度和热处理工艺有关,通过改善热处理工艺参数,适当降低螺栓的强度,增加酸洗后的除氢时间降低氢含量,从而避免氢脆发生的可能性。 相似文献
5.
Huahai Shen Menglu Li Pengcheng Li Haiyan Xiao Haibin Zhang Xiaotao Zu 《Journal of the American Ceramic Society》2021,104(5):2301-2312
In the past decades, pyrochlores, such as Gd2Zr2O7, have demonstrated great potential to immobilize nuclear wastes such as Pu, which results in the production of Pu2Zr2O7. Due to the high radioactivity of Pu, it is difficult to investigate the radiation response behavior of Pu2Zr2O7 and its physical properties of the damaged state experimentally. Consequently, few related data have been reported in the literature thus far. In this study, first-principles calculations have been carried out to investigate the defect formation and its effect on the thermodynamic properties of Pu2Zr2O7. It reveals that PuZr antisite and O8a interstitial defects are very easy to form in Pu2Zr2O7. In particular, the O8a interstitial defect can be formed spontaneously, while it is mechanically unstable. When vacancy, interstitial or antisite defects are formed in Pu2Zr2O7, and the elastic moduli and Debye temperature are decreased. Besides, better ductility is resulted. As compared with other zirconate pyrochlores, such as Gd2Zr2O7, the Pu2Zr2O7 is suggested to be less resistant to radiation-induced amorphization. This study demonstrates that the created defects due to self-radiation from actinide decay have remarkable influences on the thermophysical properties of Pu2Zr2O7. 相似文献
6.
Yuelong Ma Le Zhang Tianyuan Zhou Bingheng Sun Chen Hou Shunshun Yang Jin Huang Rui Wang Farida A. Selim Zhongying Wang Ming Li Hao Chen Yun Wang 《Journal of the European Ceramic Society》2021,41(4):2834-2846
Ce:Y3Al5O12 transparent ceramics (TCs) with appropriate emission light proportion and high thermal stability are significant to construct white light emitting diode devices with excellent chromaticity parameters. In this work, strategies of controlling crystal-field splitting around Ce3+ ion and doping orange-red emitting ion, were adopted to fabricate Ce:(Y,Tb)3(Al,Mn)5O12 TCs via vacuum sintering technique. Notably, 85.4 % of the room-temperature luminescence intensity of the TC was retained at 150 °C, and the color rendering index was as high as 79.8. Furthermore, a 12 nm red shift and a 16.2 % increase of full width at half maximum were achieved owing to the synergistic effects of Tb3+ and Mn2+ ions. By combining TCs with a 460 nm blue chip, a warm white light with a low correlated color temperature of 4155 K was acquired. Meanwhile, the action mechanism of Tb3+ ion and the energy transfer between Ce3+ and Mn2+ ions were verified in prepared TCs. 相似文献
7.
Ying Zhang Jian Chen Yixing Cai Qingfeng Zhang Yinmei Lu Haitao Huang Yunbin He 《Journal of the American Ceramic Society》2021,104(2):928-935
Traditional self-powered ultraviolet photodetectors, which are usually designed based on p-n junction interfacial effects, exhibit low responsivity and specific detectivity because the photogenerated electrons and holes cannot be separated effectively. Unlike wide band-gap semiconductor materials, ferroelectrics have large remnant polarization and thus high depolarization electric field throughout the whole bulk region, which can cause effective separation of photogenerated electrons and holes. Based on this, in this study, we prepare Pb0.93La0.07(Zr1-xTix)0.9825O3 (PLZT) ferroelectric thin films with large remnant polarization and self-powered ultraviolet photodetectors with Au/PLZT/FTO structure. The results indicate that the photoelectric response performances of the detectors improve as the remnant polarization of the PLZT thin film and positive poling voltage increase. By adjusting the Ti content, due to large remnant polarization of 47.4 μC/cm2 in the PLZT thin films with 80 mol% Ti, the corresponding photodetector exhibits the best self-powered ultraviolet photoelectric response with the high photo/dark current ratio of 2600, responsivity of 2.05 mA/W, specific detectivity of 5.45 × 1010 Jones, and fast response speed (rise time of 18 ms). These values are superior to those of recently reported self-powered ultraviolet photodetectors. 相似文献
8.
基于深度学习的视频超分辨率方法主要关注视频帧内和帧间的时空关系,但以往的方法在视频帧的特征对齐和融合方面存在运动信息估计不精确、特征融合不充分等问题。针对这些问题,采用反向投影原理并结合多种注意力机制和融合策略构建了一个基于注意力融合网络(AFN)的视频超分辨率模型。首先,在特征提取阶段,为了处理相邻帧和参考帧之间的多种运动,采用反向投影结构来获取运动信息的误差反馈;然后,使用时间、空间和通道注意力融合模块来进行多维度的特征挖掘和融合;最后,在重建阶段,将得到的高维特征经过卷积重建出高分辨率的视频帧。通过学习视频帧内和帧间特征的不同权重,充分挖掘了视频帧之间的相关关系,并利用迭代网络结构采取渐进的方式由粗到精地处理提取到的特征。在两个公开的基准数据集上的实验结果表明,AFN能够有效处理包含多种运动和遮挡的视频,与一些主流方法相比在量化指标上提升较大,如对于4倍重建任务,AFN产生的视频帧的峰值信噪比(PSNR)在Vid4数据集上比帧循环视频超分辨率网络(FRVSR)产生的视频帧的PSNR提高了13.2%,在SPMCS数据集上比动态上采样滤波视频超分辨率网络(VSR-DUF)产生的视频帧的PSNR提高了15.3%。 相似文献
9.
采用硬质合金涂层刀具高速铣削AF1410高强度钢,基于单因素试验法研究了切削参数对切屑形态和毛边形态的影响,分析了切屑锯齿间距、毛边几何参数随切削速度和进给量的变化规律.结果 表明:切削速度较低时,切屑自由表面形成上窄下宽、上深下浅的剪切滑移变形带,带内剪切变形较小,切削速度增加,绝热剪切变形增大,切屑自由表面形成平行的锯齿形态,锯齿间距随切削速度的提高而增大;在高速切削条件下,锯齿间距随进给量的提高而略有增大,切屑由顶部沿锯齿节间沟槽发生纵向撕裂形成毛边,毛边宽度和高度随切削速度先增大后减小,随进给量减小. 相似文献
10.