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Estève Ernault Julie Diani Simon Hallais Clio Cocquet 《Polymer Engineering and Science》2021,61(7):1971-1981
The mechanical behaviors of five polyether block amide foams, obtained by mold-opening foam injection process, were investigated with regard to their microstructures. The materials vary in mass ratios of hard versus soft segments, and/or in process packing time. The resulting microstructures have been characterized in terms of cavity size and shape ratios, by analyzing scanning electron microscope images after careful sample preparation. The foam mechanical responses have been characterized in compression at small and large strain. At small strain, the initial linear part of the stress–strain curve is enhanced firstly by the hard segment mass ratio and secondly by the fineness of the microstructure. Similar results have been obtained at large strain. The foam viscoelasticity at large strain has been characterized by stress relaxation and strain recovery tests, relevant for foam applications. Reduced packing time and pressure have been shown to lead to the presence of undesired large cavities. The morphological defects appear to have a negligible impact on the macroscopic mechanical behavior of the foams at infinitesimal strain, but lead to critical inconsistency at large strain. Furthermore, the mechanical behavior of the tested polyether block amide foams is controlled first by hard versus soft segments ratio, and second by the microstructure fineness. 相似文献
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Recent Progress in Applications of the Cold Sintering Process for Ceramic–Polymer Composites 下载免费PDF全文
Jing Guo Xuetong Zhao Thomas Herisson De Beauvoir Joo‐Hwan Seo Seth S. Berbano Amanda L. Baker Clio Azina Clive A. Randall 《Advanced functional materials》2018,28(39)
Ceramic–polymer composites are of interest for designing enhanced and unique properties. However, the processing temperature windows of sintering ceramics are much higher than that of compaction, extrusion, or sintering of polymers, and thus traditionally there has been an inability to cosinter ceramic–polymer composites in a single step with high amounts of ceramics. The cold sintering process is a low‐temperature sintering technology recently developed for ceramics and ceramic‐based composites. A wide variety of ceramic materials have now been demonstrated to be densified under the cold sintering process and therefore can be all cosintered with polymers from room temperature to 300 °C. Here, the status, understanding, and application of cold cosintering, with different examples of ceramics and polymers, are discussed. One has to note that these types of cold sintering processes are yet new, and a full understanding will only emerge after more ceramic–polymer examples emerge and different research groups build upon these early observations. The general processing, property designs, and an outlook on cold sintering composites are outlined. Ultimately, the cold sintering process could open up a new multimaterial design space and impact the field of ceramic–polymer composites. 相似文献
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Clio Deferm Jaco Hulsegge Claudia Möller Ben Thijs 《Journal of Applied Electrochemistry》2013,43(8):797-804
The electrochemical dissolution of Pt in several ionic liquids (ILs) was studied. Different ILs were tested assessing their potential to dissolve Pt. Dissolution rate and current efficiency were evaluated. The main focus was on Cl containing ILs: first generation, eutectic-based ILs and second generation ILs with discrete anions. Pt dissolution only occurred in type 1 eutectic-based ILs with a max. dissolution rate of 192.2 g m?2 h?1 and a max. current efficiency of 99 % for the ZnCl2–1-ethyl-3-methylimidazolium chloride IL, and 9.090 g m?2 h?1 and 96 % for the 1:1 ZnCl2–choline chloride IL. The dissolution occurred through the formation of [PtClx]y? complexes. To form these complexes, addition of a metal chloride was necessary. Furthermore, an IL with an electrochemical window of 1.5 V, preferably 2.0 V was required to achieve Pt dissolution. The added metal salt needed to have a higher decomposition potential than 1.5 V or should be a Pt salt. 相似文献
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Noncontact optical imaging in mice with full angular coverage and automatic surface extraction 总被引:1,自引:0,他引:1
Meyer H Garofalakis A Zacharakis G Psycharakis S Mamalaki C Kioussis D Economou EN Ntziachristos V Ripoll J 《Applied optics》2007,46(17):3617-3627
During the past decade, optical imaging combined with tomographic approaches has proved its potential in offering quantitative three-dimensional spatial maps of chromophore or fluorophore concentration in vivo. Due to its direct application in biology and biomedicine, diffuse optical tomography (DOT) and its fluorescence counterpart, fluorescence molecular tomography (FMT), have benefited from an increase in devoted research and new experimental and theoretical developments, giving rise to a new imaging modality. The most recent advances in FMT and DOT are based on the capability of collecting large data sets by using CCDs as detectors, and on the ability to include multiple projections through recently developed noncontact approaches. For these to be implemented, we have developed an imaging setup that enables three-dimensional imaging of arbitrary shapes in fluorescence or absorption mode that is appropriate for small animal imaging. This is achieved by implementing a noncontact approach both for sources and detectors and coregistering surface geometry measurements using the same CCD camera. A thresholded shadowgrammetry approach is applied to the geometry measurements to retrieve the surface mesh. We present the evaluation of the system and method in recovering three-dimensional surfaces from phantom data and live mice. The approach is used to map the measured in vivo fluorescence data onto the tissue surface by making use of the free-space propagation equations, as well as to reconstruct fluorescence concentrations inside highly scattering tissuelike phantom samples. Finally, the potential use of this setup for in vivo small animal imaging and its impact on biomedical research is discussed. 相似文献
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Clio Deferm Jaco Hulsegge Claudia Möller Ben Thijs 《Journal of Applied Electrochemistry》2013,43(8):789-796
The electrochemical dissolution of Pt in several ionic liquids (IL’s) was studied. Different IL’s were tested assessing their potential to dissolve Pt. Dissolution rate and current efficiency were evaluated. The main focus was on Cl containing IL’s: first generation, eutectic based IL’s and second generation IL’s with discrete anions. Pt dissolution only occurred in type 1 eutectic-based IL’s with a max. dissolution rate of 192.2 g m?2 h?1 and a max. current efficiency of 99 % for the ZnCl2-1-ethyl-3-methylimidazolium chloride IL, and 9.090 g m?2 h?1 and 96 % for the 1:1 ZnCl2–choline chloride ionic liquid. The dissolution occurred via the formation of [PtCl x ] y? complexes. To form these complexes, addition of a metal chloride was necessary. Furthermore, an IL with an electrochemical window of 1.5 V, preferably 2.0 V is required to achieve Pt dissolution. The added metal salt needed to have a higher decomposition potential than 1.5 V or should be a Pt salt. 相似文献
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Clio Azina Tim Bartsch Damian M. Holzapfel Martin Dahlqvist Johanna Rosen Lukas Löfler Alba San Jose Mendez Marcus Hans Daniel Primetzhofer Jochen M. Schneider 《Journal of the American Ceramic Society》2023,106(4):2652-2665
Herein we report on the synthesis of a metastable (Cr,Y)2AlC MAX phase solid solution by co-sputtering from a composite Cr–Al–C and elemental Y target, at room temperature, followed by annealing. However, direct high-temperature synthesis resulted in multiphase films, as evidenced by X-ray diffraction analyses, room-temperature depositions, followed by annealing to 760°C led to the formation of phase pure (Cr,Y)2AlC by diffusion. Higher annealing temperatures caused a decomposition of the metastable phase into Cr2AlC, Y5Al3, and Cr-carbides. In contrast to pure Cr2AlC, the Y-containing phase crystallizes directly in the MAX phase structure instead of first forming a disordered solid solution. Furthermore, the crystallization temperature was shown to be Y-content dependent and was increased by ∼200°C for 5 at.% Y compared to Cr2AlC. Calculations predicting the metastable phase formation of (Cr,Y)2AlC and its decomposition are in excellent agreement with the experimental findings. 相似文献
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