Efficient Excitation of Hybrid Modes in a THz Clinotron

Journal of Infrared, Millimeter, and Terahertz Waves - Various regimes of hybrid, bulk-surface, modes being excited in the clinotron oscillator with a sheet electron beam and nonuniform grating...     

Solvent-Aided Crystallization for Biodiesel Purification

The application of solvent-aided crystallization (SAC) is based on the addition of a solvent, here 1-butanol, to crude biodiesel to catalyze the purification process by separating biodiesel from contaminants via crystallization process. Response surface methodology was applied to optimize the process parameters of SAC, represented by biodiesel purity. The purified biodiesel was analyzed by means of gas chromatography-mass spectrometry for the composition of the present fatty acid methyl ester (FAME). Under the predicted optimum process conditions within the experimental ranges for the highest biodiesel purity, the predicted biodiesel purity was 99.375 %.     

Structural properties of nanocomposites based on resole-type phenol-formaldehyde oligomers and detonation nanodiamonds

Using the methods of infrared spectroscopy (IRS) and X-ray photoelectron spectroscopy (XPS), it was shown that short-term high-energy machining of detonation nanodiamonds (DND) leads to structural changes in the crystal structure and functional composition of the surface layer on particles. The possibility of spontaneous formation for stable colloidal systems with a narrow size distribution of mechanically activated DND in phenol-formaldehyde oligomers (PFO) was established. By molecular spectroscopy it was revealed that π → π* interactions of the aromatic rings of PFO are caused by orientational phenomena as a result of hydrogen bonds between an activated DND surface and functional groups of PFO. The effect of DND concentration on the curing reaction parameters ofpsgr the phenol-formaldehyde oligomer was determined by differential scanning calorimetry (DSC). The concentration effect of mechanically activated nanodiamonds on the physical and mechanical characteristics of a composite material based on phenol-formaldehyde binder and polyamide paper (Nomex) was studied. © 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2020 , 137, 48582.     

Efficient Modular Synthesis of Isomeric Mono‐ and Bispyridyl[2.2]paracyclophanes by Palladium‐Catalyzed Cross‐ Coupling Reactions

Pyridyl‐substituted [2.2]paracyclophanes build a multifunctional structural motif that is useful in material chemistry, catalysis and for luminescent structures. Nonetheless, there is still a lack of general methods for the synthesis of these structures tolerating easily accessible bromides as well as different isomeric pyridyl groups. Hence the coupling of functionalized [2.2]paracyclophanes with various substituted and functionalized pyridyl derivatives was achieved using Stille, Suzuki and Kumada coupling conditions. Hereby the Stille coupling of a [2.2]paracyclophane is presented as a versatile reaction for the formation of heteromeric [2.2]paracyclophane‐containing biaryl structures.

     

Anthropogenic I in the atmosphere: Overview over major sources, transport processes and deposition pattern

Wet and, to a lesser extent, dry deposition of atmospheric ¹²⁹I are known to represent the dominating processes responsible for ¹²⁹I in continental environmental samples that are remote from ¹²⁹I sources and not directly influenced by any liquid ¹²⁹I release of nuclear installations. Up to now, however, little is known about the major emitters and the related global deposition pattern of ¹²⁹I.In this work an overview over major sources of ¹²⁹I is given, and hitherto unknown time-dependent releases from these were estimated. Total gaseous ¹²⁹I releases from the US and former Soviet reprocessing facilities Hanford, Savannah River, Mayak, Seversk and Zheleznogorsk were found to have been 0.53, 0.27, 1.05, 0.23 and 0.14 TBq, respectively. These facilities were thus identified as major airborne ¹²⁹I emitters.The global deposition pattern due to the ¹²⁹I released, depending on geographic latitude and longitude, and on time was studied using a box model describing the global atmospheric transport and deposition of ¹²⁹I. The model predictions are compared to ¹²⁹I concentrations measured by means of Accelerator Mass Spectrometry (AMS) in water samples that were collected from various lakes in Asia, Africa, America and New Zealand, and to published values.As a result, both pattern and temporal evolution of ¹²⁹I deposition values measured in and calculated for different types of environmental samples are, in general, in good agreement. This supports our estimate on atmospheric ¹²⁹I releases and the considered substantial transport and deposition mechanisms in our model calculations.     

The slope of a transfer function

Exact and approximate equations are derived that relate the magnitude slope of a general transfer function directly to its phase angle. The result is used to derive simple conditions on stabilizability of feedback loops with right half-plane poles and zeros or dead-time.     

The impact of nuclear analysis on ITER design and licensing

The complexity of nuclear analysis on the design components of ITER is discussed. These analyses include the determination of several nuclear responses and it is shown that these results are not only relevant to the component under examination but have implications for the design of many other, often remote, systems. The contribution of nuclear analysis to the licensing process is discussed. An example is given of how this complexity means that the there is a large set of complementary analyses required to address the concerns of the licensing authorities. It also means that the nuclear analysis must be co-ordinated to ensure that the results are self-consistent and provide an integrated solution.