Gas permeation property of polyaniline films

We examined the influence of polyaniline (PAn)'s unit sequence and doping with low molecular weight dopants or polymer dopants on permeation property. It was found that CO₂ permeability was increased by the formation of a quinonediimine unit in PAn with the oxidation. CO₂ sorption amount of PAn was decreased by oxidation. The increase of CO₂ permeability with oxidation, therefore, resulted from the increase of diffusivity, which was attributable to morphological variation by the increase of a quinonediimine unit. The permselectivity of PAn films was found to be remarkably improved by doping. In particular, the selectivity value of the PAn film doped with polyvinyl sulphonic acid as a polymer dopant went up to over 2,000. This remarkable increase of selectivity was found to result in the increase of selectivity, depending on diffusivity. It was also found that the permselectivity of the PAn film doped by polymer dopants was surpassed, as compared with that doped by low molecular dopants. © 1995 John Wiley & Sons, Inc.     

Sorption and permeation of iodine in water-swollen poly(vinyl alcohol) membranes and iodine complex formation

The sorption and the permeation of iodine in water-swollen poly(vinyl alcohol) (PVA) membranes and the formation of PVA–iodine complexes were studied. The logarithms of the permeability and the diffusion coefficient decreased approximately linearly with the increase in polymer volume fraction. When the membrane was soaked in an aqueous I₂–KI solution, it contracted and Young's modulus increased. These findings were explained in terms of the formation of extra junction points due to the PVA–iodine complexes. These changes were reversible and could be recovered by replacing the solution with water. The length of the polyiodine chain increased with the increase in the degree of hydration of the membrane. At a fixed degree of hydration, Young's modulus of an iodine-sorbed membrane was much greater than that of a membrane soaked in pure water. This finding was explained on the basis of a double-network structure. The extension of the membrane promoted the complex formation, and the complex disappeared when the tension was released. The critical strain necessary for the complex formation was independent of the degree of hydration. The length of polyiodine chain increased with strain and became constant at higher strains.     

Preparation of Silicon Carbide and Aluminum Silicon Carbide from a Montmorillonite–Polyacrylonitrile Intercalation Compound by Carbothermal Reduction

Both silicon carbide and aluminum silicon carbide have simultaneously been obtained directly from naturally occurring aluminosilicate by carbothermal reduction for the first time. A precursor of a montmorillonite–polyacrylonitrile (PAN) intercalation compound was heated at 1700°C in Ar. For comparison, montmorillonite–carbon mixtures were similarly heated. α-SiC, β-SiC, and Al₄Si₂C₅ formed from the montmorillonite–PAN intercalation compound. Mainly α-Al₄SiC₄ was obtained with ternary carbides from the montmorillonite–carbon mixtures in addition to a large amount of β-SiC. Hence, aluminum silicon carbide formation was affected by the mixing condition of the starting materials.     

Plasma developable photoresist containing electronic excitation energy quenching system

A dry developable negative working resist composition comprised of poly(methyl isopropenyl ketone) (PMIPK) and 4-methyl-2,6-di(4′-azido-benzylidene) cyclohexanone-1 was examined. The main photochemical product formed in the resist pattern was found to be a secondary amine which crosslinks PMIPK. Post-annealing forms a hydrogen-bonded product which shows a powerful electronic excitation energy quenching effect. The quencher is more powerful than the aromatic compound arising from the azide by post-annealing only. The residual resist thickness of the negative pattern is about 80 percent of the initial thickness of the coating in spite of all the azide compound remaining in the resist coating. The obtained dry developed resist pattern has a high dry etch resistance. Etchings of Si and SiO₂ were performed by plasma and reactive ion etching, respectively.     

Interdiffusion in Co-Mn alloys

Interdiffusion coefficient in cobalt-manganese alloys has been determined by Matano's method in the temperature range between 1133 and 1423 K on (pure Co)-(Co-30.28 at. pct Mn alloy) and (pure Co)-(Co-51.76 at. pct Mn alloy) couples. This, ∼D, has been found to increase with the increase of manganese content. However, the activation energy (∼Q) and frequency factor ( ₀) show a maximum at about 10 at. pct Mn. The concentration dependence of and has been discussed taking into account the thermodynamic properties of the alloy. The difference in between the ferro- and paramagnetic phases in Co-5 at. pct Mn alloy has been found to be 24 kJ/mol, which is larger, than that for the diffusion of Mn⁵⁴ in this alloy. Further it has been found that the Kirkendall marker moves toward manganese-rich side, showing that manganese atoms diffuse faster than cobalt atoms. From the marker shift, the intrinsic diffusion coefficients,D _Co andD _Mn, at 33 at. pct Mn have been determined as follows:D _Co=0.22×10⁻⁴ exp(−263 kJ mol⁻¹/RT) m²/s, andD _Mn=0.98×10⁻⁴ exp(−229 kJ mol⁻¹/RT) m²/s.     

Normal Spectral Emissivity Measurement of Molten Cu–Co Alloy Using an Electromagnetic Levitator Superimposed with a Static Magnetic Field

The normal spectral emissivity of molten Cu–Co alloy with different compositions was measured in the wavelength range of 780 nm to 920 nm and in the temperature range of 1430 K to 1770 K including the undercooled condition by an electromagnetic levitator superimposed with a static magnetic field. The emissivity was determined as the ratio of the radiance from a levitated molten Cu–Co droplet measured by a spectrometer to the radiance from a blackbody calculated by Planck’s law at a given temperature, where a static magnetic field of 2.5 T to 4.5 T was applied to the levitated droplet to suppress the surface oscillation and translational motion of the sample. We found little temperature dependence of the normal spectral emissivity of molten Cu–Co alloy. Concerning the composition dependence, the emissivity decreased markedly above 80 at%Cu and reached that of pure Cu, although its dependence was low between 20 at%Cu and 80 at%Cu. In addition, this composition dependence of the emissivity of molten Cu–Co alloy can be explained well by the Drude free-electron model.     

Nonlinear phase distortion and its compensation in l.e.d. direct modulation

Differential phase distortion of the light-emitting diode is measured and analysed. An effective technique is proposed to compensate the d.p. distortion. An experimental result shows that 2.8° d.p. distortion has been reduced to within 1°.     

Speckle Noise Reduction in Fiber Optic Analog Video Transmission Using Semiconductor Laser Diodes

This paper investigates the effects of speckle noise on analog video transmission systems using semiconductor laser diodes. The system linearity degradation due to speckle noise is examined using different fiber types. Then this paper proposes a new modulation technique employing a superimposed pulse scheme to reduce speckle noise. It is experimentally confirmed that the proposed modulation method is effective in reducing speckle noise. Based on the above investigations, analog video transmission experiments are performed using single-mode fibers, step-index multimode fibers, and graded-index multimode fibers in the 0.8 and 1.3 μm wavelength regions. The results of the transmission tests have confirmed the feasibility of analog video transmission using semiconductor laser diodes.     

A Review of Broad-Band Fiber System Activity in Japan

In the future information society, various kinds of services will be required in offices, factories, homes, and communities. Fiber optic broad-band systems will play the most important role in the integrated services networks that will provide such services. This paper reviews field trials of fiber optic broad-band systems in Japan, focusing on subscriber loop system technology.