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排序方式: 共有896条查询结果,搜索用时 15 毫秒
1.
Mollie B. Schear Arianna Neal Jadah S. Clarke Andrew P. Saab Carl B. Giller Riccardo Casalini Matthew Laskoski 《应用聚合物科学杂志》2021,138(12):50053
The preparation of highly aromatic elastomers from a bisphenol A-based divinyl-terminated resin and polymerization with various aromatic silane containing compounds utilizing a room temperature hydrosilylation reaction is demonstrated. The polymers exhibit high thermal and oxidative stability with 5% weight losses around 430 and 350°C and char yields ranging from 35% to 40%. The thermosets maintained their elastomeric properties with good hardness and mechanical properties as measured by elongation measurements. The toughness of the thermosets was not improved with the inclusion of aromatic moieties but the hardness did appear to increase with the addition of more aromatic groups. 相似文献
2.
Russell C. Rockne Andrew D. Trister Joshua Jacobs Andrea J. Hawkins-Daarud Maxwell L. Neal Kristi Hendrickson Maciej M. Mrugala Jason K. Rockhill Paul Kinahan Kenneth A. Krohn Kristin R. Swanson 《Journal of the Royal Society Interface》2015,12(103)
Glioblastoma multiforme (GBM) is a highly invasive primary brain tumour that has poor prognosis despite aggressive treatment. A hallmark of these tumours is diffuse invasion into the surrounding brain, necessitating a multi-modal treatment approach, including surgery, radiation and chemotherapy. We have previously demonstrated the ability of our model to predict radiographic response immediately following radiation therapy in individual GBM patients using a simplified geometry of the brain and theoretical radiation dose. Using only two pre-treatment magnetic resonance imaging scans, we calculate net rates of proliferation and invasion as well as radiation sensitivity for a patient''s disease. Here, we present the application of our clinically targeted modelling approach to a single glioblastoma patient as a demonstration of our method. We apply our model in the full three-dimensional architecture of the brain to quantify the effects of regional resistance to radiation owing to hypoxia in vivo determined by [18F]-fluoromisonidazole positron emission tomography (FMISO-PET) and the patient-specific three-dimensional radiation treatment plan. Incorporation of hypoxia into our model with FMISO-PET increases the model–data agreement by an order of magnitude. This improvement was robust to our definition of hypoxia or the degree of radiation resistance quantified with the FMISO-PET image and our computational model, respectively. This work demonstrates a useful application of patient-specific modelling in personalized medicine and how mathematical modelling has the potential to unify multi-modality imaging and radiation treatment planning. 相似文献
3.
Rebecca J. O'Toole Christopher J. Bartel Maila U. Kodas Alexa J. Horrell Sandrine Ricote Neal P. Sullivan Christopher J. Gump Charles B. Musgrave Alan W. Weimer 《Journal of the American Ceramic Society》2019,102(5):2283-2293
The addition of aluminum oxide (Al2O3) as a sintering aid to yttria-stabilized zirconia (YSZ) reduces the required densification temperature. Sintering aids are incorporated using a number of processes which can lead to ambiguity when determining the effect of the sintering aid on the densification mechanism. In this study, a novel method for sintering aid addition, Particle Atomic Layer Deposition (ALD), was used to deposit an amorphous Al2O3 thin film on YSZ particles. Transmission electron microscopy confirmed the deposition of conformal Al2O3 thin films on the surface of the YSZ particles. The addition of Al2O3 to YSZ reduced the temperature at which densification began by ~75°C, and 2.2 wt% Al2O3 addition resulted in a minimum activation energy for the intermediate stage of densification. This concentration is well in excess of the solubility limit of Al2O3 in YSZ, showing that Al2O3 does not enhance the densification of YSZ solely by dissolving into the YSZ lattice and activating volume diffusion. The addition of 0.7 wt% Al2O3 with one Particle ALD cycle enhanced the ionic conductivity of YSZ by 23% after sintering at 1350°C for 2 hours, demonstrating that dense parts with high oxygen ion conductivities can be produced after sintering at reduced temperatures. One Particle ALD cycle is a fast, easily scaled-up process that eliminates the use of solvents and has substantial cost/performance advantages over conventional processing. 相似文献
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5.
Adrien N. Djomo J. Andrew Grant Celestine Fonyikeh-Bomboh Lucha Julie Tchoko Gagoe Noël H. Fonton Neal Scott 《The International journal of environmental studies》2018,75(2):251-266
Forests play a significant role in the global carbon budget, and can help to mitigate climate change impacts. Tropical forests which experience high rates of deforestation and forest degradation are particularly important, as they are the most active in winter. Based on academic research into global environmental policies in Central Africa, this study finds that REDD+ policies can succeed when there is a carbon market mechanism that increases participation by developing countries, with better integration of forest management and community forestry. Incentives should be based on an appropriate baseline, accurate carbon stocks and fluxes estimation, a suitable silvicultural system and regular monitoring. 相似文献
6.
Dong Quan Peter Moloney Declan Carolan Hisham Abourayana Calvin Ralph Alojz Ivankovic Denis Dowling Neal Murphy 《应用聚合物科学杂志》2021,138(1):49605
This work studied the effects of adding short basalt fibers (BFs) and multi-walled carbon nanotubes (MWCNTs), both separately and in combination, on the mechanical properties, fracture toughness, and electrical conductivity of an epoxy polymer. The surfaces of the short BFs were either treated using a silane coupling agent or further functionalized by atmospheric plasma to enhance the adhesion between the BFs and the epoxy. The results of a single fiber fragmentation test demonstrated a significantly improved BF/epoxy adhesion upon applying the plasma treatment to the BFs. This resulted in better mechanical properties and fracture toughness of the composites containing the plasma-activated BFs. The improved BF/epoxy adhesion also affected the hybrid toughening performance of the BFs and MWCNTs. In particular, synergistic toughening effects were observed when the plasma-activated BFs/MWCNTs hybrid modifiers were used, while only additive toughening effects occurred for the silane-sized BFs/MWCNTs hybrid modifiers. This work demonstrated a potential to develop strong, tough, and electrically conductive epoxy composites by adding hybrid BF/MWCNT modifiers. 相似文献
7.
Lanthanum erbium carbide, La0.5Er0.5C2, a salt-like carbide with a cubic fluorite phase structure, has been produced from 13C, allowing carbon diffusion rate to be determined using 12C. Carbon in salt-like carbides exhibits significant ionicity, and a high carbon diffusion rate would enable a new class of
high temperature fuel cells based on carbon-ion transport. The complete lack of carbon diffusion data for salt-like carbides
is the motivation for this work. The carbon diffusion rate in La0.5Er0.5C2 has now been determined to be 2.0 ± 0.8 × 10−13 cm2/s at 850 °C, increasing to 1.8 ± 0.8 × 10−11 cm2/s at 1150 °C, with an activation energy of about 95 kJ/mole. These diffusion rates are too low for a carbon-ion fuel cell,
but a number of other salt-like carbides exist. Be2C, in particular, is a salt-like carbide with an antifluorite structure, and should have higher carbon-ion diffusion than
cubic La0.5Er0.5C2 due to the unoccupied octahedral sites in the antifluorite structure, but Be2C presents special difficulties due to the toxic nature of its hydrolysis products. 相似文献
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10.
The Maxim's Electron Scatter Chamber (Maxim Chamber) was developed to obtain uniform dose distribution when applying electron beam (e-beam) irradiation to materials of irregular surface. This was achieved by placing a stainless steel mesh surrounding a cylindrical area where the target sample was placed. Upon contact with the mesh, electrons scatter and are directed onto the target from multiple angles, eliminating the e-beam linearity and resulting in a uniform dose distribution over the target surface. The effect of irradiation in the Maxim Chamber on dose distribution and pathogen reduction was tested on rabbit carcasses to simulate other larger carcasses. The dose uniformity ratio (DUR) on the rabbit carcasses was 1.8, indicating an acceptable dose distribution. On inoculated carcasses, this treatment reduced Escherichia coli O157:H7 by > 5 log cycles. These results indicate that carcass irradiation using e-beam is feasible using the Maxim's electron scattering chamber. Appropriate adjustments will be further needed for commercial application on beef and other animal carcasses. 相似文献