纯铝等径角挤技术（I）——显微组织演化

研究了纯铝在 3种 (A、B和C)不同等径角挤工艺中的显微组织演化。结果表明 :纯铝经过等径角挤压变形后 ,其显微组织特征与加工路线有很大的关系。提出了立方元素扭转模型 ,分析了 3种不同加工路线的剪切面和剪切方向 ,较好地解释了采用 3种不同路线挤压后材料显微组织的演化规律。在路线C(各道次挤压间试样旋转 180°)中 ,每次挤压样品总是在相同的剪切面上发生剪切 ,每相邻道次之间的剪切方向相反 ,前一次变形产生的剪切应变被随后紧接着的下一次挤压所抵消 ,这导致了多余的剪切应变 ;在路线A(各道次挤压间试样不旋转 )中 ,有两个相交成 6 0°的剪切面 ,剪切交替地在两个剪切面上进行 ;在路线B(各道次挤压间试样旋转 90°)中 ,存在 4个不同的剪切面和剪切方向 ,挤压交替地在 4个剪切面上进行 ,X ,Y和Z平面上的晶粒都发生了剪切 ,这有利于等轴晶结构的形成     

Effects of can parameters on canned—forging process of TiAl base alloy（Ⅱ）——Mechanical behavior

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Ti-Al基合金中的Hall-Petch关系及影响因素分析

研究了全层片状组织Ti-Al基合金的室温拉伸性能与品团尺寸的关系。Ti-Al基合金的室温拉伸屈服强度和断裂强度与晶团尺寸成Hall-Petch关系。当合金中添加替代元素Cr和Nb时，其Hall-Petch斜率不变；而添加间隙元素C和B时，其Hall-Petch斜率增加。Ti-Al基合金的室温延伸率与晶团尺寸不满足Hall-Petch关系。     

Electrodeposition of Ni-Co-Fe2O3 composite coatings

Ni-Co-Fe₂O₃ composite coatings were electrodeposited using cetyltrimethylammonium bromide (CTAB)-modified Watt’s nickel bath with Fe₂O₃ particles dispersed in it. The effects of the plating parameters on the chemical composition, structural and morphological characteristics of the electrodeposited Ni-Co-Fe₂O₃ composite coatings were investigated by energy dispersive X-ray (EDS) spectroscopy, X-ray diffractometry (XRD) and scanning electron microscopy (SEM). The results reveal that Fe₂O₃ particles can be codeposited in the Ni-Co matrix. The codeposition of Fe₂O₃ particles with Ni-Co is favoured at high Fe₂O₃ particle concentration and medium stirring, and the deposition of Co is favoured at high concentration of CTAB. Moreover, the study of the textural perfection of the deposits reveals that the presence of particles leads to the worsening of the quality of the observed 〈220〉 preferred orientation. Composites with high concentration of embedded particles exhibit a preferred crystal orientation of 〈111〉. The more the embedded Fe₂O₃ particles in the metallic matrix, the smaller the sizes of the crystallite for the composite deposits.     

Electrocatalytic properties of Ni-S-Co coating electrode for hydrogen evolution in alkaline medium

Amorphous Ni-S-Co alloy was prepared by means of chemical electro-deposition method on the foam nickel matrix. The surface morphology and microstructure of Ni-S-Co coatings were studied usmg SEM and XRD, and the electrochemical properties were tested by electrochemical methods. The results show that the coating has amorphous structure and the particles of the surface are fine with large specific surface area. The Ni-S-Co alloy is more active with lower potential for hydrogen evolution, higher exchange current density and lower activation energy compared with Ni and Ni-S electrode. Its hydrogen evolution reaction（HER） is enhanced, the size of particles of surface decreases and the surface area increases after being activated by KOH alkaline solution.     

HA/Ti composite for biomedical application by mechanical milling

In order to overcome the poor mechanical properties of HA and the low bioactivity of Ti,HA/Ti composites with various compositions were prepared by mechanical milling.The effects of milling condition and the composition on the microstructure,the density and the hardness of the composites were studied.The results show that during the ball milling process.Ti particles are refined and the homogeneity of the HA/Ti mixtures is improved;HA will partially decompose due to the existence of Ti and high sintering temperature.The microstructure of HA/Ti composites is highly dependent on the milling condition and the composition.In the microstructure.Ti phase connects to be a continuous network,and HA/Ti mixtures disperse in the network.The longer the milling time,the finer the network will be.The density of HA/T composites decreases with the content of HA increasing and the milling time prolonging,because HA deteriorates the sinterability of Ti.The hardness of HA/Ti composites increases firstly with the content of HA increasing,and then drops when the content of HA exceeds 30%.Addition of HA will strengthen the HA/T composite but will decrease the density of the composite,which accounts for the effect of HA on the hardness of the composites.     

纯铝等径角挤技术(Ⅱ)--变形行为模拟

通过有限元模拟和坐标网格，对纯铝等径角挤过程的变形行为进行了模拟和试验。结果表明，纯铝在单道次等径角挤压过程中所需的载荷随着样品位移的增加大致可分为快速增加、缓慢增加、快速增加、载荷值趋于稳定、载荷下降5个阶段。由于样品外部在主要变形区的流动速率比样品内部的快，因而样品在等径角挤压过程中会出现不均匀变形，样品底部沿宽度方向的塑性变形量明显少于样品顶部和中部的，坐标网格法实验结果也证明了这一点。在等径角挤压过程中，样品不同部位的应力状态不一致，样品内部存在压应力→拉应力的转变，样品外部存在压应力→拉应力→压应力的转变。摩擦消除后，有效应变有所增加，但并不能降低样品变形的不均匀性；采用尖角模具既能产生更大的剪切应变，又能提高变形的均匀性。     

机械合金化制备超细、纳米晶CuCr触头材料的探讨

分析探讨了机械合金化工艺制备超细、纳米晶CuCr材料中的晶粒尺寸、氧含量和材料密度控制等主要问题，提出了一种低成本制备高性能CuCr触头材料的新思路，即添加高性能晶粒长大抑制剂 普通真空烧结工艺。     

氧化铋的应用研究进展

氧化铋是一种先进的功能粉体材料,应用前景广阔.综述了氧化铋的国内外研究进展,详细介绍了氧化铋在电子陶瓷粉体材料、电解质材料、光电材料、高温超导材料、催化剂方面的应用,强调了其特殊性能的优势和应用潜力,阐明了我国研究开发氧化铋的意义.