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排序方式: 共有221条查询结果,搜索用时 31 毫秒
1.
Olga Yu Kurapova Sergey M. Shugurov Evgenia A. Vasil'eva Daniil A. Savelev Vladimir G. Konakov Sergey I. Lopatin 《Ceramics International》2021,47(8):11072-11079
Ceria-based solid solutions are important materials for high- and medium-temperature electrochemical applications. However, the stabilities of both binary and ternary ceria-based solid solutions are insufficient at elevated temperatures, which limits their application as solid electrolytes or SOFC cathodes. Data on the high-temperature stability of ceria-based ceramics are unavailable in the literature. In the present study, we report a thermodynamic stability investigation of Y2O3-CeO2 and Y2O3-ZrO2-CeO2 solid solutions. The thermal prehistories of binary and ternary systems were investigated using STA, XRD, and ESCA techniques. The vaporization processes were investigated in the temperature range of 1577–2227°С via the Knudsen effusion mass spectrometry technique. Using data on the component activity in solid-phase thermodynamic properties of Y2O3-CeO2 solid solutions, which is represented as the Gibbs energy, the excess Gibbs energy was calculated as a function of the ceria mol. %. It was shown that the reduction of Ce4+ to Ce3+ in Y2O3-CeO2 and Y2O3-ZrO2-CeO2 solid solutions corresponds to less-negative Gibbs energy compared to ZrO2-CeO2 solid solutions. 相似文献
2.
Motrenko Anastasia Simchuk Egor Khairullin Renat Inyakin Andrey Kashirin Daniil Strijov Vadim 《Multimedia Tools and Applications》2022,81(4):4877-4895
Multimedia Tools and Applications - The paper addresses the problem of human activity recognition based on the data from wearable sensors. Human activity recognition depends on a wide context of... 相似文献
3.
Chumakov Yu. A. Knyazeva A. G. Pribytkov G. A. 《Theoretical Foundations of Chemical Engineering》2021,55(3):490-503
Theoretical Foundations of Chemical Engineering - On the basis of the classic concepts of the theory of solid-phase combustion, for the first time, a model with a detailed scheme of chemical... 相似文献
4.
Svetlana V. Klinova Boris A. Katsnelson Ilzira A. Minigalieva Oksana P. Gerzen Alexander A. Balakin Ruslan V. Lisin Ksenia A. Butova Salavat R. Nabiev Oleg N. Lookin Leonid B. Katsnelson Larisa I. Privalova Daniil A. Kuznetsov Vladimir Ya. Shur Ekaterina V. Shishkina Oleg H. Makeev Irene E. Valamina Vladimir G. Panov Marina P. Sutunkova Larisa V. Nikitina Yuri L. Protsenko 《International journal of molecular sciences》2021,22(7)
Subchronic intoxication was induced in outbred male rats by repeated intraperitoneal injections with lead oxide (PbO) and/or cadmium oxide (CdO) nanoparticles (NPs) 3 times a week during 6 weeks for the purpose of examining its effects on the contractile characteristics of isolated right ventricle trabeculae and papillary muscles in isometric and afterload contractions. Isolated and combined intoxication with these NPs was observed to reduce the mechanical work produced by both types of myocardial preparation. Using the in vitro motility assay, we showed that the sliding velocity of regulated thin filaments drops under both isolated and combined intoxication with CdO–NP and PbO–NP. These results correlate with a shift in the expression of myosin heavy chain (MHC) isoforms towards slowly cycling β–MHC. The type of CdO–NP + PbO–NP combined cardiotoxicity depends on the effect of the toxic impact, the extent of this effect, the ratio of toxicant doses, and the degree of stretching of cardiomyocytes and muscle type studied. Some indices of combined Pb–NP and CdO–NP cardiotoxicity and general toxicity (genotoxicity included) became fully or partly normalized if intoxication developed against background administration of a bioprotective complex. 相似文献
5.
6.
Marina A. Marchenko Victoria V. Nefedova Daria S. Yampolskaya Galina V. Kopylova Daniil V. Shchepkin Sergey Y. Bershitsky Natalia A. Koubassova Andrey K. Tsaturyan Dmitrii I. Levitsky Alexander M. Matyushenko 《International journal of molecular sciences》2020,21(22)
Tropomyosin (Tpm) is one of the major actin-binding proteins that play a crucial role in the regulation of muscle contraction. The flexibility of the Tpm molecule is believed to be vital for its functioning, although its role and significance are under discussion. We choose two sites of the Tpm molecule that presumably have high flexibility and stabilized them with the A134L or E218L substitutions. Applying differential scanning calorimetry (DSC), molecular dynamics (MD), co-sedimentation, trypsin digestion, and in vitro motility assay, we characterized the properties of Tpm molecules with these substitutions. The A134L mutation prevented proteolysis of Tpm molecule by trypsin, and both substitutions increased the thermal stability of Tpm and its bending stiffness estimated from MD simulation. None of these mutations affected the primary binding of Tpm to F-actin; still, both of them increased the thermal stability of the actin-Tpm complex and maximal sliding velocity of regulated thin filaments in vitro at a saturating Ca2+ concentration. However, the mutations differently affected the Ca2+ sensitivity of the sliding velocity and pulling force produced by myosin heads. The data suggest that both regions of instability are essential for correct regulation and fine-tuning of Ca2+-dependent interaction of myosin heads with F-actin. 相似文献
7.
Abstract Using a perturbation method, constructed in terms of SU(2) group representations, the interaction of N initially unexcited two-level atoms and a weak single-mode cavity field is studied. The field is assumed to be initially either in a Fock state with a number of photons equal to n or in a coherent state. In the case of the photon-number state with n 3, the pure phenomenon of collective collapses and revivals manifests itself. For the initially coherent field the phenomenon of collapses and revivals arising from the photon number distribution mechanism is additionally modulated by this collective mechanism. The problem of the interaction of excited atoms with an initially coherent field has already been solved numerically by Barnett and Knight. For n=1 2 and 3 the approximate solution is compared with the exact solutions also given in this paper and the limit of applicability of our approach is established. 相似文献
8.
Georgy Terentyuk Elizaveta Panfilova Vitaly Khanadeev Daniil Chumakov Elina Genina Alexey Bashkatov Valery Tuchin Alla Bucharskaya Galina Maslyakova Nikolai Khlebtsov Boris Khlebtsov 《Nano Research》2014,7(3):325-337
Nanocomposites (NCs) consisting of a gold nanorod core and a mesoporous silica shell doped with hematoporphyrin (HP) have been fabricated in order to improve the efficiency of cancer treatment by combining photothermal and photodynamic therapies (PDT + PTT) in vivo. In addition to the long-wavelength plasmon resonance near 810-830 nm, the fabricated NCs exhibited a 400-nm absorbance peak corresponding to bound HP, generated singlet oxygen under 633-nm excitation near the 632.5-nm Q-band, and produced heat under a 808-nm near-infrared (NIR) laser irradiation. These modalities were used for a combined PDT + PTT treatment of large (about 3 cm3) solid tumors in vivo with a xenorafted tumor rat model. NCs were directly injected into tumors and irradiated simultaneously with 633-nm and 808-nm lasers to stimulate the combined photodynamic and photothermal activities of NCs. The efficiency of the combined therapy was evaluated by optical coherence tomography, histological analysis, and by measurements of the tumor volume growth during a 21-day period. The NC-mediated PDT led to weak changes in tissue histology and to a moderate 20% decrease in the tumor volume. In contrast, the combined PDT + PTT treatment resulted in the large-area tumor necrosis and led to dramatic decrease in the tumor volume. 相似文献
9.
The ability of treatment of pulp and paper production wastewater is showed by carbon-graphite and polymeric membranes. The influence of lignins, organic and inorganic substances containing in wastewater on specific capacity is studied. Capacity calculation of different types of membrane is suggested. 相似文献
10.
Listeria monocytogenes is an important food associated pathogen because of its relatively high heat resistance and ability to multiply in refrigeration temperatures. Its thermotolerance can be increased when its cells are subjected to heat shock. One- to eight-fold increase of D values of L. monocytogenes have been reported, depending on the heat shock duration, the temperature and the heating menstrum. This acquisition of heat tolerance is related to the induction of the synthesis of heat shock proteins (HSPs).The adaptive response of food pathogens has important consequences on the safety of thermally processed foods. It is believed that this is responsible for the frequent occurrence of deviations (tails and shoulders) during heat treatments that are observed in the exponential model of microbial inactivation. These deviations from log-linear kinetic especially encountered under mild heat treatments, mean that prediction of food safety can no longer rely upon D and z values. Adaptive response to heat must be considered when quantifying and modeling microbial inactivation during thermal processing in order to achieve microbiologically safe products without overly conservative heat processes. Therefore a more mechanistic approach is needed for more accurate predictions of thermal inactivation. Prerequisite to this model are thorough studies to understand how L. monocytogenes and other pathogens adapt their cellular physiology to overcome heat and other stresses. 相似文献