Synthesis of polymer supported Ni (II)-Schiff Base complex and its usage as a catalyst in sodium borohydride hydrolysis

Influence of using as catalysis, Ni-Schiff Base complex which we previously synthesized [1] used to support with amberzyme oxirane resin (A.O.R.) polymer for increasing the catalytic activity in NaBH₄ hydrolysis reaction, to hydrogen generation was studied. The prepared catalyst was characterized by using SEM, XRD, BET, FT-IR analyze technique. Polymer supported Ni-Schiff Base complex catalyzed NaBH₄ hydrolysis reaction was investigated depending on concentration of NaBH₄, concentration of NaOH, temperature, percentage of Ni complex in total polymer supported Ni-Schiff Base complex and amount of catalyst factors. The maximum hydrogen production rate from hydrolysis of sodium borohydride with nickel-based complex catalyst compared to the pure nickel catalyst is increased from 772 mL H₂·g^?1 cat.·min^?1 to 2240 mL H₂ g^?1 cat.·min^?1 [1], and with supported amberzyme oxirane resin polymer this nickel based complex catalyst was increased to 13000 mL H₂·g^?1 cat.·min^?1 at 30 °C. The activation energy of complex catalyzed NaBH₄ hydrolysis reaction was found as 25.377 kJ/mol. This work also includes kinetic information for the hydrolysis of NaBH₄.     

Highly active and stable CeO2 supported nickel-complex catalyst in hydrogen generation

Cerium oxide supported 5-Amino-2,4-dichlorophenol-3,5-ditertbutylsalisylaldimine-Nickel complex for the first time was used to produce H₂ from hydrolysis of sodium borohydride. Cerium oxide supported Nickel complex catalyzed hydrolysis system was studied depend on temperature, concentration of sodium hydroxide, amount of Cerium oxide supported Ni complex catalyst, concentration of Ni complex and concentration of sodium borohydride. Cerium oxide supported Ni(II) complex display highly effective catalytic activity in sodium borohydride hydrolysis reaction. The obtained Cerium oxide supported Ni(II) complex catalyst was characterized by using Fourier Transform Infrared Spectroscopy, Scanning Electron Microscope, Transmission Electron Microscope, Brunauer-Emmett-Teller Surface Area Analysis, X-Ray Diffraction Analysis techniques. The catalyst stability was tested, even the fifth recycle the catalytic activity was maintained at 100%. Additionally the proposed Cerium oxide supported-Ni (II) complex catalyzed sodium borohydride hydrolysis mechanism was determined carefully. The experimental results showed that Cerium oxide supported Ni (II) complex catalyst accelerate sodium borohydride hydrolysis with 43,392 and 19,630 mL H₂ g_cat^?1 min^?1 hydrogen production rates at 50 °C and 30 °C respectively and 20,587 kJ mol^?1 activation energy.     

Effect of heat treatment on the creep behavior of α/β SiAlON sintered with multication oxide sintering additives

SiAlONs are important materials for high-temperature applications and creep properties of SiAlONs are largely controlled by the amount and type of sintering additives. It has been established that heat treatment can reduce the amount of amorphous intergranular phase through crystallization. However, there is no study on the creep behavior of heat-treated SiAlON ceramics containing multication sintering additives. Therefore, the aim of the study was to investigate the effect of heat treatment on the creep properties of multication containing (Y-Sm-Ca oxides) α/β-SiAlON ceramics. The heat treatments of the sintered samples were carried out at 1600°C for 2 hours. The creep tests were carried out in the range 1300-1400°C under different loads (50-150 MPa). The existing phases and the microstructures of samples before and after creep were investigated using XRD and SEM techniques. It was found that heat treatment resulted in a better creep performance compared to as-sintered samples. The activation energy and stress exponent for heat-treated SiAlONs were also calculated as 708 ± 45 kJ/mol and 1.4, respectively. Compared to the sintered sample values, the results suggested that the acting creep mechanism of grain-boundary sliding and cavitation was reduced with the heat treatment.     

Biosorption of Acid Red P-2BX by lichens as low-cost biosorbents

The aim of this study is to examine the dye biosorption properties of lichen species called Cladonia convoluta and Evernia prunastri. Since lichens are extensively found in the environment, their suitability as a cheap adsorbent has been investigated in this study. The optimal parameters for textile dye biosorption were also determined. The dried lichen biomass showed better dye biosorption capacity than ash lichen biomass. C. convoluta had better dye biosorption capacity than E. prunastri. Dye biosorption rate was found as 71.41% at optimal conditions. This study concluded that C. convoluta was a successful and cheap biosorbent for treatment of water contaminated by Acid Red P-2BX dye.     

Historical narratives as strategic resources: analysis of the Turkish international contracting sector

The Turkish contracting sector has an enviable reputation for operating in high-risk international markets. The sector’s ability to respond to market instability could meaningfully be construed as sectoral-level capability. We aim to demonstrate how history can be mobilised in a formalised “strategy text” to create a strategic narrative on the sectoral level. The Geography of Contractors as published by the Turkish Contractors Association (TCA) ostensively portrays the strategic development of Turkish international contractors over four decades. Such quasi-historical narratives are routinely mobilised for the purposes of creating a shared memory on the sectoral level. The chosen strategy text draws from multiple narrative fragments derived from past experience to generate a strategic agenda for the future. The representation given to multiple voices reflects the pluralistic nature of strategy making praxis. The overarching strategy narrative reflects a performative intent in legitimising some practices whilst discrediting others. Narrative analysis demonstrates the way in which actors, actions and events are positioned within a plot structure, with direct implications for the enactment of future strategic practices. The findings suggest that strategic actions can only ever be identified in retrospect and that such arguments are always made with an eye on the future.     

Investigating the effect of production process of ball mill refiner on some physical quality parameters of compound chocolate: response surface methodology approach

Chocolate compound was produced using ball mill refiner, and the effect of agitator shaft speed and refining time on the physical quality parameters (particle size, colour and steady‐state rheology) of compound chocolate was determined using response surface methodology. The shaft speed and refining time range were selected between 40–60 r.p.m. and 10–30 min, respectively. Determination coefficient of the models established for particle size, Newtonian viscosity and colour parameters (brightness, chroma and hue angle) were found to be very close to unity. Increasing shaft speed and time induced a reduction in particle size and an increase in viscosity of the samples. Temperature sweep test was also performed, and the obtained data were successfully fitted to Arrhenius equation to calculate the corresponding parameters representing temperature dependency of the compounds. The results highlighted that the establishment of such models can provide essential information in terms of optimisation of production processes regarding usage purpose of the compound chocolate.