全文获取类型
收费全文 | 427篇 |
免费 | 52篇 |
国内免费 | 1篇 |
专业分类
电工技术 | 4篇 |
综合类 | 1篇 |
化学工业 | 119篇 |
金属工艺 | 13篇 |
机械仪表 | 21篇 |
建筑科学 | 7篇 |
能源动力 | 10篇 |
轻工业 | 24篇 |
石油天然气 | 1篇 |
武器工业 | 2篇 |
无线电 | 75篇 |
一般工业技术 | 118篇 |
冶金工业 | 5篇 |
原子能技术 | 7篇 |
自动化技术 | 73篇 |
出版年
2023年 | 4篇 |
2022年 | 2篇 |
2021年 | 16篇 |
2020年 | 13篇 |
2019年 | 18篇 |
2018年 | 17篇 |
2017年 | 15篇 |
2016年 | 24篇 |
2015年 | 22篇 |
2014年 | 34篇 |
2013年 | 34篇 |
2012年 | 35篇 |
2011年 | 41篇 |
2010年 | 31篇 |
2009年 | 29篇 |
2008年 | 20篇 |
2007年 | 14篇 |
2006年 | 11篇 |
2005年 | 17篇 |
2004年 | 17篇 |
2003年 | 19篇 |
2002年 | 16篇 |
2001年 | 6篇 |
2000年 | 6篇 |
1999年 | 6篇 |
1998年 | 4篇 |
1997年 | 2篇 |
1993年 | 2篇 |
1991年 | 1篇 |
1989年 | 1篇 |
1988年 | 1篇 |
1987年 | 1篇 |
1985年 | 1篇 |
排序方式: 共有480条查询结果,搜索用时 15 毫秒
1.
2.
Hydrogen is considered to be the most important future energy carrier in many applications reducing significantly greenhouse gas emissions, but the safety issues associated with hydrogen applications need to be investigated and fully understood to be applicable as the carrier. Generally, the locations of hydrogen production and consumption are different. Hydrogen must be transported from the point of production to the point of use. Pipeline delivery is cheaper than all other methods for large quantities of hydrogen. The rupture of a hydrogen pipeline can lead to outcomes that can pose a significant threat to people and property in the immediate vicinity of the failure point. In this work, a simplified equation of hazard analysis is proposed for the pipeline transporting hydrogen, which relates the diameter, the operating pressure and the length of the pipeline to the size of the affected area in the event of a failure of the pipeline. The dominant hazards are thermal radiation from sustained fire and shock pressure from gas cloud explosion. For a transmission pipeline of hydrogen gas, the hazard area from the fire is slightly larger than by the other event. The hazard area is directly proportional to the operating pressure raised to the power one-half, and to the pipeline diameter. This simplified equation to estimate the hazard area will be a useful tool for safety management of hydrogen gas transmission pipelines. 相似文献
3.
Seung Bum Kil Yannick Augros Yves Leterrier Jan‐Anders E. Mnson Andreas Christel Camille Borer 《Polymer Engineering and Science》2003,43(2):329-343
The rheological properties in solution, in shear and in uniaxial elongation of poly(ethylene terephthalate) (PET) reacted together with hyperbranched polymers (HBPs) were investigated. Two different PET grades, of low and high molecular weights, were compounded with sub‐ to over‐stoichiometric concentrations of HBPs of second and fourth pseudo‐generation, and subsequently subjected to a solid‐state polycondensation (SSP). The formation of microgels, which occurs at high HBP concentration, gave rise to a large increase in melt elasticity and a related decrease in melt strength. At low HBP concentrations, the complex viscosity of the unreacted HBP/PET was considerably reduced, thus demonstrating a lubrication effect of the HBP molecules. During SSP, the intrinsic and shear viscosities exhibited a gradual increase, which was similar for both PET and HBP/PET blends, and was correlated to an increase in molecular weight, through linear‐chain extension and branching reactions. The elongational viscosity of the reactive blends was also increased as a function of reaction time, and this increase was much larger in the case of the HBP/PET blends. A 400% increase in melt strength of the PET was obtained by combining SSP and trace amounts of an HBP of second generation, without any decrease in drawability. 相似文献
4.
Yong?An?Jung Du?Young?Choi Seung?Bum?Hong Kyung?Ho?RowEmail author 《Korean Journal of Chemical Engineering》2003,20(4):705-708
Reversed-phase high-performance liquid chromatography was successfully developed for the simultaneous and rapid separation for the main whey proteins, α-Lactalbumin and β-Lactoglobulin. This method consisted of a linear gradient of the two mobile phases of 0.1% trifluoroacetic acid in water and 0.1% trifluoroacetic acid in acetonitrile. The total run time for this separation was approximately 30 min, and α-Lactalbumin was eluted followed byβ- Lactoglobulin. The injection volume was fixed at 20 μl and the flow rate was 1 ml 1/min. The optimum mobile phase composition and gradient conditions to separate α-Lactalbumin and β-Lactoglobulin (A+B) were experimentally obtained at the 15 μm particle with a pore size of 300 Å on the linear-gradient mode. 相似文献
5.
Min Jeong Kim Mina Choi Yong Bum Kim Fengyi Liu Hyungpil Moon Ja Choon Koo Hyouk Ryeol Choi 《International Journal of Control, Automation and Systems》2014,12(2):406-414
This paper proposes a method of exploring the local shape of an unknown object using the force and torque information obtained from active touch. In the first, we present a method to estimate an unknown curvature, using rolling and sliding motion with a force/torque sensor attached to the fingertip of the hand. Then, the normal curvature equation from 2D curvatures is obtained. Finally we present a reconstruction algorithm of local geometry by using a normal curvature equation, which is composed of principal curvatures and principal directions. The method is tested by using a hand-arm system consisting of an industrial robot arm and an anthropomorphic robot hand with 6-axis force/torque sensor. The feasibility of the proposed method is experimentally validated for objects with simple geometries such as cylinder, spheres etc. 相似文献
6.
The removal of hydrogen sulfide (H2S) from simulated gas was carried out in a batch type fluidized-bed reactor using natural manganese ore (NMO), which consists
of several metal oxides (MnOx: 51.85%, FeOy: 3.86%, CaO: 0.11%). The H2S breakthrough curves were obtained by changing temperature, gas velocity, initial H2S concentration, and aspect ratio. Moreover, the effects of the particle size and the particle-mixing fraction on H2S removal were investigated in a binary system of different particle size. From this study, H2S removal efficiency increased with increasing temperature but decreased with increasing excess gas velocity. The breakthrough
time for H2S decreased as the gas velocity increased, which leads to reducing gas-solid contacting due to gas bypassing in a fluidized
bed reactor. Improvement of H2S removal efficiency in continuous process can be expected from the results of the binary particle system with different size
in a batch experiment. The NMO could be considered as a potential sorbent in H2S removal. 相似文献
7.
Geun Bum Koo Jin Bae Park Young Hoon Joo 《International Journal of Control, Automation and Systems》2013,11(6):1075-1083
In this paper, a novel intelligent digital redesign (IDR) technique using the guaranteed cost control method is proposed for nonlinear systems which can be represented by a Takagi-Sugeno (T-S) fuzzy model. The IDR technique, which is one of the sampled-data fuzzy controller design methods, guarantees not only the stability condition of the sampled-data closed-loop system with the sampleddata fuzzy controller and the state-matching error is presented. By using the concept of the guaranteed cost control method, sufficient conditions are obtained for both minimization of the state-matching error and stabilization of the sampled-data closed-loop system and derived in terms of linear matrix inequalities (LMIs). Finally, a numerical example is provided to verify the effectiveness of the proposed technique. 相似文献
8.
Dohyung Kim Hyeonsu Bang Hyoung Won Baac Jongmin Lee Phuoc Loc Truong Bum Ho Jeong Tamilselvan Appadurai Kyu Kwan Park Donghyeok Heo Vu Binh Nam Hocheon Yoo Kyeounghak Kim Daeho Lee Jong Hwan Ko Hui Joon Park 《Advanced functional materials》2023,33(14):2213064
Reversible metal-filamentary mechanism has been widely investigated to design an analog resistive switching memory (RSM) for neuromorphic hardware-implementation. However, uncontrollable filament-formation, inducing its reliability issues, has been a fundamental challenge. Here, an analog RSM with 3D ion transport channels that can provide unprecedentedly high reliability and robustness is demonstrated. This architecture is realized by a laser-assisted photo-thermochemical process, compatible with the back-end-of-line process and even applicable to a flexible format. These superior characteristics also lead to the proposal of a practical adaptive learning rule for hardware neural networks that can significantly simplify the voltage pulse application methodology even with high computing accuracy. A neural network, which can perform the biological tissue classification task using the ultrasound signals, is designed, and the simulation results confirm that this practical adaptive learning rule is efficient enough to classify these weak and complicated signals with high accuracy (97%). Furthermore, the proposed RSM can work as a diffusive-memristor at the opposite voltage polarity, exhibiting extremely stable threshold switching characteristics. In this mode, several crucial operations in biological nervous systems, such as Ca2+ dynamics and nonlinear integrate-and-fire functions of neurons, are successfully emulated. This reconfigurability is also exceedingly beneficial for decreasing the complexity of systems—requiring both drift- and diffusive-memristors. 相似文献
9.
Photonic Reactions Leading to Fluorescence in a Polymeric System Induced by the Photothermal Effect of Magnetite Nanoparticles Using a 780 nm Multiphoton Laser 下载免费PDF全文
Bum Chul Park Hee‐Dae Kim June Park Yu Jin Kim Young Keun Kim 《Small (Weinheim an der Bergstrasse, Germany)》2017,13(37)
Recently, polymer‐coated magnetite (Fe3O4) nanoparticles (NPs) are extensively studied for applications in therapeutics or diagnostics using photothermal effect. Therefore, it is essential to understand the interactions between Fe3O4 NPs and polymers when optical stimuli are applied. Herein, the photonic reactions of Fe3O4 NPs and polymer composites upon application of a 780 nm multiphoton laser are analyzed. The photonic reactions produce unique results including fluorescence from conformationally changed polymer and low‐temperature phase transformation of Fe3O4 NPs. Typically, π‐conjugated chains are formed, inducing fluorescence through a series of main and side‐chain cleavage reactions of polymers with the aliphatic chain. In addition, fluorescence is detected in the cellular system by photonic reactions between Fe3O4 NPs and biomolecules. After multiphoton laser irradiation, light emission is detected near the intracellular Fe3O4 NPs, and a stronger intensity is observed in large‐sized NPs. 相似文献
10.
Dominance of Plasmonic Resonant Energy Transfer over Direct Electron Transfer in Substantially Enhanced Water Oxidation Activity of BiVO4 by Shape‐Controlled Au Nanoparticles 下载免费PDF全文
Mi Gyoung Lee Cheon Woo Moon Hoonkee Park Woonbae Sohn Sung Bum Kang Sanghan Lee Kyoung Jin Choi Ho Won Jang 《Small (Weinheim an der Bergstrasse, Germany)》2017,13(37)
The performance of plasmonic Au nanostructure/metal oxide heterointerface shows great promise in enhancing photoactivity, due to its ability to confine light to the small volume inside the semiconductor and modify the interfacial electronic band structure. While the shape control of Au nanoparticles (NPs) is crucial for moderate bandgap semiconductors, because plasmonic resonance by interband excitations overlaps above the absorption edge of semiconductors, its critical role in water splitting is still not fully understood. Here, first, the plasmonic effects of shape‐controlled Au NPs on bismuth vanadate (BiVO4) are studied, and a largely enhanced photoactivity of BiVO4 is reported by introducing the octahedral Au NPs. The octahedral Au NP/BiVO4 achieves 2.4 mA cm?2 at the 1.23 V versus reversible hydrogen electrode, which is the threefold enhancement compared to BiVO4. It is the highest value among the previously reported plasmonic Au NPs/BiVO4. Improved photoactivity is attributed to the localized surface plasmon resonance; direct electron transfer (DET), plasmonic resonant energy transfer (PRET). The PRET can be stressed over DET when considering the moderate bandgap semiconductor. Enhanced water oxidation induced by the shape‐controlled Au NPs is applicable to moderate semiconductors, and shows a systematic study to explore new efficient plasmonic solar water splitting cells. 相似文献