Efficient conversion of light paraffinic naphtha to aromatics over metal-modified Mo/MFI catalysts

Journal of Porous Materials - The transformation of light naphtha to value-added aromatic compounds is gaining momentum in the petrochemical industry. In this work, a series of metal modified...     

Formulation and in vitro Evaluation of pH-Sensitive Cross-linked Xanthan Gum-Grafted Acrylic Acid Copolymer for Controlled Delivery of Perindopril Erbumine (PE)

A novel xanthan gum-co-acrylic acid superabsorbent hydrogel composite was formulated by free radical polymerization reaction of acrylic acid on xanthan gum. Effect of variables like dynamic swelling ratio, equilibrium swelling ratio, drug loading and drug release was investigated. Swelling ratio increases with decrease in crosslinker concentration. Drug release studies were conducted in pH 7.4 and 0.1N HCl. In acidic environment, drug release was low whereas it was sustained release in alkaline. XG4 showed significant swelling and drug release up to 24?hr. Physicochemical evaluation also confirmed it was optimized formulation. Hence XG4-co-AA was optimized for once daily dose of Perindopril Erbumine.     

Influence of Chemical Reaction on Mass Transport in Yield Stress Exhibiting Flow Regime

Theoretical Foundations of Chemical Engineering - In this study, the simulations for first-order chemical reactions (constructive and destructive) in the flow of the Casson fluid with...     

Fatigue assessment of high‐frequency mechanical impact (HFMI)‐treated welded joints subjected to high mean stresses and spectrum loading

The fatigue strength of welded joints can be improved with various post‐weld treatment methods. High‐frequency mechanical impact treatment is a residual stress modification technique that creates compressive residual stresses at the weld toe. However, these beneficial residual stresses may relax under certain loading conditions. In this paper, previously published fatigue data for butt and fillet welded joints subjected to high stress ratios and variable amplitude cyclic stresses were evaluated in relation to the current International Institute of Welding (IIW) recommendations on fatigue strength improvement and a proposed IIW design guideline for high‐frequency mechanical impact‐treated welded joints. The evaluation showed that the current IIW recommendations resulted in both non‐conservative and overly conservative fatigue strength estimations depending on the applied stress level, whereas the proposed fatigue assessment guideline fitted the current data well.     

Comparison of chlorination and chloramination practices on microbial inactivation efficiencies within a scaled‐up water distribution network using central composite design

Disinfection practices reduce the incidence of water‐borne diseases but may result in formation of disinfection byproducts (DBPs) in raw water that are reported to be carcinogenic. Central composite design (CCD) was employed in the present study for optimization of disinfectant dose and contact time with the rationale to evaluate if an optimal balance could be achieved between minimal DBPs formation and effective microbial inactivation with either free or combined chlorine in treated water within a lab‐scale prototype network to simulate real water distribution network conditions. After a series of experimental runs based upon design of experiments (DoE) by CCD, dose was found to be the most significant factor (P < 0.01) in determining DBPs formation in both disinfectant’s applications. Where, contact time significantly (P < 0.01) affected bacterial inactivation in chlorination experiments, in contrast, dose was effective in chloramination experiments. Thus, it was concluded that the optimal balance may be achieved in the water networks with the help of multifactorial optimization when disinfectant dose was maintained near 3 mg/L as applied chlorine dose in both disinfection cases, while contact time was 62 and 155 min for chlorine and chloramine, respectively.     

Edge-Node-Aware Adaptive Data Processing Framework for Smart Grid

Wireless Personal Communications - Smart grid is an autonomous power generation and production system, that includes various energy management sub-systems such as energy efficient resources, smart...     

Storage and permeation of hydrogen molecule,atom and ions (H+ and H−) through silicon carbide nanotube; a DFT approach

The barriers for the encapsulation and decapsulation of hydrogen ions (cationic hydrogen and hydride), atom, and molecule through silicon carbide nanotube are thoroughly studied. DFT method is selected to measure the kinetic barriers for the passage of hydrogen atom, ions and molecule through nanotube via scanning potential energy surface. The kinetic barriers for the passage (encapsulation and decapsulation) of hydrogen are very important to understand the mechanism of hydrogen storage and release. The barriers for the permeation of H, H⁺ and H^? across SiC nanosheet are lower compared to hydrogen molecule (H₂). The exohedral and endohedral adsorption of hydrogen ions (cation and anion), atom and exohedral hydrogen molecule on silicon carbide are exothermic in nature. Whereas the encapsulation of hydrogen molecule in silicon carbide is endothermic. Electronic properties are analyzed through measurement of energy gap between highest occupied and lowest unoccupied molecular orbitals gap (G_H-L) and the density of state (DOS) spectra. The G_H-L analysis reveals that endohedral complexes have more pronounced effect on electronic properties compared to exohedral complexes. The SiC nanotube has highly favorable properties for storage and release of hydrogen ions, and atom.     

Hybrid model of content extraction

We present a hybrid model for content extraction from HTML documents. The model operates on Document Object Model (DOM) tree of the corresponding HTML document. It evaluates each tree node and associated statistical features like link density and text distribution across the node to predict significance of the node towards overall content provided by the document. Once significance of the nodes is determined, the formatting characteristics like fonts, styles and the position of the nodes are evaluated to identify the nodes with similar formatting as compared to the significant nodes. The proposed hybrid model is derived from two different models, i.e., one is based on statistical features and other on formatting characteristics and achieved the best accuracy. We describe the validity of model with the help of experiments conducted on the standard data sets. The results revealed that the proposed model outperformed other existing content extraction models. We present a browser based implementation of the proposed model as proof of concept and compare the implementation strategy with various state of art implementations. We also discuss various applications of the proposed model with special emphasis on open source intelligence.     

Effect of cellulosic sugar degradation products (furfural and hydroxymethyl furfural) on acetone–butanol–ethanol (ABE) fermentation using Clostridium beijerinckii P260

Studies were performed to identify chemical compounds present in wheat straw hydrolysate (WSH) that enhance acetone butanol ethanol (ABE) productivity. These compounds were identified as furfural and hydroxymethyl furfural (HMF). Control experiment resulted in the production of 21.38 g L^?1 ABE with a productivity of 0.30 g L^?1 h^?1. WSH contained 0.04–0.34 g L^?1 furfural and 0.12–0.88 g L^?1 HMF. Addition of furfural to the fermentation medium at a concentration of 0.50 g L^?1 resulted in a productivity of 0.88 g L^?1 h^?1 which is 293% of the productivity obtained in control experiments. Supplementation with 1.00 g L^?1 HMF into the fermentation medium produced 25.27 g L^?1 ABE with a productivity of 0.68 g L^?1 h^?1. A combination of furfural (0.50 g L^?1) and HMF (0.50 g L^?1) also enhanced ABE production and productivity when added to the fermentation medium. Both furfural and HMF enhanced specific productivity (233–308%) of ABE. In brief, WSH contained an adequate concentration of furfural and HMF that enhanced ABE productivity, specific productivity, and product concentration.