Effect of Co addition on microstructural and mechanical properties of WC–B4C–SiC composites

In this study, the effect of Co addition on microstructural and mechanical properties of WC-B₄C–SiC composites sintered by spark plasma sintering (SPS) method was investigated. For this purpose, three batches of WC-B₄C–SiC with different contents of Co (10 vol%, 15 vol%, and 20 Vol %) were sintered at 1400 °C. The results of X-ray diffraction (XRD) analysis of the samples indicated the formation of W₂B₅, W₃CoB₃ as well as the remained C phases and unreacted SiC phase. It was observed that by increasing the Co content, the amount of W₂B₅ phase reduces and W₃CoB₃ and C contents increase. Therefore, W₂B₅ peaks were not detected in the sample containing 20vol% Co. Relative density values above 97% were obtained for all the composites. However, a decrease was observed in relative density by increasing the Co content in the composites. The highest flexural strength (510 ± 42 MPa), fracture toughness (10.34 ± 0.82 MPa m^1/2), and hardness (20.63 ± 0.75 GPa) were also obtained for the sample containing 10vol% Co compared to the other samples. In addition, Transgranular fracture of SiC as well as pulling out of W₃CoB₃ and W₂B₅ particles were observed in the fracture surface micrographs of the samples. The presence of micro-cracks in the SiC grains, fracture of W₃CoB₃ grains, and crack deflection was reported as dominant toughening mechanisms.     

Structural,ferroelectric, magnetic and magnetoelectric properties of (1-x) Ba0.85Ca0.15Zr0.1Ti0.9O3 -x La0.67Sr0.33MnO3 lead-free magnetoelectric composites

The influence of an additional La_0.67Sr_0.33MnO₃ (LSMO) magnetic phase on the structural, ferromagnetic, ferroelectric, and magnetoelectric properties of Ba_0.85Ca_0.15Zr_0.1Ti_0.9O₃ (BCZT) ferroelectric phase was studied for composites of (1-x)BCZT -xLSMO (x = 0, 25, 50, 75 and 100%). The ferroelectric BCZT sample showed a perovskite single phase formation with a tetragonal crystal structure of the P4mm space group, and the magnetic phase of LSMO presented a rhombohedral crystal structure of R3c space group as shown by XRD. The composite sample with 25% LSMO exhibited large ferroelectric and piezoelectric properties with remnant, saturation polarization, and coercive electric field P_r ~7.74 μC/cm², P_s ~11.69 μC/cm² and E_C ~12.22 kV/cm with a piezoelectric coefficient d₃₃ ~ 231 pC/N. The magnetic characterization for the composites showed that the sample containing 75% of LSMO revealed the highest remnant, saturation magnetization, and coercive field of M_r ~1.358 emu/g, M_s ~19.17 emu/g, and H_C ~33.19 Oe, respectively. Moreover, it revealed the largest magnetoelectric coupling coefficient α_ME ~2.51 mV/cm.Oe with high coupling quality at a lower applied magnetic field. The results highlight the value of these composites as lead-free room temperature magnetoelectric sensors and actuators.     

In vitro evaluation and in vivo performance of lyophilized gliclazide

Enhancement of the dissolution rate of the poorly water-soluble hypoglycemic agent, gliclazide, by the aid of lyophilization was investigated. Mannitol, sodium lauryl sulfate (SLS) and polyvinyl pyrrolidone (PVP-k-30) were employed in different weight ratios (43%, 56% and 64% w/w, respectively) as water-soluble excipients in the formulation. Lyophilized systems were found to exhibit extremely higher in vitro dissolution rate compared to the unprocessed drug powder. Solid state characterization of the lyophilized systems using X-ray powder diffraction, Fourier transform infrared spectroscopy and differential scanning calorimetry techniques revealed that dissolution enhancement was attributable to transformation of gliclazide from the crystalline to an amorphous state in the solid dispersion formed during the lyophilization process. The gastrointestinal absorption and hypoglycemic effect of the lyophilized gliclazide/SLS system were investigated following oral administration to Albino rabbits. C_max and area under the plasma concentration–time curve of gliclazide (AUC_0–12) after administration of the lyophilized formulations were significantly higher than those obtained after administration of the unprocessed gliclazide.     

Assessment of Mineralogical,Textural, and Water Chemistry Changes During Long-Distance Tailings-Slurry Transport

An exploratory study demonstrated that subtle changes in solids and process water were caused by long-distance turbulent transport of tailings from the concentrator to the impoundment of a Cu (Mo) porphyry copper deposit. Slurry water chemical analysis was complemented by modelling potential phase precipitation or dissolution and speciation of dissolved metals. It was found that transport did not affect major insoluble mineral phases. However, the degrees of liberation of several phyllosilicates, as determined by automated mineralogy, were reduced close to the impoundment, which points to separation of clay particles from tectosilicate surfaces by the turbulence; this also was observed by SEM examination of micro-aggregate specimens. Reduction of maximum particle sizes, increased N2 monolayer adsorption, and resultant specific surface areas indicate that transport modified the micro-aggregates. Major element water chemistry is controlled by the presence of soluble mineral phases, such as gypsum, and reagents, such as lime, in the flotation process. Changes in the dissolved concentrations of some elements could potentially affect tailings deportment in the impoundment. Increased concentrations of Al may affect the clay settling behaviour, while Mo and As levels will require treatment prior to the discharge of water from the tailings impoundment. This study demonstrated that systematic scrutiny of tailings slurries leaving the concentrator and before entering the impoundment can be potentially useful, though care will have to be exercised to replicate sample handling and analytical conditions, during any long-term monitoring.     

Effect of cellulose acetate/cellulose triacetate ratio on reverse osmosis blend membrane performance

Surface functionalization and modification including the grafting process are effective approaches to improve and enhance the reverse osmosis (RO) membrane performance. This work is aimed to synthesize grafted/crosslinked cellulose acetate (CA)/cellulose triacetate (CTA) blend RO membranes using N-isopropylacrylamide (N-IPAAm) as a monomer and N,N-methylene bisacrylamide (MBAAm) as a crosslinker. The morphology of these membranes was analyzed by scanning electron microscopy and their surface roughness was characterized by atomic force microscopy. The performance of these membranes was evaluated through measuring two major parameters of salt rejection and water flux using RO unit at variable operating pressures. It was noted that the surface average roughness obviously decreased from 148 nm for the pure CA/CTA blend membrane with 2.5% CTA to 110 nm and 87 nm for the grafted N-IPAAm and grafted/crosslinked N-IPAAM/MBAAm/CA/CTA-RO membranes, respectively. Moreover, the contact angle decreased from 51.98° to 47.6° and 43.8° after the grafting and crosslinking process. The salt rejection of the grafted CA/CTA-RO membrane by 0.1% N-IPAAm produced the highest value of 98.12% and the water flux was 3.29 L/m²h at 10 bar.     

Silicon Nanoparticles Produced by Two-Step Nanosecond Pulsed Laser Ablation in Ethanol for Enhanced Blue Emission Properties

In this work, we introduce a facile method of laser ablation to synthesize silicon rich oxide nanoparticles colloid with blue-green emissions. The method includes a two-step nanosecond pulsed laser ablation of silicon in ethanol. First, the micro-porous layer is formed on the silicon surface by laser ablation of the target, followed by ablating the oxidized micro-porous silicon to prepare the nanoparticles dispersed in ethanol. The nanoparticles interface structure exhibit the crystalline of quartz and non-stoichiometric oxide in suboxide phase of the SiO1.5 as examined by Fourier transform infrared spectroscopy, UV-vis spectrophotometry and X-ray diffraction pattern. Study of the colloid photoluminescence properties reveals that the coupling of silicon nanocrystals and interfacial states may play important role in the blue emission mechanism of the colloid. Our results support that the radiative recombination at the interfacial localized states of Si/SiO1.5 can easily occur in the colloid resulting the blue emission peak at the wavelength of 425 nm. In other words, a more effective pathway is provided for excited electrons in the colloid including occurrence of excitations in silicon nanocrystal states and emission in the interfacial states. This method avoids any toxic by-product during the synthesis of colloid and can be used for the commercial-scale production of silicon nanoparticles as the blue emission material.     

A systematic review and meta-analysis of artificial neural network application in geotechnical engineering: theory and applications

Artificial neural network (ANN) aimed to simulate the behavior of the nervous system as well as the human brain. Neural network models are mathematical computing systems inspired by the biological neural network in which try to constitute animal brains. ANNs recently extended, presented, and applied by many research scholars in the area of geotechnical engineering. After a comprehensive review of the published studies, there is a shortage of classification of study and research regarding systematic literature review about these approaches. A review of the literature reveals that artificial neural networks is well established in modeling retaining walls deflection, excavation, soil behavior, earth retaining structures, site characterization, pile bearing capacity (both skin friction and end-bearing) prediction, settlement of structures, liquefaction assessment, slope stability, landslide susceptibility mapping, and classification of soils. Therefore, the present study aimed to provide a systematic review of methodologies and applications with recent ANN developments in the subject of geotechnical engineering. Regarding this, a major database of the web of science has been selected. Furthermore, meta-analysis and systematic method which called PRISMA has been used. In this regard, the selected papers were classified according to the technique and method used, the year of publication, the authors, journals and conference names, research objectives, results and findings, and lastly solution and modeling. The outcome of the presented review will contribute to the knowledge of civil and/or geotechnical designers/practitioners in managing information in order to solve most types of geotechnical engineering problems. The methods discussed here help the geotechnical practitioner to be familiar with the limitations and strengths of ANN compared with alternative conventional mathematical modeling methods.

     

Magnetic micropolar nanofluids flow in double lid-driven enclosures using two-energy equation model

Impacts of an inclined electromagnetic force on a mixed convective process in two-sided lid-driven geometries using the two-energy equation model are examined in this study. The flow domain is filled by a porous medium and the local thermal nonequilibrium model is applied. Magnetic micropolar nanofluids are assumed as working fluids consisting of water as a base fluid and CuO as nanoparticles. The forced convection situation is due to the moving of the upper and lower walls in the right direction with a constant velocity. The used methodology depends on the finite volume method, together with the SIMPLE algorithm. The obtained outcomes are visualized using contours of the streamlines, isotherms for the nanofluid phase, isotherms for the solid phase, and angular velocity. The main findings revealed that the increase in lengths of the heated parts and the Nield number reduces the Nusselt number for the nanofluid phase. Also, the average heat transfer rate for the nanofluid and solid phases are boosted with the increase in the vortex viscosity.     

Water Conflict Management between Agriculture and Wetland under Climate Change: Application of Economic-Hydrological-Behavioral Modelling

Water Resources Management - Water resources at the basin level are affected by climate change in the form of available water scarcity and multiple droughts leading to conflicts among different...     

Passage of selected heavy metals from Sphaerotilus (bacteria: chlamydobacteriales) to Paramecium caudatum (protozoa: ciliata)

Sphaerotilus, a bacterium occurring in polluted waters, was found to take up Zn, Pb, Ni and Mn. Metal-containing cultures of this bacterium were employed to feed the protozoan Paramecium caudatum, and analytical results revealed the accumulation of Zn, Pb and Ni. Since Sphaerotilus was the only food source for paramecia during this study, the results indicate that trace amounts of metals were passed from bacteria to protozoa in a predator-prey relationship.