Experimental and Numerical Investigation of Airflow Inside Refrigerated Shipping Containers

During transportation of fruits and vegetables, factors such as temperature, air exchange, humidity levels, packaging design and stacking arrangements in the reefer (refrigerated shipping container) are extremely important to maintain the cold chain. In this study, the airflow distribution inside two types of refrigerated shipping containers (T-bar floor and flat floor) used for transporting fresh fruit handling were investigated. Computational fluid dynamics (CFD) model of airflow was developed and experimentally validated. Measurements of air velocities were taken from 222 sample positions inside a full-size reefer. The validated model was then implemented to study the effects of container designs and operational conditions on airflow pattern and distribution. High and low evaporator speed scenarios of the two reefer designs (T-bar floor and flat floor) were investigated. The result showed that airflow distribution in the two container designs were markedly different. Good agreement was found between measured and predicted values of air velocities. The air exchange rate in the rear part of the reefers for the two designs were compared. For the flat floor reefer, the air exchange was 0.2 m³ h^?1 while for the T-bar floor, it was 0.6 m³ h^?1. Also, in the primary recirculation region, (between 3 and 8 m from the inlet side) the average vertical air velocity was higher in the T-bar floor reefer (0.04 m s^?1) than in the flat floor reefer (0.01 m s^?1). As a result, reefer with T-bar floor design exhibited a noticeable reduction of air recirculation zone and enhanced uniform vertical air movement compared to the reefer with flat floor design.     

Modeling the diffusion-adsorption kinetics of 1-methylcyclopropene (1-MCP) in apple fruit and non-target materials in storage rooms

The purpose of this research was to model the kinetics of adsorption of 1-methylcyclopropene (1-MCP) in apple fruit and non-target solid materials found in apple storage rooms. The process was described by Fick’s second law of diffusion of the gas through the pores of the material coupled with adsorption kinetics of the gas on the material’s binding sites. A finite element formulation of the model, describing the diffusion and adsorption mechanisms separately, was first developed. The values of the relevant parameters were estimated based on headspace measurements of the decrease of 1-MCP in jars containing the different materials. The headspace concentration of 1-MCP was measured using gas chromatography. Apple fruit (Golden Delicious and Jonagold) and the following bin construction materials were investigated: high density polyethylene (HDPE), oak, poplar wood and card lining. The range in the magnitude of the diffusion coefficient, adsorption coefficient, and concentration of active sites in the various solids was 10,000-, 8-, and 30-fold, respectively.     

Bankruptcy to Surplus: Sharing Transboundary River Basin’s Water under Scarcity

In this article a three-stage framework is proposed for allocating water and welfare in transboundary river basins under water scarcity. The proposed allocation framework combines the bargaining theory with resource allocation and bankruptcy games. The water bankrupt Euphrates River was taken as a case study to demonstrate the applicability of the allocation framework. The results showed that the total monetary welfare that can be generated by reallocating the water in order of decreasing water productivity value of each riparian country is greater by 43.43% of total monetary warfare that can be made if each country were to utilize the water allocated to it independently. The proposed allocation framework rewarded Turkey, Syria and Iraq with welfare assignments which are 41.5%, 42.1% and 57.45% greater than what they could have achieved by unilaterally utilizing the water allocated to them. Generally, the proposed water allocation, water reallocation and welfare assignment framework provide some insights for allocating transboundary water in a way which is efficient, fair and sustainable.     

Lead-free Solders in Microelectronics

Practically all microelectronic assemblies in use today utilize Pb–Sn solders for interconnection. With the advent of chip scale packaging technologies, the usage of solder connections has increased. The most widely used Pb–Sn solder has the eutectic composition. Emerging environmental regulations worldwide, most notably in Europe and Japan, have targeted the elimination of Pb usage in electronic assemblies, due to the inherent toxicity of Pb. This has made the search for suitable “Pb-free” solders an important issue for microelectronics assembly. Approximately 70 Pb-free solder alloy compositions have been proposed thus far. There is a general lack of engineering information, and there is also significant disparity in the information available on these alloys. The issues involved can be divided into two broad categories: manufacturing and reliability/performance. A major factor affecting alloy selection is the melting point of the alloy, since this will have a major impact on the other polymeric materials used in microelectronic assembly and encapsulation. Other important manufacturing issues are cost, availability, and wetting characteristics. Reliability related properties include mechanical strength, fatigue resistance, coefficient of thermal expansion and intermetallic compound formation. The data available in the open literature have been reviewed and are summarized in this paper. Where data were not available, such as for corrosion and oxidation resistance, chemical thermodynamics was used to develop this information. While a formal alloy selection decision analysis methodology has not been developed, less formal approaches indicate that Sn-rich alloys will be the Pb-free solder alloys of choice, with three to four alloys being identified for each of the different applications. Research on this topic continues at the present time at a vigorous pace, in view of the imminence of the issue.     

Investigating the Effects of Table Grape Package Components and Stacking on Airflow, Heat and Mass Transfer Using 3-D CFD Modelling

The flow phenomenon during cooling and handling of packed table grapes was studied using a computational fluid dynamic (CFD) model and validated using experimental results. The effects of the packaging components (bunch carry bag and plastic liners) and box stacking on airflow, heat and mass transfer were analysed. The carton box was explicitly modelled, grape bunch with the carry bag was treated as a porous medium and perforated plastic liners were taken as a porous jump. Pressure loss coefficients of grape bunch with the carry bag and perforated plastic liners were determined using wind tunnel experiments. Compared with the cooling of bulk grape bunch, the presence of the carry bag increased the half and seven eighth cooling time by 61.09 and 97.34 %, respectively. The addition of plastic liners over the bunch carry bag increased the half and seven eighth cooling time by up to 168.90 and 185.22 %, respectively. Non-perforated liners were most effective in preventing moisture loss but also generated the highest condensation of water vapour inside the package. For perforated plastic liners, cooling with a high relative humidity (RH) air minimised fruit moisture loss. Partial cooling of the grape bunch inside the carry bag before covering it with a non-perforated plastic liner maintained the required high RH inside the package without condensation. The stacking of packages over the pallet affected the airflow pattern, the cooling rate and moisture transfer. There was a good agreement between measured and predicted results. The result demonstrated clearly the applicability of CFD models to determine optimum table grape packaging and cooling procedures.     

Growth of germanium–carbide thin film on crystal substrate

The formation of germanium-carbide in crystalline germanium substrate is studied using the perturbed γ–γ angular correlation (PAC) method. The growth of Ge–C micro-crystalline system in the host matrix was observed after annealing the sample above 450°C in vacuum. The Ge–C complexes have been detected at high dose carbon implantation in germanium (≥1 × 10¹⁵cm ⁻²). Information about the lattice locations of the carbon atoms in the host lattice can be obtained via the interaction between carbon atoms with unstable probe nucleus (¹¹¹In). Several carbon related complexes have been detected in this investigations which can be characterized by unique quadrupole interaction frequencies. The parameters of the hyperfine interactions drawn from the time spectra provide additional information about the formation of Ge–C system in germanium.