Effects of B2O3 addition on structural and dielectric properties of PVDF

α‐Crystalline form of PVDF doped with Boron oxide (B₂O₃₎ composite films were produced between 0.2 and 1% weight ratio via the casting procedure. This low‐level doping rate did not change the crystalline structure of PVDF; however, they increased the lower and upper glass transition temperatures, which are associated with the amorphous ratio of polymer. This increment was found to be the highest for the sample 0.8% B₂O₃‐doped PVDF as 25 and 9.7%, respectively. Because of the low specific volume occurred in the 0.8% doped sample, B₂O₃ molecules are closer to the side groups of PVDF and, therefore, the coordination bonds also occurred according to the interaction between them and as a result of this interaction a geometric deformation occurred on the morphology of B₂O₃. In consequence of this deformation, morphology of B₂O₃ gained net dipole moment and provided a contribution to the dipole moment density of the structure. Hence, higher dielectric constant values obtained than that of pure PVDF. At 1 kHz and 300 K, the real dielectric constant increased by 236% compared to that of pure PVDF. It was shown experimentally by the 0.8% doping level of B₂O₃ that decreasing porous and gap structure resulted a high dielectric constant. POLYM. ENG. SCI., 54:2536–2543, 2014. © 2013 Society of Plastics Engineers     

Textile supercapacitors‐based on MnO2/SWNT/conducting polymer ternary composites

This paper describes a simple and fast process for the fabrication of flexible and textile‐based supercapacitors. Symmetric electrodes made up of binder‐free ternary composites of manganese oxide (MnO₂) nanoparticles, single walled carbon nanotubes (SWNT) and a conducting polymer (either polyaniline (PANI) or poly(3,4‐ethylenedioxythiophene)–poly(styrenesulfonate) (PEDOT:PSS)) were layer‐by‐layer deposited onto cotton substrates by dip coating method. Solid‐state supercapacitor devices were assembled using a gel electrolyte. Specific capacitances of 294 F/g and 246 F/g were obtained for MnO₂/SWNT/PANI and MnO₂/SWNT/PEDOT:PSS ternary nanocomposite supercapacitors, respectively. Power densities for these supercapacitors were 746.5 W/kg and 640.5 W/kg for MnO₂/SWNT/PANI and MnO₂/SWNT/PEDOT:PSS, respectively. Good capacity retention (more than 70%) upon cycling over 1000 times was achieved for both electrode compositions. Supercapacitors demonstrated in this work would be well suited as disposable power sources for wearable and intelligent textiles. Copyright © 2015 John Wiley & Sons, Ltd.     

Sample Elimination for Generating Poisson Disk Sample Sets

In this paper we describe sample elimination for generating Poisson disk sample sets with a desired size. We introduce a greedy sample elimination algorithm that assigns a weight to each sample in a given set and eliminates the ones with greater weights in order to pick a subset of a desired size with Poisson disk property without having to specify a Poisson disk radius. This new algorithm is simple, computationally efficient, and it can work in any sampling domain, producing sample sets with more pronounced blue noise characteristics than dart throwing. Most importantly, it allows unbiased progressive (adaptive) sampling and it scales better to high dimensions than previous methods. However, it cannot guarantee maximal coverage. We provide a statistical analysis of our algorithm in 2D and higher dimensions as well as results from our tests with different example applications.     

Proposal of a mathematical model for describing magnetorheological fluid dynamic behavior

Journal of Mechanical Science and Technology - This study proposes a model for describing magnetorheological (MR) fluid dynamic behavior. Experimental research was conducted to validate the model...     

Using augmented reality technology in storytelling activities: examining elementary students’ narrative skill and creativity

The aim of the study was to examine the effects of augmented reality technology on stories in terms of narrative skill, story length and creativity and also to examine correlations between these variables. Posttest-only design with a nonequivalent group model was used. In this study, the sample consisted of 100 fifth-grade elementary students, comprising 46 boys and 54 girls. Purposive and convenience sampling methods were applied. For purposive sampling, the group’s ages, education levels, and experiences in storytelling activities were gathered, and for convenience sampling, easy access to schools was considered. As data collection tools, a suitable narrative scale was used which was found in the literature and creative story form was developed by the researcher. According to the findings, mean scores for all variables for the experimental group were higher than those for the control group. Also, a statistically significant mean difference was found between the experimental and control groups with regard to narrative skill, length of stories, and creativity in stories. In fact, a positive correlation was found between all variables. It is important to recognize when a technology is found to contribute positively to narrative skill and creativity in telling stories, and to ensure this technology is used. Determining correlation between these variables may provide a contribution to studies about evaluating the effect of the new technologies.     

Phenolic contents,antioxidant activities and potential bioaccessibilities of industrial pomegranate nectar processing wastes

Antioxidant potential and bioaccessibility of co‐products from industrial pasteurised pomegranate nectar (PN) processing such as peel (PP), press cake (PC) and precipitate after clarification (PAC) in comparison with raw material (arils) and final products (CON and PN) were determined. Total phenolic (TPC), flavonoid (TFC), anthocyanin (TAC), tannin contents (TTC) and antioxidant activity (TAA) were determined besides identifying major phenolics and investigating in vitro bioaccessibility after gastrointestinal (GI) digestion. PP showed the highest values, except for TAC. Phenolics (12.7–43.0%) were found to be more stable than anthocyanins (0.6–2.1%) after in vitro GI digestion. PAC was found to be a better source for anthocyanins than CON and also showed higher phenolic bioaccessibility (28.8%) than PN (19.6%). PC and PAC possessed as much TPC, TFC, TTC and TAA levels as CON, with some exceptions. Therefore, these results indicated that not only PP but also PC and PAC should be valorised as a good source for phenolics and anthocyanins.     

Using directionality in mobile routing

The increased usage of directional methods of communications has prompted research into leveraging directionality in every layer of the network stack. In this paper, we explore the use of directionality in layer 3 to facilitate routing in highly mobile environments. We introduce Mobile Orthogonal Rendezvous Routing Protocol (MORRP) for mobile ad-hoc networks (MANETs). MORRP is a lightweight, but scalable routing protocol utilizing directional communications (such as directional antennas or free-space-optical transceivers) to relax information requirements such as coordinate space embedding, node localization, and mobility. This relaxation is done by introducing a novel concept called the directional routing table (DRT) which maps a set-of-IDs to each interface direction to provide probabilistic routing information based on interface direction. We show that MORRP achieves connectivity with high probability even in highly mobile environments while maintaining only probabilistic information about destinations. Additionally, we compare MORRP with various proactive, reactive, and position-based routing protocols using single omni-directional interfaces and multiple directional interfaces and show that MORRP gains over 10–14 × additional goodput vs. traditional protocols and 15–20% additional goodput vs. traditional protocols using multiple interfaces. MORRP scales well without imposing DHT-like graph structures (eg: trees, rings, torus etc). We also show that high connectivity can be achieved without the need to frequently disseminate node position resulting increased scalability even in highly mobile environments.     

Au/Porous silicon‐based sodium borohydride fuel cells

The Au/Porous silicon structure (Au/PS) was developed as hydrogen fuel cell. The use of a porous silicon filled with hydrochloric acid as a proton‐conducting membrane and thin gold film as a catalyst in Au/PS/Si fuel cell is demonstrated. The devices were fabricated by first creating 10–20 µm thick porous silicon layer by anodization etching in a standard silicon wafer and then depositing the gold catalyst film onto the porous silicon. Using sodium borohydride (NaBH₄) solution as the fuel, generation of the open‐circuit voltage of 0.55 V and the fuel cell peak power density of 13 mW cm⁻² at room temperature was achieved. Moreover production of hydrogen by evolution (out‐diffusion) of hydrogen from solid sodium borohydride during thermal annealing at 30–120°C was investigated. Data on the effective diffusion coefficient of the hydrogen in NaBH₄ were determined from intensity changes of infrared vibration peaks of B–H bond (2280 and 3280 cm⁻¹), as a result of thermal annealing of NaBH₄ samples. The relatively high values of the diffusion coefficient of hydrogen, increasing from 1×10⁻⁶ cm² s⁻¹ to 2×10⁻⁴ cm² s⁻¹ suggest that a thermo‐stimulated evolution process can be used for producing hydrogen from NaBH₄. Copyright © 2010 John Wiley & Sons, Ltd.     

Renewable energy sources for clean and sustainable energy policies in Turkey

Energy is an essential factor to achieve sustainable development. So, countries striving to this end are seeking to reassess their energy systems with a view towards planning energy programmes and strategies in line with sustainable development goals and objectives. As would be expected, the rapid expansion of energy production and consumption has brought with it a wide range of environmental issues at the local, regional and global levels. States have played a leading role in protecting the environment by reducing emissions of greenhouse gases. Turkey is an energy importing country with more than half of the energy requirement being supplied by imports, and air pollution is becoming a great environmental concern in the country. On the other hand, Turkey's geographical location has several advantages for extensive use of most of the renewable energy sources. In this regard, renewable energy resources appear the most efficient and effective solutions for clean and sustainable energy development in Turkey. This paper provides an overview of global energy use and renewables for clean and sustainable energy policies in Turkey.     

Gold recovery from dilute gold solutions using DEAE-cellulose

The present work investigates gold recovery using DEAE-cellulose, a common biopolymer derivative, from synthetically prepared diluted gold-bearing solutions of 50 ppm. The effects of different recovery parameters on gold recovery efficiency were studied in detail. It was demonstrated that gold recovery efficiency increased with an increasing amount of sorbent, as well as increasing contact time. A gold recovery efficiency of 99% was attained under conditions of 20–40 g DEAE-cellulose per liter at a shaking rate of 130 rpm for 30 min at room temperature. On the other hand, with smaller amounts of sorbent (6 g/l), it was also possible to recover gold from the solution with 99% efficiency when the reaction temperature was increased to 60 °C. The shaking rate and temperature were demonstrated to play a vital role in the recovery process. It was also found that gold recovery by DEAE-cellulose is an intermediate-controlled process with an activation energy of 37.11 kJ/mol. The XRD pattern and SEM images revealed that the recovered gold was in the metallic form.