Microstructure and mechanical behavior of laser aided additive manufactured low carbon interstitial Fe49.5Mn30Co10Cr10C0.5 multicomponent alloy

Laser aided additive manufacturing(LAAM)was used to fabricate bulk Fe49.5Mn30Co10Cr10C0.5 interstitial multicomponent alloy using pre-alloyed powder.The room temperature yield strength(σy),ultimate tensile strength(σUTS)and elongation(εUST)were 645 MPa,917 MPa and 27.0％respectively.The as-built sample consisted of equiaxed and dendritic cellular structures formed by elemental segregation.These cellular structures together with oxide particle inclusions were deemed to strengthen the material.The other contributing components include dislocation strengthening,friction stress and grain bound-ary strengthening.The high εUTS was attributed to dislocation motion and activation of both twinning and transformation-induced plasticity(TWIP and TRIP).Tensile tests performed at-40℃and-130℃demonstrated superior tensile strength of 1041 MPa and 1267 MPa respectively.However,almost no twinning was observed in the fractured sample tested at-40℃and-130℃.Instead,higher fraction of strain-induced hexagonal close-packed(HCP)ε phase transformation of 21.2％were observed for fractured sample tested at-40℃,compared with 6.3％in fractured room temperature sample.     

Fe3O4-carbon spheres core–shell supported palladium nanoparticles: A robust and recyclable catalyst for suzuki coupling reaction

Suzuki-Miyaura (S-M) is regarded the most powerful way for synthesis biaryls, triaryls, or incorporating of substituted aryl moieties in organic preparation by the cross-coupling of aryl boronic acid with aryl halides using the Pd catalyst. This work reports the combining of the hydrothermal and microwave-assisted protocol to convert the glucose to magnetic carbon spheres (Fe₃O₄-CSPs) decorated with Pd nanoparticles (NPs) as the catalyst for Suzuki-Miyaura cross-coupling reactions. The physicochemical properties in the produced composite were examined using FESEM, HRTEM, nitrogen isotherms, Raman spectroscopy, FTIR, XPS, and XRD. The as-fabricated composite Pd/Fe₃O₄-CSPs is mostly spherical with a core–shell structure and possesses a great surface area of 253.2 m²·g^-1. Its catalytic performance demonstrates that the composite has excellent stability and high tolerance Suzuki-Miyaura cross-coupling reactions in 30 min at 80 ℃. Both activated and deactivated aryl halides provided excellent yield. The as-fabricated catalyst was recycled for up to four catalytic cycles without a substantial decline in performance. Moreover, this research offers a facile roadmap for synthesizing Pd/Fe₃O₄-CSPs composites and promoting the practical implementation of Pd/Fe₃O₄-CSPs catalysts for organic transformation processes.     

Reusable and durable electrostatic air filter based on hybrid metallized microfibers decorated with metal-organic-framework nanocrystals

As global air pollution becomes increasingly severe,various types of fibrous filters have been devel-oped to improve air filter performance.However,fibrous filters have limitations such as high packing density that generally causes high-pressure drop and ultimately deterioration in the filtration effi-ciency.High-pressure particulate matter precipitators are limited in terms of scope for commercialization because they require high voltage supplies and ozone generators.In this study,we develop fibrous fil-ters with enhanced durability and improved performance using metallized microfibers decorated with metal-organic-framework(MOF)nanocrystals.Not only does the efficiency of the developed filters remain at or above 97％for 0.50-1.5 μm PMs but the durability also significantly increases.In addi-tion,using the water purification ability of the MOF,we explore the dye degradation effect of the hybrid microfibers by immersing them into Rhodamine B aqueous solution.In such an experiment the Rho-damine B aqueous solution is completely purified by the presence of the hybrid microfibers under the UV irradiation.     

新与旧的融合 法国MAISONDELA文化中心

正这是位于法国小镇Saint-Pierre-dePlesguen上的一栋传统住宅,除了主体建筑之外,房屋的东西两面各有一个院子。本项目邀请了法国本土的设计工作室ATELIER 56S将其打造成了一个文化中心。设计师打通了原本完全封闭的东部立面,以加强内外空间的联系,促进建筑内部各空间的交流与互动。同时,设计最大程度地保留了原有建筑的外观风貌,体现了对历史的足够尊重。     

A boronic acid-based fluorescent hydrogel for monosaccharide detection

A boronic acid-based anthracene fluorescent probe was functionalised with an acrylamide unit to incorporate into a hydrogel system for monosaccharide detection. In solution, the fluorescent probe displayed a strong fluorescence turn-on response upon exposure to fructose, and an expected trend in apparent binding constants, as judged by a fluorescence response where D-fructose>D-galactose>D-mannose>D-glucose. The hydrogel incorporating the boronic acid monomer demonstrated the ability to detect monosaccharides by fluorescence with the same overall trend as the monomer in solution with the addition of D-fructose resulting in a 10-fold enhancement (≤0.25 mol/L).     

生物基油对白炭黑填充天然橡胶胶料加工性能和硫化特性的影响

通常使用的石油基加工油,比如重质环烷油(HNO)和轻质环烷油(LNO)具有潜在的致癌性。本文研究了一种新型生物基油——茶籽油(TO)可能会成为通用加工油的替代品。在进行试验对比时,还选择了另外两种生物基油,分别是棕榈油(PO)和椰子油(CO)。试验结果表明,所有研究的生物基油的热稳定性均高于轻质环烷油(LNO),在白炭黑填充天然橡胶(NR)配方中,配合生物基油的混炼胶加工性能比添加石油基油的胶料更加优异。主要表现为:生物基油的热稳定性高,在相同混炼条件下,与添加石油基油的混炼胶相比,添加生物基油能够提高白炭黑与天然橡胶的混合效率,改善白炭黑在天然橡胶基质中的分散性,提高混炼胶的塑化效果。加工油的不同类型和用量对混炼胶的硫化特性影响很小。通过试验结果分析,所研究的TO、PO和CO生物基油很有可能成为石油基加工油的替代产品。     

混炼试验的潘恩效应和分散率对比(二)

正(接上期)4.1.6 EPDM图20示出了三元乙丙橡胶(EPDM)具有类似于丁基橡胶(IIR)的对炭黑弱的亲和力。就像混炼丁基橡胶(IIR)填充胶那样,所看到的EPDM填充胶的G′潘恩效应曲线都很接近,这点EPDM与IIR很相似,均缺乏与炭黑的亲和     

滴施腐植酸肥和化肥对辣椒生产率的影响

正采用随机区组设计,在不添加腐植酸(单独施肥)和添加腐植酸(联合施肥)的条件下,以NPK推荐施肥量100%、80%和60%的3个施肥水平,研究了NPK滴灌对辣椒养分分配和生产率的影响。在较深的土层中,联合施肥能降低土壤速效N和K含量,提高土壤速效P含量。单独施肥的基础上联合施肥,辣椒产量提高了17%~27%。联合施肥的肥     

Hybrid plasmonic label-free multi-analyte refractive index sensor

We propose a label-free refractive index sensor based on hybrid plasmonic resonator which consists of silver split-ring resonator and photonic waveguide. The finite difference time domain evaluation of the design exhibit strong field confinement at the center of the ring and introduces tunable and sensitive notches in the transmission spectrum. The planar tunable architecture which performs well over the range of micro fluid detection, holds the promise of developing multi-analyte label-free biosensors and compactness towards a complete on-chip integrated sensing system. The performance of the proposed refractive index sensor is evaluated by placing different analytes such as saline water and ethanol at the center of the hybrid plasmonic ring which exhibits sensitivity of 847.50 nm.RIU-1 with a figure of merit of 563.25 RIU-1.     

Separation of hematite from banded hematite jasper (BHJ) by magnetic coating

The separation of iron oxide from banded hematite jasper(BHJ) assaying 47.8% Fe, 25.6% Si O2 and 2.30%Al2O3 using selective magnetic coating was studied. Characterization studies of the low grade ore indicate that besides hematite and goethite,jasper, a microcrystalline form of quartzite, is the major impurity associated with this ore. Beneficiation by conventional magnetic separation technique could yield a magnetic concentrate containing 60.8% Fe with 51% Fe recovery. In order to enhance the recovery of the iron oxide minerals, fine magnetite, colloidal magnetite and oleate colloidal magnetite were used as the coating material. When subjected to magnetic separation, the coated ore produces an iron concentrate containing 60.2% Fe with an enhanced recovery of56%. The AFM studies indicate that the coagulation of hematite particles with the oleate colloidal magnetite facilitates the higher recovery of iron particles from the low grade BHJ iron ore under appropriate conditions.