固定化生物硅藻土强化CAST工艺处理含盐污水研究

采用9%聚乙烯醇+0.5%海藻酸钠包埋耐盐菌群的固定化生物硅藻土小球投加到循环式活性污泥(CAST)反应器中,对比传统CAST工艺和投加固定化小球的CAST工艺对含盐污水COD和氨氮的去除效果,考察固定化生物硅藻土小球强化CAST工艺处理含盐污水性能。试验结果表明:在相同运行条件下,投加固定化生物硅藻土小球的CAST工艺出水COD、氨氮去除率基本维持在88%和90%以上,与传统CAST工艺相比分别提高了15%和10%。同时,向CAST工艺添加固定化生物硅藻土有助于维持反应器中微生物浓度稳定,提高出水水质及其稳定性。     

有氧条件下黄铁矿活化过硫酸钠降解对氯苯胺的研究

文章研究了在有氧条件下黄铁矿(Fe S2)活化过硫酸盐(PS)降解对氯苯胺(PCA)。探讨了初始p H、Fe S2投加量、初始PS浓度,考察了水体系中溶解氧对PCA降解的影响。结果表明有氧条件下有利于PCA降解率,PCA降解率随着Fe S2投加量或PS浓度的增加而增加,但随着初始p H的增加而降低。采用乙醇,叔丁醇和1,4-苯醌来考察硫酸自由基(SO4?-),羟基自由基(OH?),超氧自由基(O2?-)的存在与作用。结果说明SO4?-通过Fe S2/PS/Air体系中作为PCA的降解重要作用。     

温度饱和水下的裂隙岩体力学特性研究*

在理论上，利用O‘Connell的饱和水裂隙岩体等效弹性模量与岩石模量的关系式，并由式中的裂隙密度概念意义，建立了温度作用下的裂隙密度与Oda提出的裂隙张量之间的关系式；在试验的基础上，给出了温度、饱和水下的单裂隙岩体应力－应变、抗压强度回归拟合关系表达式。并通过试验与拟合结果对以加以验证，其裂隙岩体力学模型可为裂隙岩体THM耦合分析提供合理的依据。     

三边形钢管塔在移动通信领域的应用

三边形钢管塔是一种造型新颖的塔架结构,已运用于移动通信领域,通过分析其作为移动通信用塔的优势及存在的不足,探讨其设计方法,为该塔型在移动通信领域的推广应用抛砖引玉。     

十三陵抽水蓄能电站地下工程冬期施工

根据北京昌平地区温度观测资料,确定了十三陵抽水蓄能电站工程砼冬施参数,达到了既能满足拆模强度,又保证了砼的质量。     

Pt-modulated Cu/SiO2 catalysts for efficient hydrogenation of CO2-derived ethylene carbonate to methanol and ethylene glycol

Copper-based catalysts were widely used in the heterogeneous selective hydrogenation of ethylene car-bonate (EC),a key step in the indirect conversion of CO2 to methanol.However,a high H2/EC molar ratio in feed is required to achieve favorable activity and the methanol selectivity still needs to be improved.Herein,we fabricated a series of Pt-modulated Cu/SiO2 catalysts and investigated their catalytic perfor-mance for hydrogenation of EC in a fixed bed reactor.By modulating the Pt amount,the optimal 0.2Pt-Cu/SiO2 catalyst exhibited the highest catalytic performance with ～99％ EC conversion,over 98％ selectiv-ity to ethylene glycol and 95.8％ selectivity to methanol at the H2/EC ratio as low as 60 in feed.In addition,0.2Pt-Cu/SiO2 catalyst showed excellent stability for 150 h on stream over different H2/EC ratios of 180-40.It is demonstrated a proper amount of Pt could significantly lower the H2/EC molar ratio,promote the reducibility and dispersion of copper,and also enhance surface density of Cu+ species.This could be due to the strong interaction of Cu and Pt induced by formation of alloyed Pt single atoms on the Cu lattice.Meanwhile,a relatively higher amount of Pt would deteriorate the catalytic activity,which could be due to the surface coverage and aggregation of active species.These findings may enlighten some fundamen-tal insights for further design of Cu-based catalysts for the hydrogenation of carbon-oxygen bonds.     

用磨粒叶序排布砂轮磨削外圆生成的凹坑表面仿真

结构化凹坑表面能够有效降低零件表面的流体拖曳摩擦阻力,从而改善零件在流体中的运动性能。从生物学的叶序排布理论出发,设计了磨粒叶序排布的超硬材料砂轮,并应用该砂轮磨削外圆生成结构化的凹坑表面。利用Matlab软件对磨粒叶序排布砂轮的磨削过程进行运动学仿真,获得了磨粒叶序排布参数及磨削参数对磨削区域内结构化凹坑表面形貌的影响规律。仿真及实验结果表明:转速比影响凹坑的周向排布和凹坑尺寸,转速比越高,凹坑周向排布越密集,凹坑尺寸越小;叶序系数影响凹坑的轴向排布,叶序系数越小,凹坑轴向排布越密集;磨削深度影响凹坑尺寸,磨削深度越深,凹坑宽度和深度越大,毛刺隆起高度越高,约为磨削深度的一半。      

6061-T6铝合金双轴肩搅拌摩擦焊接头组织与力学性能

针对6 mm厚6061-T6铝合金板材,在主轴转速800 r/min,焊接速度150 mm/min参数下实现双轴肩搅拌摩擦焊接,并对一部分试件进行焊后热处理。对焊态试件和焊后热处理试件同时进行金相试验、拉伸试验和显微硬度试验对比分析。在焊态下,接头平均抗拉强度为203 MPa,达到母材的64%,接头在焊缝区32 mm的宽度区域内显微硬度出现不同程度的下降,显微硬度分布呈"W"型;接头经焊后热处理后,焊态下溶解消失的强化相重新析出,使接头组织重新得到强化,热处理态接头平均抗拉强度为292 MPa,达到母材的92%,整个焊缝区显微硬度均得到提高,焊态下"W"型显微硬度分布规律消除。     

Comparative In Vitro Osteoinductivity Study of HA and α‐TCP/HA Bicalcium Phosphate

A bicalcium phosphate (BCP) bioceramic comprising α‐tricalcium phosphate (α‐TCP) and hydroxyapatite (HA) was prepared by a two‐step sintering. The microstructure of the BCP bioceramic was investigated using scanning electron microscopy (SEM), transmission electron microscopy (TEM), and X‐ray diffraction. The in vitro osteoinductivity was evaluated by culturing MG63 osteoblast‐like cells on the BCP bioceramic. Results showed that the BCP bioceramic comprising α‐TCP and HA in a moderate ratio possessed a hardness of 93.7 Hv. The cells spread faster on the BCP bioceramic than those on the commercial HA. It suggested that the BCP bioceramic can enhance osteoinductivity in vivo.     

深水钻井装置浅水区动力定位方式风险研究

当今世界上先进的深水钻完井装置具有锚泊及动力定位2种方式作业能力,业内推荐做法为水深小于1 500 m都可以使用锚泊方式定位,对于动力定位方式在浅水区的适应性和风险则缺少分析。通过对动力定位方式的原理及其漂移限制进行论述,包括了浅水定位的理论限制以及规避风险的措施,提出如何设定观察圈范围及浅水作业使用动力定位方式时应考虑因素、作业风险及应对措施,除了环境及深水钻井装置应急解脱时间影响因素外,还将考虑隔水管系统极限、水下井口和结构套管强度、通讯系统、定位传感器系统等影响因素,应对措施包括井口设备选择、隔水管系统分析、人员交流培训和使用者和承包商协议等,对浅水区使用定位方式作业有一定的指导意义。