“房奴”解套之我见

每年都有新名词出现,而新名词的出现总是反映了一定的社会现象和价值取向,去年最火的是"超女",到今年最火的当数"房奴".     

Simulation on function mechanism of T1(Al_2CuLi) precipitate in localized corrosion of Al-Cu-Li alloys

1Introduction Al-Li alloys,compared with traditional Al alloys,possess more excellent properties,such as lower density,greater elastic modulus and higher specific strength.In the near future,they would be widely applied in airplane structures.However,they…     

铝合金时效成形及时效成形铝合金

介绍了铝合金时效成形的方法、基本原理、工艺特点及应用情况,概括了国外研究铝合金时效成形工艺及相关可时效成形铝合金的现状,重点阐述了时效成形对铝合金微观组织结构的影响.     

应力作用下1420Al-Li合金的腐蚀行为研究

通过动电位极化曲线、电化学阻抗谱,并结合SEM图,研究恒应力作用下1420Al-Li合金在3.5%NaCl溶液中的腐蚀行为.结果表明:随着应力增加,材料的腐蚀加剧;合金主要腐蚀类型为孔蚀,这是由于合金的主要时效强化相为δ'相(Al3Li),它作为阳极相均匀弥散分布在基体中,晶界处仅有少量的S(Al2MgLi)相.     

第二相在铝合金局部腐蚀中的作用机制

铝合金中通常含有一些时效析出相及杂质相等第二相粒子,这些第二相粒子对铝合金局部腐蚀行为产生重大影响.概括了析出相θ(Al2Cu)、η(MgZn2)、β(Mg3Al2)及含Fe杂质相FeAl3等在铝合金局部腐蚀中的作用机制,重点介绍了S相(Al 2CuMg)和T1相(Al2CuLi)对铝合金局部腐蚀作用机制的不同观点.     

Localized corrosion mechanism associated with precipitates containing Mg in Al alloys

To clarify the localized corrosion mechanism associated with precipitates containing Mg in Al alloys, the simulated bulk precipitates of S and β were synthesized through melting and casting. Their electrochemical behaviors and coupling behaviors with α（Al） in NaCl solution were measured. Meanwhile, simulated Al alloys containing S and β particles were prepared and their corrosion morphologies were observed. It＇s found that there exist two kinds of corrosion mechanisms associated with precipitates containing Mg. The precipitate of β is anodic to the alloy base, resulting in its anodic dissolution and corrosion during the whole corrosion process. While, there exists a corrosion conversion mechanism associated with the S precipitate, which contains active element Mg and noble element Cu simultaneously. At an initial stage, S is anodic to the alloy matrix at its periphery and the corrosion occurs on its surface. However, during its corrosion process, Mg is preferentially dissolved and noble Cu is enriched in the remnants. This makes S become cathodic to a（Al） and leads to anodic dissolution and corrosion on the alloy base at its periphery at a later stage.     

5052铝合金热压缩变形流变应力

在Gleeble-1500热模拟机上,采用高温等温压缩,在应变速率为0.001~10 s-1和变形温度为300℃~500℃条件下对5052铝合金的流变应力行为进行了研究。结果表明:在应变速率为0.1 s-1(变形温度为420℃~500℃)以及应变速率为0.01和0.001(变形温度为300℃~500℃)时,5052铝合金热压缩变形出现了明显的峰值应力,表现为连续动态再结晶特征;在其他变形条件下存在较为明显的稳态流变特征。可采用Zener-Hol-lomon参数的双曲正弦函数来描述5052铝合金高温变形时的流变应力行为;在获得的流变应力σ解析表达式中A、α和n值分别为12.68×1011s-1,0.023MPa-1和5.21;其热变形激活能Q为182.25 kJ/mol。     

应力作用下Al-Li合金的腐蚀行为研究

通过测量动电位极化曲线，并用扫描电镜（SEM）、透射电镜（TEM）观察，分析应力作用下峰时效的2195、1420Al-Li合金在3．5％NaCl溶液中的腐蚀行为。结果表明，无应力时1420Al-Li合金发生蚀孔较大且不连续的均匀腐蚀，2195Al-Li合金发生局部腐蚀为晶间腐蚀和孔蚀的均匀腐蚀；施加应力时1420Al-Li合金蚀孔增多、尺寸减小，2195Al-Li合金晶间腐蚀加重，大量孔蚀连接成片形成严重的均匀腐蚀。