油泵站加油工具车液压系统及故障排除

本文首先介绍了液压系统的分类和故障类型,以液压系统油的清洁度为切入点,介绍作者设计的油泵站加油工具车的液压系统设计原理并介绍其在海南联网工程500kV充油海底电缆油泵站中的应用,最后从多角度介绍了该液压系统的常见故障分析与故障处理方法。     

近缆抛锚技术在海南联网二回路由勘察中的应用

介绍了近缆抛锚技术在海南联网二回路由勘察中的应用方法、实施过程,在确保海南联网一回海底电缆安全稳定运行的前提下,完成了海南联网二回路由勘察施工作业,极大地降低了因抛锚施工给运行中的海底电缆带来的安全风险。     

Study on purification and application of novel precipitant for ceria-based polishing powder

Novel precipitant prepared through carbonation with MgCl2 wastewater generated from rare earth extraction separation process and low-price dolomite as raw materials was studied in this paper. The purification methods of novel precipitant by adding appropriate oxidizing agent were studied. It was found that optimal purification result could be achieved with sodium hypochlorite as iron removal reagent and the iron removal rate could reach up to 90% when the adding amount was 0.1 vol.%. During the preparation, the particle size and distribution of ceria-based polishing powder were affected obviously by the parameters such as concentration, reaction temperature and feeding rate. The results showed that ceria-based polishing powder with D50 =2.5-3.5 μm and the particle size distribution of 0.65-0.75 μm could be prepared when the concentration of CeCl3 was 0.6 mol/L, the reaction temperature was maintained at 50 °C and the feeding speed was controlled at 25 ml/min. Compared with commercial powder, the self-made polishing powder had roughly the same cutting amount, but the surface finish of polished glass was better than that of commercial polishing powder.     

磷矿中微量稀土提取技术研究进展

磷矿中伴生的微量稀土作为一种潜在的稀土资源,开展综合回收稀土的研究具有重要意义.简单介绍了磷矿中稀土含量及分布状况,综述了磷化工过程中回收稀土的最新研究进展,分别介绍了回收稀土的方法及现状,对未来磷矿中微量稀土提取技术研究方向进行了探讨.     

利用氟铝络合物溶液合成冰晶石的研究

以氟碳铈矿氧化焙烧-稀硫酸浸出-萃取洗涤得到的氟铝络合物溶液为原料,通过补充氟盐和钠盐控制一定的F/Al比、Na/Al比,并调节pH值得到冰晶石沉淀,经过滤、洗涤、烘干得冰晶石产品.重点探讨了合成冰晶石的原理,研究了溶液pH值、F/Al比、Na/Al比和合成温度等对冰晶石产品质量及回收率的影响,并对制备工艺进行了优化.研究结果表明:溶液pH值在5左右、F/Al比在5.5～6之间、Na/Al比在3.0～3.3之间,合成温度在95℃以上合成的冰晶石符合国家标准,且氟、铝的回收率均可达95%以上.     

电感耦合等离子体原子发射光谱法测定磷矿中微量稀土元素

样品经碱熔,溶液提取,沉淀富集后得到只含稀土元素的溶液,采用电感耦合等离子体原子发射光谱(ICP-AES)法测定磷矿中15种稀土元素La、Ce、Pr、Nd、Sm、Eu、Gd、Tb、Dy、Ho、Er、Tm、Yb、Lu、Y。主要考察了共存元素间的干扰情况,选择无干扰或干扰量对分析结果可以忽略不计的谱线为最佳分析线,标准曲线法直接测定磷矿中稀土元素。本法测定结果与ICP-MS测定结果相符合,可满足日常分析要求。     

Effect of MgF2-H3BO3 flux on the properties of (Ce,Tb)MgAl11O19 phosphor

The green-emitting(Ce,Tb)MgAl11O19(CTMA) phosphor was prepared by the conventional high temperature solid-state reaction method.The effect of fluxes on the crystal structure,particle morphology,size distribution and photoluminescence properties of CTMA phosphor was investigated by means of the X-ray powder diffraction,scanning electron microscopy and photoluminescence spectrum.The results showed that the addition of appropriate amount of MgF2-H3BO3 flux improved the phase purity of CTMA phosphor,and influen...     

High temperature stability of Eu2＋-activated nitride red phosphors

The novel nitride-based luminescent materials have received much attention since the end of the last century. In this paper, the commercial Eu2＋-activated nitride red phosphors, Sr1.95Si5N8：Eu0.05, Sr1.85Si5N8：Eu0.15 and Ca0.99AlSiN3：Eu0.01 phosphors were an-nealed at different temperatures （beyond 300 oC） to investigate the dependence of their luminescence performance and structure vari-ability on the temperature. By photoluminescence spectra, X-ray diffraction （XRD） and thermogravimetry-differential scanning calo-rimetry （TG-DSC） analysis, the high temperature stability of the hosts and activator of the three samples were disclosed. With the an-nealing temperature increasing, the activator Eu2＋ions were firstly oxidized and then host in Sr1.95Si5N8：Eu0.05 and Sr1.85Si5N8：Eu0.15, but for Ca0.99AlSiN3：Eu0.01, only the oxidation of the host could be observed, which would lead to the luminescence degradation and even failure of these phosphors. The activator Eu2＋ions were much more stable in CaAlSiN3：Eu than Sr2Si5N8：Eu due to their crystal surroundings, and its concentration also influenced the temperature stability of Sr2Si5N8：Eu.     

500 kV充油海底电缆导体温度分布式光纤传感监测及应用

依据海南联网系统500 kV海底电缆捆绑特殊海底光缆的实际情况,通过分布式光纤传感技术结合经有限元仿真模型优化的IEC60287热路模型的方法可以监测海底电缆内部的温度分布。在实验室中搭建岸上模拟实验平台,利用中压电缆捆绑光纤的结构进行捆绑电缆岸上模拟实验。同时,将经验证的温度监测方法应用于海南联网系统500 kV海底电缆,以C相空气段为例监测捆绑电缆光单元的温度。采用有限元仿真计算电缆表面的温度,根据电缆表面的温度基于热路模型推导出对应的导体温度,得到电缆导体在实际运行过程中的温度变化。岸上模拟实验测量的导体温度与数值计算得到导体温度的误差低于1.77%, 验证了海底电缆导体温度监测方法的准确性。     

500kV海底电缆油泵站远程监控系统研究

海底电缆油泵站作为海南联网工程的重要组成部分,满足3根海底电缆用油及压力需求.油泵站系统投运9年,出现多起故障,当海底电缆油泵站控制系统故障后,无法监控油泵站的运行状况,无法手动对油泵站系统进行就地操作及了解海底电缆的供油情况.研究海底电缆油泵站的工作原理,打破原有代码屏蔽,开发一套海底电缆油泵站远程监控系统,实现对油泵站的远程监控.