Biocatalytic electrode improvement strategies in microbial fuel cell systems

Microbial fuel cells (MFCs) produce electricity as a result of the microbial metabolism of organic substrates, hence they represent a sustainable approach for energy production and waste treatment. If the technology is to be implemented in industry, low cost and sustainable bioelectrodes must be developed to increase power output, increase waste treatment capacity, and improve service intervals. Although the current application of abiotic electrode catalysts, such as platinum and electrode binders such as Nafion leads to greater MFC performance, their use is cost prohibitive. Novel bioelectrodes which use cost effective and sustainable materials are being developed. These electrodes are developed with the intention to reduce start-up time, reduce costs, extend life-span and improve core MFC performance metrics (i.e. power density, current density, chemical oxygen demand (COD) reduction and Coulombic efficiency (CE)). Comparison of different MFC systems is not an easy task. This is due to variations in MFC design, construction, operation, and different inocula (in the case of mixed-culture MFCs). This high intra-system variability should be considered when assessing MFC data, operation and performance. This review article examines the major issues surrounding bioanode and biocathode improvement in different MFC systems, with the ultimate goal of streamlining and standardising improvement processes. © 2018 Society of Chemical Industry     

The COVID‐19 crisis and complexity: A soft systems approach

The COVID‐19 pandemic is a crisis with high complexity and should be understood as such by scholarship. A complexity science approach situates increasingly divergent ideological and epistemological perspectives about the crisis within the practical exigencies of containment and mitigation measures. We ask which of the seven stages of soft systems methodology contributes to deeper understandings about COVID‐19 as a policy issue, beyond the contributions of current and conventional perspectives. The discussion outlines implications for practice and places them within broader debates about tensions between scientific facts and political values.     

Debiasing overoptimistic beliefs about braking capacity

We investigated, using questionnaires, different strategies for removing drivers’ overoptimism (Svenson et al., 2012a) about how fast their speed could be decreased when they were speeding compared with braking at the speed limit speed. Three different learning groups and a control group made collision speed judgments. The first learning group had the distance a car travels during a driver's reaction time for each problem. The second group had this information and also feedback after each judgment (correct speed). The third group judged collision speed but also braking distance and received correct facts after each problem. The control group had no information at all about reaction time and the distance traveled during that time. The results suggested the following rank order from poor to improved performance: control, group 1, group 3 and group 2 indicating that information about distance driven during a driver's reaction time improved collision speed judgments and that adding stopping distance information did not add to this improvement.     

Trace Elements in the Si Furnace-Part II: Analysis of Condensate in Carbothermal Reduction of Quartz

Silicon feedstock for production of solar-grade silicon should be as pure as possible to decrease the cost of manufacturing of solar cells. Impurities in quartz, carbonaceous materials, electrodes, and refractories are mostly present in the form of oxides. These oxides can be reduced to volatile gaseous compounds in presence of SiO(g) and CO(g) atmosphere and potentially leave the furnace or stay in the condensed reaction products, metal, and slag. This work investigates the conditions under which volatile impurities report to the gas phase in laboratory experiments with lumpy and pelletized mixtures of SiO₂, SiC, and Si at 1923 K and 2123 K (1650 °C and 1850 °C), respectively, were carried out. The volatile compounds were generated by the reduction of quartz and collected in the form of condensate. The effects of the reaction temperature, quartz type, charge composition, pellets, and lumps on the composition of the condensate were studied. The trace elements in the charge input, reacting charge, and condensate were analyzed using inductively coupled plasma (ICP)-mass spectroscopy (MS) and X-ray diffraction (XRD). CO(g) and SiO(g), which are the major components in reduction reactions, formed four types of condensate: white, brown, green, and orange. The condensate constituents were amorphous SiO₂, 3C:SiC, Si, and α-quartz. Each impurity present in the quartz charge entered the gas phase during quartz reduction and was detected in the condensate. Al and Fe show limited volatility. The volatility of Mn, P, and B depends on the charge mix: a higher P_CO enhances the concentration of these elements in the gas phase. Fluid inclusions, common in hydrothermal quartz, enhance the distribution of the contaminants to the gas phase. Industrial campaigns on Si and Fe-Si production confirm the experimental results.     

Virtual learning environments as sociomaterial agents in the network of teaching practice

This article presents findings related to the sociomaterial agency of educators and their practice in Norwegian education. Using actor-network theory, we ask how Virtual Learning Environments (VLEs) negotiate the agency of educators and how they shape their teaching practice. Since the same kinds of VLE tools have been widely implemented throughout Norwegian education, it is interesting to study how practices are formed in different parts of the educational system. This research is therefore designed as a case study of two different teaching contexts representing lecturers from a higher education institution and teachers from primary schools. Data are collected by means of interviews, online logging of VLE activities and self-reported personal logs. From the analysis of the data, three main networks of aligned interests can be identified. In each of those, the sociomaterial agency of the teaching practice with VLE is crucial in shaping and consolidating the network.     

Synthesis of Bisindolylmethanes and Their Cytotoxicity Properties

Polymer supported dichlorophosphate (PEG-OPOCl₂) is an efficient green catalyst for the electrophilic substitution reaction of indole with aromatic aldehydes, in neat condition, to afford an excellent yield of bis(indolyl) methanes with short reaction time, at room temperature. The synthesized compounds and their anti-cancer activity are evaluated.