中空介孔硅基刺激响应型纳米药物载体的研究进展

对中空介孔硅的制备方法及其优缺点进行阐述，同时总结了pH、光、氧化还原和多重刺激响应型中空介孔硅药物载体的刺激响应原理及研究进展，最后对其目前存在的问题以及未来研究方向进行了分析和展望。     

Fe3O4-carbon spheres core–shell supported palladium nanoparticles: A robust and recyclable catalyst for suzuki coupling reaction

Suzuki-Miyaura (S-M) is regarded the most powerful way for synthesis biaryls, triaryls, or incorporating of substituted aryl moieties in organic preparation by the cross-coupling of aryl boronic acid with aryl halides using the Pd catalyst. This work reports the combining of the hydrothermal and microwave-assisted protocol to convert the glucose to magnetic carbon spheres (Fe₃O₄-CSPs) decorated with Pd nanoparticles (NPs) as the catalyst for Suzuki-Miyaura cross-coupling reactions. The physicochemical properties in the produced composite were examined using FESEM, HRTEM, nitrogen isotherms, Raman spectroscopy, FTIR, XPS, and XRD. The as-fabricated composite Pd/Fe₃O₄-CSPs is mostly spherical with a core–shell structure and possesses a great surface area of 253.2 m²·g^-1. Its catalytic performance demonstrates that the composite has excellent stability and high tolerance Suzuki-Miyaura cross-coupling reactions in 30 min at 80 ℃. Both activated and deactivated aryl halides provided excellent yield. The as-fabricated catalyst was recycled for up to four catalytic cycles without a substantial decline in performance. Moreover, this research offers a facile roadmap for synthesizing Pd/Fe₃O₄-CSPs composites and promoting the practical implementation of Pd/Fe₃O₄-CSPs catalysts for organic transformation processes.     

Microstructure and mechanical behavior of laser aided additive manufactured low carbon interstitial Fe49.5Mn30Co10Cr10C0.5 multicomponent alloy

Laser aided additive manufacturing(LAAM)was used to fabricate bulk Fe49.5Mn30Co10Cr10C0.5 interstitial multicomponent alloy using pre-alloyed powder.The room temperature yield strength(σy),ultimate tensile strength(σUTS)and elongation(εUST)were 645 MPa,917 MPa and 27.0％respectively.The as-built sample consisted of equiaxed and dendritic cellular structures formed by elemental segregation.These cellular structures together with oxide particle inclusions were deemed to strengthen the material.The other contributing components include dislocation strengthening,friction stress and grain bound-ary strengthening.The high εUTS was attributed to dislocation motion and activation of both twinning and transformation-induced plasticity(TWIP and TRIP).Tensile tests performed at-40℃and-130℃demonstrated superior tensile strength of 1041 MPa and 1267 MPa respectively.However,almost no twinning was observed in the fractured sample tested at-40℃and-130℃.Instead,higher fraction of strain-induced hexagonal close-packed(HCP)ε phase transformation of 21.2％were observed for fractured sample tested at-40℃,compared with 6.3％in fractured room temperature sample.     

冰天雪地找油热

2020年12月28日晚,北疆古尔班通古特沙漠,气温低至零下30多摄氏度。中石化地球物理公司胜利分公司SGC2105队放炮队员朱文亮和郭谋子正快速穿行着,进行放炮生产。随着气温的降低,项目上的100多台施工车从0号柴油逐渐换到了-35号,并且加上了低密度的润滑油。即便这样,晚上每隔3小时就要发动半小时,否则早上出工就打不着火了。     

上升气泡内气溶胶沉降机理研究

气溶胶池洗过滤是反应堆严重事故中去除放射性源项的重要手段。本文以严重事故条件下上升气泡中气溶胶的滞留过程为背景，设计搭建了可视化单气泡鼓泡实验装置。通过该装置研究了气溶胶在上升气泡中的沉降效率，并与MELCOR中的气溶胶沉降模型计算结果进行了对比。结果表明，气溶胶沉降效率对气泡尺寸的变化较为敏感，当气体流量大于0.1 L/min时，气泡等效直径迅速增加，相应的气溶胶沉降效率快速降低；与MELCOR模型计算结果的对比表明，两者在总体趋势上呈现出较好的一致性，但计算结果低估了液相对气溶胶的实际去除能力，导致这种偏差的主要原因是气泡在上升过程中存在无规则的晃动以及气液界面的波动。     

地面驱动螺杆泵井故障诊断方法

为提高地面驱动螺杆泵井的故障诊断效率,提出了一种将小波包与概率神经网络相结合的故障诊断方法.运用小波包技术提取有功功率信号的能量特征,与动液面、瞬时流量、井口回压共同作为特征参数,输入到概率神经网络进行故障诊断.为证明所提诊断方法的优越性,与BP神经网络、径向基神经网络进行对比,结果表明所提方法诊断效率更高、速度更快,更加满足故障诊断实时性的要求;故障诊断实例结果也进一步证明了该方法在地面驱动螺杆泵井故障诊断的可行性.     

城市复杂环境下钢结构桥梁吊装施工技术

吊装是桥梁钢箱梁施工中的重点环节。以复杂环境下的桥梁工程实例为依托,对吊装临时支架的搭设、设备的选用及吊装施工要点进行详细的分析,以探寻兼具安全性、可靠性的钢结构桥梁吊装施工技术。     

在腐植酸存在的条件下动态模拟铜在贻贝类体内的富积

正依据金属生物利用度模型,腐植酸对铜的络合作用有望降低水生生物对铜的生物利用度,就如生物配体模型(BLM)。这个模型在海洋无脊椎动物胚胎或是微藻类等不进食生物中得到了证实。但对于像紫贻贝等滤食性生物体,在腐植酸存在的条件下铜的富积较高,表明摄取的铜-腐植     

基于齿槽效应的高速永磁电机转子涡流损耗解析计算

针对齿槽效应引起的高速永磁电机转子涡流损耗,提出精确解析计算模型。该解析计算模型考虑包括槽和槽口在内的五个子域,通过在各个子域中建立、求解磁矢位方程以及借助子域间的边界条件对模型进行推导,同时考虑保护套和永磁体产生的涡流反应。基于建立的解析模型,能够计算出转子各部分的涡流损耗,并能够通过解析模型获得槽开口宽度、保护套材料和保护套厚度与转子涡流损耗之间的影响规律。将解析模型的计算结果与有限元结果进行对比,并进行实验测试,验证了转子涡流损耗解析模型的正确性。     

考虑煤层倾角和钻孔倾角的钻屑量理论研究

为准确预测与预防深部开采煤与瓦斯突出,建立了考虑煤层倾角与钻孔倾角的新钻屑量理论计算公式,并分析了煤层倾角和钻孔倾角对钻屑量的影响。以平煤股份有限公司八矿为研究对象,将钻屑量理论计算值与该矿己15-21030风巷现场钻屑量实测值进行对比验证,得出在煤层倾角一定时,钻屑量随钻孔倾角增大呈幂指数递减关系,减小的比率呈“V”形变化趋势,原钻屑量理论值与实测值平均误差为5.5%,在考虑煤层倾角与钻孔倾角情况下的新钻屑量理论值与实测值平均误差为3.9%。