Large Area Self-Assembled Ultrathin Polyimine Nanofilms Formed at the Liquid–Liquid Interface Used for Molecular Separation

Separation membranes with higher molecular weight cut-offs are needed to separate ions and small molecules from a mixed feed. The molecular sieving phenomenon can be utilized to separate smaller species with well-defined dimensions from a mixture. Here, the formation of freestanding polyimine nanofilms with thicknesses down to ≈14 nm synthesized via self-assembly of pre-synthesized imine oligomers is reported. Nanofilms are fabricated at the water–xylene interface followed by reversible condensation of polymerization according to the Pieranski theory. Polyimine nanofilm composite membranes are made via transferring the freestanding nanofilm onto ultrafiltration supports. High water permeance of 49.5 L m^-2 h⁻¹ bar⁻¹ is achieved with a complete rejection of brilliant blue-R (BBR; molecular weight = 825 g mol⁻¹) and no more than 10% rejection of monovalent and divalent salts. However, for a mixed feed of BBR dye and monovalent salt, the salt rejection is increased to ≈18%. Membranes are also capable of separating small dyes (e.g., methyl orange; MO; molecular weight = 327 g mol⁻¹) from a mixed feed of BBR and MO. Considering a thickness of ≈14 nm and its separation efficiency, the present membrane has significance in separation processes.     

Effect of the Time and Temperature of Isothermal Quenching on Microstructure and Mechanical Properties of Bainitic Gray Cast Iron

Metal Science and Heat Treatment - Mechanical properties of copper-alloyed bainitic gray cast iron are studied after isothermal quenching for bainite at different temperatures and holds. The...     

Low power and high speed design issues of CMOS Hamming code generation and error detection circuit at 22 nm and 16 nm channel length of MOS transistor

Microsystem Technologies - This paper represents low power and high speed design issues of Hamming code generation and error detection circuit using complementary metal oxide semiconductor (CMOS)...     

Assessing the sustainability of a manufacturing process using life cycle assessment technique—a case of an Indian pharmaceutical company

Clean Technologies and Environmental Policy - Manufacturing organizations are under continuous pressure to implement sustainability in their activities. There is a need to identify the...     

Transport phenomena in laser surface alloying

A three dimensional, transient model is developed for studying heat transfer, fluid flow and mass transfer for the case of a single-pass laser surface alloying process. The numerical study is performed in a co-ordinate system fixed to the laser which moves with a constant scanning speed. The coupled momentum, energy and species conservation equations are solved using a finite volume technique. Phase change processes are modelled using a fixed-grid enthalpy-porosity technique, which is capable of predicting the continuously evolving solid-liquid interface. The three-dimensional model is able to predict the species concentration distribution inside the molten pool during alloying, as well as in the entire cross section of the solidified alloy. Corresponding experimental results show a good qualitative agreement with the numerical predictions with regard to pool shape and final composition distribution.     

Microbiological safety of kinema, a fermented soya bean food

Kinema is a fermented soya bean food of Nepal and the hilly regions of North-eastern States of India. Generally, the fermentation is dominated by Bacillus spp. that often cause alkalinity and desirable stickiness in the product. The present study was undertaken in a limited number of commercial (market) kinema samples to test for the presence of foodborne pathogens and their properties. Bacillus cereus was present in numbers exceeding 10⁴ cfu/g product in five of the tested 15 market samples. Enterobacteriaceae and coliform bacteria exceeded 10⁵ cfu/g in 10 of the 15 samples. Escherichia coli exceeding 10⁵ cfu/g was found in two samples. Staphylococcus aureus was not detected in any of the tested samples. Of 31 isolated typical and atypical strains of B. cereus, 18 representative strains were tested qualitatively for the ability to produce diarrhoeal type enterotoxin (BCET) using an Oxoid BCET-RPLA test kit. Overall, BCET was formed by 12 strains in BHIG (brain heart infusion broth +1% glucose), by seven strains on sterilized cooked rice, and by five strains on sterilized cooked soya beans. Semi-quantitative tests on BCET revealed that levels exceeding 256 ng/g soya beans, produced by single pure culture inoculation with the isolated B. cereus strains, were reduced to ≤ 8 ng/g by frying kinema in oil, a common procedure when making kinema curry. It was also shown in a mixed pure culture experiment that a kinema strain B. Subtilis DK-W1, is able to suppress growth and BCET formation by a selected toxin producing strain (BC7-5) of B. cereus. It is concluded that the traditional way of making kinema and its culinary use in curries is safe. However, for novel applications of kinema, safety precautions are advisable.     

A tutorial on wavelets from an electrical engineering perspective.I. Discrete wavelet techniques

The objective of this paper is to present the subject of wavelets from a filter-theory perspective, which is quite familiar to electrical engineers. Such a presentation provides both physical and mathematical insights into the problem. It is shown that taking the discrete wavelet transform of a function is equivalent to filtering it by a bank of constant-Q filters, the non-overlapping bandwidths of which differ by an octave. The discrete wavelets are presented, and a recipe is provided for generating such entities. One of the goals of this tutorial is to illustrate how the wavelet decomposition is carried out, starting from the fundamentals, and how the scaling functions and wavelets are generated from the filter-theory perspective. Examples (including image compression) are presented to illustrate the class of problems for which the discrete wavelet techniques are ideally suited. It is interesting to note that it is not necessary to generate the wavelets or the scaling functions in order to implement the discrete wavelet transform. Finally, it is shown how wavelet techniques can be used to solve operator/matrix equations. It is shown that the “orthogonal-transform property” of the discrete wavelet techniques does not hold in numerical computations     

Analysis of a wide radiating slot in the ground plane of amicrostrip line

An analysis of a wide rectangular radiating slot excited by a microstrip line is described. Coupled integral equations are formulated to find the electric current distribution on the feed line and the electric field in the aperture. The solution is based on the method of moments and using the space domain Sommerfeld-type Green's function. The information about the input impedance or reflection coefficient is extracted from the electric current distribution on the microstrip line utilizing the matrix pencil technique. The theoretical analysis is described and data are presented and compared with other theoretical and experimental results     

Response level crossing rate of a linear system excited by a partially specified Gaussian load process

The problem of determining the maximum mean response level crossing rate of a linear system driven by a partially specified Gaussian load process has been considered. The partial specification of the load is given only in terms of its total average energy. The critical input power spectral (PSD) function, which maximizes the mean response level crossing rate, is obtained. The critical input PSD turns out to be highly narrow-banded which fails to capture the erratic nature of the excitation. Consequently, the trade-off curve between the maximum mean response level crossing rate and the maximum disorder in the input process, quantified in terms of its entropy rate, has been generated. The method of Pareto optimization is used to tackle the conflicting objectives of the simultaneous maximization of the mean response level crossing rate and the input entropy rate. The non-linear multi-objective optimization has been carried out using a recently developed multi-criteria genetic algorithm scheme. Illustrative example of determining the critical input of an axially vibrating rod, excited by a partially specified stationary Gaussian load process, has been considered.