Kinetic and mechanistic investigations of progesterone reaction with ozone

The removal of progesterone by ozone in aqueous solution was studied in this work. The absolute rate constant was evaluated and first by-products were identified. The reaction was studied in the 2.0-8.0 pH range and was found to be a second-order reaction, first-order relative to each compound concentration. The rate constant, determined by kinetic experiments in presence of an OH radical scavenger (tert-butanol), was independent of pH. The value was evaluated to be equal to 480+/-30 M(-1)s(-1) by two kinetic methods. Mass spectrometry analyses were performed to investigate primary degradation products generated by the reaction of ozone with progesterone. Two by-products were evidenced. According to these results, a degradation pathway of progesterone reacting with ozone was proposed.     

Stackable nonvolatile memory with ultra thin polysilicon film and low-leakage (Ti, Dy)xOy for low processing temperature and low operating voltages

We report the fabrication process as well as material and electrical characterization of ultra thin body (UTB) thin film transistors (TFTs) for stackable nonvolatile memories by using in situ phosphorous doped low-temperature polysilicon followed by the chemical mechanical polishing (CMP) process. The resulting polysilicon film is about 13 nm thick with approximately 10¹⁹ cm⁻³ doping. Root mean square surface roughness below 1 nm is achieved. Metal nanocrystals and high-k dielectric are selected for storage nodes and tunneling barriers to achieve low operating voltages. The number density and average diameter of nanocrystals embedded in the gate stack are 7.5 × 10¹¹ cm⁻² and 5.8 nm, respectively. Furthermore, scanning transmission electron microscopy (STEM), convergent beam electron diffraction (CBED) and electron energy loss spectroscopy (EELS) are performed for material characterization. The dielectric constant of the (Ti, Dy)_xO_y film is 35, and the off-state leakage current at −1 V bias and 2.8 nm equivalent oxide thickness is 5 × 10⁻⁷ A/cm². We obtain a memory window of about 0.95 V with ±6 V program/erase voltages. Our results show that UTB TFT is a promising candidate for the three-dimensional integration in high-density nonvolatile memory applications.     

High resolution solid state 13C n.m.r. of butadiene grafted polypropylene

¹H dipolar decoupled ¹³C n.m.r. experiments with the aid of the magic angle spinning technique have been used to determine the graft content and the isomer content of the polybutadiene grafts in a graft copolymer with isotactic polypropylene.     

Influence of traditional smoking on the triglyceride composition during the ripening of Idiazabal cheese

 The influence of traditional smoking on the triglyceride (TG) composition of Idiazabal cheese during ripening was studied using HPLC. The partition numbers (PNs) of the TGs ranged between 22 and 53, the groupings of TG peaks with PN values of 36, 34, and 38 being the main contributors. Statistically significant differences between the smoked and the unsmoked cheeses were recorded during the ripening period. Smoking had a significant effect on certain groups of TGs at different ripening times and no effect on others. The differences in the TG profiles of the cheeses were the result of differing levels of lipolytic activity, which was heightened by smoking. Received: 29 December 1997 / Revised version: 9 March 1998     

The role of achievement goals in the development of interest: Reciprocal relations between achievement goals, interest, and performance.

The dynamics of individual and situational interest and academic performance were examined in the college classroom and 7 semesters later in conjunction with achievement goals. At the beginning of an introductory psychology course, participants reported their initial interest in psychology, achievement goals, and situational interest in course lectures. At the end of the semester, participants (N = 858) reported their situational interest in course lectures and psychology. In the short term, relationships emerged among initial interest, achievement goals, situational interest, and class performance. Longitudinally, situational interest during the introductory course, independent of initial interest, predicted subsequent course choices. Results are discussed in terms of S. Hidi and K. A. Renninger's (2006) 4-phase model of interest development and the multiple goals model (J. M. Harackiewicz, K. E. Barron, P. R. Pintrich, A. J. Elliot, & T. M. Thrash, 2002). (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

The feasibility of motion and structure from noisy time-varying image velocity information

This research addresses the problem of noise sensitivity inherent in motion and structure algorithms. The motion and structure paradigm is a two-step process. First, we measure image velocities and, perhaps, their spatial and temporal derivatives, are obtained from time-varying image intensity data and second, we use these data to compute the motion of a moving monocular observer in a stationary environment under perspective projection, relative to a single 3-D planar surface. The first contribution of this article is an algorithm that uses time-varying image velocity information to compute the observer's translation and rotation and the normalized surface gradient of the 3-D planar surface. The use of time-varying image velocity information is an important tool in obtaining a more robust motion and structure calculation. The second contribution of this article is an extensive error analysis of the motion and structure problem. Any motion and structure algorithm that uses image velocity information as its input should exhibit error sensitivity behavior compatible with the results reported here. We perform an average and worst case error analysis for four types of image velocity information: full and normal image velocities and full and normal sets of image velocity and its derivatives. (These derivatives are simply the coefficients of a truncated Taylor series expansion about some point in space and time.) The main issues we address here are: just how sensitive is a motion and structure computation in the presence of noisy input, or alternately, how accurate must our image velocity information be, how much and what type of input data is needed, and under what circumstances is motion and structure feasible? That is, when can we be sure that a motion and structure computation will produce usable results? We base our answers on a numerical error analysis we conduct for a large number of motions.     

Effects of high pressure treatment on volatile profile during ripening of ewe milk cheese

The effect of high-pressure treatment on the volatile profile of ewe milk cheeses was investigated. Cheeses were submitted to 200, 300, 400 and 500 MPa at 2 stages of ripening (after 1 and 15 d of manufacturing) and volatile compounds were assayed at 15 and 60 d of ripening. High-pressure treatment altered the balance of volatile profile of cheeses, limiting the formation of acids, alcohols, ketones, aldehydes, and sulfur compounds and enhancing the formation of 2,3-butanedione. In general, cheeses pressurized at 15 d of ripening were more similar to untreated cheeses than those treated at 1 d. Cheeses treated at 300 MPa after 1 d of manufacturing were characterized by higher levels of free amino acids, ethanol, ethyl esters, and branched-chain aldehydes, whereas cheeses treated at 500 MPa after 1 d of manufacturing had lower microbial populations, showed the highest abundance of 2,3-butanedione, pyruvaldehyde, and methyl ketones, and the lowest abundance of alcohols.