Indoor air quality assessment in dwellings with different ventilation strategies in Nunavik and impacts on bacterial and fungal microbiota

Indoor air quality is a major issue for public health, particularly in northern communities. In this extreme environment, adequate ventilation is crucial to provide a healthier indoor environment, especially in airtight dwellings. The main objective of the study is to assess the impact of ventilation systems and their optimization on microbial communities in bioaerosols and dust in 54 dwellings in Nunavik. Dwellings with three ventilation strategies (without mechanical ventilators, with heat recovery ventilators, and with energy recovery ventilators) were investigated before and after optimization of the ventilation systems. Indoor environmental conditions (temperature, relative humidity) and microbiological parameters (total bacteria, Aspergillus/Penicillium, endotoxin, and microbial biodiversity) were measured. Dust samples were collected in closed face cassettes with a polycarbonate filter using a micro-vacuum while a volume of 20 m³ of bioaerosols were collected on filters using a SASS3100 (airflow of 300 L/min). In bioaerosols, the median number of copies was 4.01 × 10³ copies/m³ of air for total bacteria and 1.45 × 10¹ copies/m³ for Aspergillus/Penicillium. Median concentrations were 5.13 × 10⁴ copies/mg of dust, 5.07 × 10¹ copies/mg, 9.98 EU/mg for total bacteria, Aspergillus/Penicillium and endotoxin concentrations, respectively. The main microorganisms were associated with human occupancy such as skin-related bacteria or yeasts, regardless of the type of ventilation.     

Influence of organic liquids on the nanostructure of precipitated cellulose

Organic liquids have been used in pretreatments to improve the digestibility of lignocellulosic biomass, ultimately reducing the amount of enzyme required to digest the material to its constituent sugars. To understand the influence of these solvents on cellulose nanostructure, phosphoric acid was used to solubilize cellulose (PAS cellulose) followed by washing of the PAS cellulose with organic liquids previously demonstrated to aid pretreatment. PAS cellulose washed using methanol, ethanol, and ethylene glycol had gel‐like properties with disrupted nanostructures. PAS cellulose washed with acetone, 2‐propanol, and water yielded an opaque white precipitate. Small‐angle neutron scattering indicated the formation of loosely bundled rods of cellulose in the gel‐like material. Fourier transform infrared resonance of solvent‐washed, flash‐dried PAS cellulose suggested an increase in interchain hydrogen bonds in the gel‐like precipitates relative to the more obvious precipitates formed in other solvents. The optimal wash liquid was determined to be 40% by volume ethanol in water to induce a highly digestible, gel‐like material. © 2012 Wiley Periodicals, Inc. J. Appl. Polym. Sci., 2013     

Reduction of hygrothermal transverse stresses in unidirectional hybrid composites under cyclic environmental conditions

When fiber-reinforced polymer plates are exposed to cyclic environmental conditions, polymer matrix absorbs or desorbs continuously the moisture due to the variation in service temperature and relative humidity. Both temperature and moisture concentration produce an important hygrothermal transverse stresses, which are maximum on both edges of the composite plates. These transverse stresses which are more important at first times of moisture diffusion, can produce a probable damage of composite plates. To extend the durability of our composite plate, interplay hybrid composites are adopted to reduce the transverse stresses on edges. Therefore, a variation of the relationship between thicknesses of unidirectional hybrid composites constituents AS/3501-5 and T300/5208 is carried out in order to find minimal transverse stresses. This thicknesses variation enables us to find the best configuration which gives favourable service conditions of our hybrid composite, i.e., to predict firstly a considerable reduction of hygrothermal transverse stresses at both edges of our hybrid plate, secondly to reduce or to attenuate the edge effect developed in 6 days and 6 weeks periods.     

The mystery of clustering in macromolecular media

Clustering occurs in most polar media such as water-soluble macromolecules. The true origin of clustering has been elusive despite a great deal of research effort. This paper uses the simplest water-soluble polymer, poly(ethylene oxide), dissolved in deuterated water to investigate the cause of clustering. The small-angle neutron scattering technique is used to separate out solvation effects from clustering effects and back out the various interaction parameters. It is found that clustering is related to attractive inter-chain interactions between hydrophobic groups which create physical crosslinks thereby causing clustering.     

Service Mosaic: A Model-Driven Framework for Web Services Life-Cycle Management

Although Web services provide abstractions for simplifying integration at lower levels of the interaction stacks, they don't yet help simplify integration at higher abstraction levels such as business-level interaction protocols. Using a model-driven framework for Web services life-cycle management, the authors help facilitate the scalable development and maintenance of service-oriented applications by analyzing and managing Web service business protocols. Instead of using simple black and white measures,they identify different classes of protocol compatibility and replaceability. They implemented this framework in a prototype platform called Service Mosaic.     

Toward self-organizing service communities

This paper discusses a framework in which catalog service communities are built, linked for interaction, and constantly monitored and adapted over time. A catalog service community (represented as a peer node in a peer-to-peer network) in our system can be viewed as domain specific data integration mediators representing the domain knowledge and the registry information. The query routing among communities is performed to identify a set of data sources that are relevant to answering a given query. The system monitors the interactions between the communities to discover patterns that may lead to restructuring of the network (e.g., irrelevant peers removed, new relationships created, etc.).     

Web service conversation modeling: a cornerstone for e-business automation

Web services are emerging as a promising technology for effectively automating interorganizational interactions. However, despite the growing interest, several issues remain to be addressed to provide Web services with benefits similar to what traditional middleware brings to intraorganizational application integration. We identify a framework that builds on current standards to help developers define extended service models and richer Web service abstractions. The framework's main feature is a conversation metamodel derived from our analysis of e-commerce portal sites.     

Preparation of TiO2-pillared montmorillonite as photocatalyst Part I. Microwave calcination, characterisation, and adsorption of a textile azo dye

Two photocatalysts based on TiO₂-pillared intercalated montmorillonite have been prepared by microwave for 10 min at 700 W or by furnace heating at 673 K. Montmorillonite pillaring with TiO₂ increased the basal spacing to 14.7 Å (conventional heating) and 17.6 Å (microwave heating). XRD patterns of both materials showed the presence of 100% anatase with a slightly higher rate of crystallinity obtained through microwave calcination than by conventional heating at 673 K. The BET specific surface area of the microwave prepared photocatalyst (151 m² g^− 1) was 3 fold higher than those of the Degussa TiO₂ P25. At pH = 5.8, the maximum adsorption capacity of Solophenyl red 3BL (a textile azo dye) on the TiO₂-pillared montmorillonite calcined by microwave was 185 mg g^− 1, whereas it was 1.4 and 3 fold lower on the TiO₂-pillared montmorillonite calcined at 673 K, and on the Degussa TiO₂ P25 respectively. The influence of pH on the adsorption of the dye depended on the pH_ZPC of the pillared montmorillonites.     

The Self-Serv environment for Web services composition

Self-Serv aims to enable the declarative composition of new services from existing ones, the multiattribute dynamic selection of services within a composition, and peer-to-peer orchestration of composite service executions. Self-Serv adopts the principle that every service, whether elementary or composite, should provide a programmatic interface based on SOAP and the Web Service Definition Language. This does not exclude the possibility of integrating legacy applications, such as those written in CORBA, into the service's business logic. To integrate such applications, however, first requires the development of appropriate adapters. The paper considers how the mechanism for composing services in Self-Serv is based on two major concepts: the composite service and the service container.