A comparative study of accelerated weathering of epoxy resins based on DGEBA and HDGEBA

The durability of epoxy resins is an important factor in applications of composites to timber engineering. We carried out a comparative study of the effect of accelerated weathering on epoxy resins based on the glycidyl ether of bisphenol A (DGEBA) or hydrogenated diglycidyl ether of bisphenol A (HDGEBA) cured with 2,2,4-trimethylene-1,6-hexadiamine, using various characterization tools, including mechanical and thermal testing and SEM to evaluate the effect of exposure to UV light, moisture and elevated temperature cycles on the properties of the resins. Mechanical testing showed that after 6 months accelerated weathering reduced by 50% the tensile strength of DGEBA-TMDA while HDGEBA-TMDA epoxies lost slightly less strength over the same exposure period. Elongation at break increased after 6 months of accelerated weathering from 5.1?±?0.1% to 7.5?±?0.3% for DGEBA-TMDA epoxy specimens, and from 0.9?±?0.3% to 2.0?±?0.1% for HDGEBA-TMDA epoxy specimens. FTIR of the epoxies showed increases in the absorbance of hydroxyl and carbonyl groups for both epoxies on accelerated weathering, but the hydroxyl and carbonyl indexes reached values 90 and 40% higher respectively for DGEBA than HDGEBA-based epoxy resins. While susceptibility to accelerated weathering on the molecular scale was clearly greater for the DGEBA-based epoxy on the molecular scale, this did not translate into a significant deterioration in mechanical properties relative to HDGEBA over the time scale of the accelerated weathering experiments.     

Effect of soluble fibre (guar gum and carboxymethylcellulose) addition on technological, sensory and structural properties of durum wheat spaghetti

Incorporation in pasta of either of two soluble fibres, carboxymethylcellulose sodium salt (CMC) and guar gum (GG), was found to significantly reduce the rate of invitro starch digestion. The amount of reducing sugars produced over 300 min was reduced by 18% at 1.5% CMC incorporation and 24% at 20% GG incorporation. Negative effects on sensory and technological properties were seen at the high levels of GG needed to reduce the rate of in vitro digestion, and a ‘matty’ layer covering the surfaces of starch granules was observed by scanning electron microscopy and confocal scanning laser microscopy. By contrast, levels of CMC incorporation giving large reductions in in vitro digestion had no negative effects on pasta properties. No significant alteration in pasta structure on CMC incorporation was observed by microscopy. The large difference in the amounts of soluble fibre required to bring about equivalent reductions in digestion rate suggests that different mechanisms may be involved in the two cases.     

脉冲电流处理过程中的相变和再结晶细化晶粒(英文)

在室温下对铸态TiAl合金和冷轧TA15合金进行高密度脉冲电流处理。应用光学金相显微镜和透射电子显微镜研究脉冲电流处理前、后试样的显微组织。实验结果表明:通过脉冲电流处理可以细化铸态TiAl基合金的晶粒,从约1000μm的原始粗大层片组织,经脉冲电流处理后可以得到尺寸为3050μm细小、均匀的晶粒。对于冷轧TA15合金,脉冲电流处理后发生了完全的再结晶,晶粒组织由原始的α板条晶粒转变为细小的α等轴晶粒。研究结果表明,脉冲电流处理是一种有效的细化晶粒方法;由于不需要热机处理所要求的挤压等变形工序和高温加热、真空保护等条件,简化了工艺过程。     

Derivation of algorithms for cutwidth and related graph layout parameters

In this paper, we investigate algorithms for some related graph parameters. Each of these asks for a linear ordering of the vertices of the graph (or can be formulated as such), and constructive linear time algorithms for the fixed parameter versions of the problems have been published for several of these. Examples are cutwidth, pathwidth, and directed or weighted variants of these. However, these algorithms have complicated technical details. This paper attempts to present ideas in these algorithms in a different more easily accessible manner, by showing that the algorithms can be obtained by a stepwise modification of a trivial hypothetical non-deterministic algorithm. The methodology is applied to rederive known results for the cutwidth and the pathwidth problem, and obtain new results for several variants of these problems, like directed and weighted variants of cutwidth and modified cutwidth.     

On problems without polynomial kernels

Kernelization is a strong and widely-applied technique in parameterized complexity. A kernelization algorithm, or simply a kernel, is a polynomial-time transformation that transforms any given parameterized instance to an equivalent instance of the same problem, with size and parameter bounded by a function of the parameter in the input. A kernel is polynomial if the size and parameter of the output are polynomially-bounded by the parameter of the input.In this paper we develop a framework which allows showing that a wide range of FPT problems do not have polynomial kernels. Our evidence relies on hypothesis made in the classical world (i.e. non-parametric complexity), and revolves around a new type of algorithm for classical decision problems, called a distillation algorithm, which is of independent interest. Using the notion of distillation algorithms, we develop a generic lower-bound engine that allows us to show that a variety of FPT problems, fulfilling certain criteria, cannot have polynomial kernels unless the polynomial hierarchy collapses. These problems include k-Path, k-Cycle, k-Exact Cycle, k-Short Cheap Tour, k-Graph Minor Order Test, k-Cutwidth, k-Search Number, k-Pathwidth, k-Treewidth, k-Branchwidth, and several optimization problems parameterized by treewidth and other structural parameters.     

In‐Situ Monitoring of the Solid‐State Microstructure Evolution of Polymer:Fullerene Blend Films Using Field‐Effect Transistors

Organic field‐effect transistors (OFETs) are used to investigate the evolution of the solid‐state microstructure of blends of poly(3‐hexylthiophene) (P3HT) and [6,6]‐phenyl C₆₁‐butyric acid methyl ester (PC₆₁BM) upon annealing. Changes in the measured field‐effect mobility of holes and electrons are shown to reveal relevant information about the phase‐segregation in this system, which are in agreement with a eutectic phase behavior. Using dual‐gate OFETs and in‐situ measurements, it is demonstrated that the spatial‐ and time‐dependence of microstructural changes in such polymer:fullerene blend films can also be probed. A percolation‐theory‐based simulation is carried out to illustrate how phase‐segregation in this system is expected to lead to a substantial decrease in the electron conductivity in an OFET channel, in qualitative agreement with experimental results.     

W-Hierarchies Defined by Symmetric Gates

The classes of the W-hierarchy are the most important classes of intractable problems in parameterized complexity. These classes were originally defined via the weighted satisfiability problem for Boolean circuits. Here, besides the Boolean connectives we consider connectives such as majority, not-all-equal, and unique. For example, a gate labelled by the majority connective outputs true if more than half of its inputs are true. For any finite set C\mathcal{C} of connectives we construct the corresponding W( C\mathcal{C} )-hierarchy. We derive some general conditions which guarantee that the W-hierarchy and the W( C\mathcal{C} )-hierarchy coincide levelwise. If C\mathcal{C} only contains the majority connective then the first levels of the hierarchies coincide. We use this to show that a variant of the parameterized vertex cover problem, the majority vertex cover problem, is W[1]-complete.     

Encapsulation of Drug Molecules by Cucurbiturils: Effects on their Chemical Properties in Aqueous Solution

The effects of the encapsulation of drugs and other molecules of biomedical interest by cucurbit[n]uril (n=5–8, 10) host molecules on the chemical properties of the drugs in aqueous solution are reviewed. The cucurbituril complexation of drug molecules has been shown to generally increase the guests’ pK_a values through preferential inclusion of the protonated species, modulate other equilibria involving the guest, improve the solubility in aqueous solution, reduce the toxicity and other side effects, as well as enhance the stability and targeted delivery of the drug molecule. These benefits have led to an increasing interest in the applications of cucurbit[n]urils in novel drug formulations.     

Behaviour of quantity surveyors as organizational citizens

Understanding the individual's collectivistic orientations toward group goals and task activities is critical for developing cooperative and productive teams. The complex environment of modern construction, where the emphasis shifts from individually oriented to team‐based work, has led to many challenges. There are important issues of cooperative behaviours in a world of cultural pluralism in which interpersonal cooperation is juxtaposed with organizational citizenship behaviour. Behaviours of construction project participants are important manifestations of culture that are dependent upon norms, values and beliefs. Certain organizational cultures support individualistic behaviours while others emphasize the benefits to the collective whole. Collectivistic orientation is examined as the cultural dimension of individualism‐collectivism (IC) and found to be related to organizational citizenship behaviour (OCB) where the correlations of IC and most OCB variables are significant for quantity surveyors in Hong Kong. Generally, the (more) individualistic persons are less likely to exhibit organizational citizenship behaviours.