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1.
K. Naveen Kumar L. Vijayalakshmi Hyeongyu Bae Kang Taek Lee Pyung Hwang Jungwook Choi 《Ceramics International》2021,47(4):4563-4571
Yb3+/Er3+codoped La10W22O81 (LWO) nanophosphor rods have been successfully synthesized by a facile hydrothermal assisted solid state reaction method, and their upconversion photoluminescence properties were systematically studied. X-ray diffraction patterns revealed that the nanophosphors have an orthorhombic structure with space group Pbcn (60). A microflowers-like morphology with irregular hexagonal nanorods was observed using field emission scanning electron microscopy for the Yb3+(2 mol%)/Er3+(2 mol%):LWO nanophosphor. The shape and size of the nanophosphor and the elements along with their ionic states in the material were confirmed by TEM and XPS studies, respectively. A green upconversion emission was observed in the Er3+: LWO nanophosphors under 980 nm laser excitation. A significant improvement in upconversion emission has been observed in the Er3+: LWO nanophosphors by increasing the Er3+ ion concentration. A decrease in the upconversion emission occurred due to concentration quenching when the doping concentration of Er3+ ions was greater than 2 mol%. An optimized Er3+(2 mol%): LWO nanophosphor exhibited a strong near infrared emission at 1.53 μm by 980 nm excitation. The green upconversion emission of Er3+(2 mol%): LWO was remarkably enhanced by co-doping with Yb3+ ions under 980 nm excitation because of energy transfer from Yb3+ to Er3+. The naked eye observed this upconversion emission when co-doping with 2 mol% Yb3+. In order to obtain the high upconversion green emission, the optimized sensitizer concentration of Yb3+ ions was found to be 2 mol%. The upconversion emission trends were studied as a function of stimulating laser power for an optimized sample. Moreover, the NIR emission intensity has also been enhanced by co-doping with Yb3+ ions due to energy transfer from Yb3+ to Er3+. The energy transfer dynamics were systematically elucidated by energy level scheme. Colorimetric coordinates were determined for Er3+ and Yb3+/Er3+: LWO nanophosphors. The energy transfer mechanism was well explained and substantiated by several fluorescence dynamics of upconversion emission spectra and CIE coordinates. The results demonstrated that the co-doped Yb3+(2 mol%)/Er3+(2 mol%): LWO nanophosphor material is found to be a suitable candidate for the novel upconversion photonic devices. 相似文献
2.
Ji Bong Choi Yong Seok Jang Seon Mi Byeon Jong Hwa Jang Yu Kyoung Kim Tae Sung Bae 《国际聚合物材料杂志》2019,68(6):328-337
We report the use of poly(ε-caprolactone) (PCL) and poly-dopamine (PD) as a protective coating that inhibits corrosion of the underlying magnesium metal. The PD coating layer also improved the adhesion of the PCL layer, which has been found to have a significant effect on corrosion behavior. In this study, electrochemical methods were employed to investigate the corrosion behavior of Mg after applying PCL composite coatings. Potentiodynamic polarization measurements determined that the PCL coating pretreated with PD effectively inhibited metal corrosion. In addition, the coating layer with improved adhesion has shown the possibility of inhibiting metal corrosion. 相似文献
3.
Muhammad Sheeraz Mamoon Ur Rashid Asad Ali Fazli Akram Ho Jeong Lee Jin San Choi Jong-Seong Bae Yong Soo Kim Young-Han Shin Chang Won Ahn Tae Heon Kim 《Journal of the European Ceramic Society》2021,41(10):5155-5162
We demonstrate the structural evolution of polymorphic phases in Al2O3-inserted SrMnO3 ceramics synthesized by solid state reaction. While the 4H-hexagonal phase is predominant in pure SrMnO3 ceramics, a small amount of 6H-hexagonal polymorph is identified in addition to the primary 4H-hexagonal SrMnO3 and the secondary hexagonal SrAl2O4 phases in the as-sintered ceramics, evidenced by x-ray diffraction and subsequent Rietveld refinement analyses. The existence of the 6H-hexagonal SrMnO3 phase is corroborated using Raman spectroscopy. The chemical compositions and electronic structures of the Al2O3-inserted SrMnO3 compounds are also examined using energy dispersive spectroscopy and x-ray photoelectron spectroscopy, respectively. The first-principles calculations reveal that there is no clear difference between the total energies of 4H- and 6H-hexagonal polymorphs regardless of the presence/absence of Sr and oxygen vacancies. Possible origins are discussed with the estimation of actual strain based on the refined lattice parameter of 6H SrMnO3. 相似文献
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Chun Dong Hyun Rhim Geun Bae Youn Min Hye Deviana Deviana Lee Ji Eun Park Ji Chan Jeong Heondo 《Topics in Catalysis》2020,63(9-10):793-809
Topics in Catalysis - Fischer–Tropsch synthesis (FTS) is a promising way to produce clean liquid fuels and high value-added chemicals from low-value carbon-containing resources such as coal,... 相似文献
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Water Resources Management - The present study considered the impacts of global climate model (GCM) selection in the Couple Model Intercomparison Phase 5 (CMIP5) scenarios on the low-flow... 相似文献
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Gait analysis is an effective clinical tool across a wide range of applications. Recently, inertial measurement units have been extensively utilized for gait analysis. Effective gait analyses require good estimates of heel‐strike and toe‐off events. Previous studies have focused on the effective device position and type of triaxis direction to detect gait events. This study proposes an effective heel‐strike and toe‐off detection algorithm using a smart insole with inertial measurement units. This method detects heel‐strike and toe‐off events through a time‐frequency analysis by limiting the range. To assess its performance, gait data for seven healthy male subjects during walking and running were acquired. The proposed heel‐strike and toe‐off detection algorithm yielded the largest error of 0.03 seconds for running toe‐off events, and an average of 0–0.01 seconds for other gait tests. Novel gait analyses could be conducted without suffering from space limitations because gait parameters such as the cadence, stance phase time, swing phase time, single‐support time, and double‐support time can all be estimated using the proposed heel‐strike and toe‐off detection algorithm. 相似文献
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Multimedia Systems - The preferences of Web information purchasers are changing. Cost-effectiveness (i.e., an emphasis on performance with respect to price) is becoming less regarded than... 相似文献