Metal–Organic Frameworks Based on Group 3 and 4 Metals

Metal–organic frameworks (MOFs) based on group 3 and 4 metals are considered as the most promising MOFs for varying practical applications including water adsorption, carbon conversion, and biomedical applications. The relatively strong coordination bonds and versatile coordination modes within these MOFs endow the framework with high chemical stability, diverse structures and topologies, and interesting properties and functions. Herein, the significant progress made on this series of MOFs since 2018 is summarized and an update on the current status and future trends on the structural design of robust MOFs with high connectivity is provided. Cluster chemistry involving Y, lanthanides (Ln, from La to Lu), actinides (An, from Ac to Lr), Ti, and Zr is initially introduced. This is followed by a review of recently developed MOFs based on group 3 and 4 metals with their structures discussed based on the types of inorganic or organic building blocks. The novel properties and arising applications of these MOFs in catalysis, adsorption and separation, delivery, and sensing are highlighted. Overall, this review is expected to provide a timely summary on MOFs based on group 3 and 4 metals, which shall guide the future discovery and development of stable and functional MOFs for practical applications.     

Pellicle formation,microbial succession and lactic acid utilisation during the aerobic deteriorating process of Sichuan pickle

The pellicles formation, microbial changes and lactic acid utilisation during the aerobic deterioration of Sichuan pickle were discussed in this study. By plate counting, chemical detection and HPLC analysis, the aerobic deterioration of Sichuan pickle was featured by microbial growth, pellicle formation, lactic acid decrease and pH elevation. Bacteria dominated in pellicles and the pellicles present morphological change from smooth to wrinkly along with the aerobic deteriorating process. Nine species of bacteria were identified and responsible for the pellicle formation. Combined with Lactobacillus plantarum, eight pellicle‐forming bacteria were the dominant lactic acid consuming organisms in deteriorating Sichuan pickle. Especially under the harsh acid condition of the early deteriorating period, Lb. plantarum, pellicle‐forming bacteria Bacillus amyloliquefaciens, B. subtilis and Citrobacter freundii participated in the pellicles, utilised lactic acid and increased the brine pH effectively. Sequence analysis of 16S rDNA libraries suggested that the resulting pH of 4.8–5.0 initiated the growth of more undesirable organisms, and the pellicle bacterial diversity changed greatly compared with that in the early deteriorating period. The study indicated the important role of pellicles in the initiation of Sichuan pickle's aerobic deterioration and enhanced our ability to understand and potentially control the aerobic deterioration.     

Textural quality of sweet dumpling: effect of germination of waxy rice

Effects of germination on components and structural changes of rice flours and, in turn, rheological properties and textural attributes of sweet dumplings were investigated in this study. Germination decreased starch, protein and lipid content, while slightly increased free amino acids content. Starch granular surface corroded, crystalline structure disrupted, and short-range ordered structures and helical structures decreased with germination. Moreover, germination resulted in a decreased paste viscosity and gel intensity of flour and a reduction of hardness and adhesiveness of dumplings. According to the Pearson’s correlation analysis, flours components and starch structures were significantly correlated with flours rheological properties that determined textural attributes of sweet dumplings. The germination contributed to significant changes in flours components and starch structures, which suggested the pretreatment of germination of waxy rice could be a promising pathway to control textural properties of sweet dumplings.     

A Close Look at the Urban Planning and Development in Asia——A Review on Asian Cities: Planning and Development

正Asian Cities:Planning and Development Editors:Wu Jiang, Zhang Fan, Sha Yongjie, Xia Liping Year:2018 Publisher:Tongji University Press ISBN:9787560875774 1. Publishing background The Asian Cities:Planning and Development edited by Prof. Wu     

Mesoporous Nanoarchitectures for Electrochemical Energy Conversion and Storage

Mesoporous materials have attracted considerable attention because of their distinctive properties, including high surface areas, large pore sizes, tunable pore structures, controllable chemical compositions, and abundant forms of composite materials. During the last decade, there has been increasing research interest in constructing advanced mesoporous nanomaterials possessing short and open channels with efficient mass diffusion capability and rich accessible active sites for electrochemical energy conversion and storage. Here, the synthesis, structures, and energy-related applications of mesoporous nanomaterials are the main focus. After a brief summary of synthetic methods of mesoporous nanostructures, the delicate design and construction of mesoporous nanomaterials are described in detail through precise tailoring of the particle sizes, pore sizes, and nanostructures. Afterward, their applications as electrode materials for lithium-ion batteries, supercapacitors, water-splitting electrolyzers, and fuel cells are discussed. Finally, the possible development directions and challenges of mesoporous nanomaterials for electrochemical energy conversion and storage are proposed.     

基于TL494 升压型DC-DC 稳压电源的设计

根据开关电源在各种电子产品中的发展趋势,介绍一种12 V转24 V的升压型DC-DC稳压电源。该电源采用TL494作为控制器件,根据其工作原理,合理选择了电源中的开关管、滤波电容、储能电感和续流二极管的参数设计,利用脉冲宽度调制技术进行电路控制,并通过控制开关管的导通时间,保持输出电压的稳定。仿真测试结果表明:该电路输出电压满载时变换效率大于70%,具有较高的安全性和可靠性。     

多级数字抽取滤波器的结构与应用

本文介绍了多级数字抽取滤波器CS5376A的特点及结构,分析了CS5376A芯片的参数设定、以及配合CS5371/72Delta-SigmaA/D转换器和TMS320LF2407DSP构成高精度数据采集系统应用于数字强震仪中的方法。     

大岩淌滑坡的弹粘塑性自适应有限元分析

应用弹粘塑性自适应有限元方法，对大岩淌滑坡进行了变形与稳定分析。主滑带采用节理元模拟，当滑坡土体出现拉剪屈服区或具有临空面的压剪屈服区时，沿拉剪屈服区的前缘或压剪屈服区的后缘自动加密网格且采用节理元模拟，搜寻新的开裂面，以判断滑坡体是否会产生新的滑动破坏模式。经计算分析，大岩淌边坡的破坏模式是整体破坏，其整体安全系数约为1．143，不存在新的局部滑动破坏模式。