Boosted hydrogen evolution activity from Sr doped ZnO/CNTs nanocomposite as visible light driven photocatalyst

CNTs were decorated onto Sr doped ZnO nanoparticles to construct an efficient photocatalyst via a facile sol-gel method. The as-fabricated Sr doped ZnO/CNTs with recyclability exhibits Sr and CNTs content dependent hydrogen evolution activit under visible light illumination. The Sr doped ZnO/CNTs photocatalyst shows the highest hydrogen evolution rate of 2732.2 μmolh^?1g^?1, which is 33.7 and 2.83 times higher than pure ZnO and Sr doped ZnO photocatalysts, respectively. The improved hydrogen evolution activity of Sr doped ZnO/CNTs is primarily assigned to high surface area, Sr doping and construction of heterojunction, which can extend the light absorption, decrease the optical band gap and improve the charge separation. Moreover, the underlying photocatalytic mechanism is proposed on the basis of Mott-Schottky study and explains the interfacial charge transfer process from ZnO to CNTs and Sr. This work open new strategies to synthesize CNTs based nanocomposite for hydrogen evolution.     

Elliptical slot based polarization insensitive compact and flexible chipless RFID tag

A miniaturized, polarization insensitive, and fully passive chipless radio frequency identification tag is proposed in this research article. The realized tag is based on slotted elliptical structures in a nested loop fashion with identical lengths and widths of slot resonators. Alteration of data sequence is accomplished by addition and elimination of nested resonators in the geometric structure. The tag is capable to encode 10 bits of data and covers spectral range from 3.6 to 15.6 GHz. The formulated structure demonstrates polarization insensitive characteristic. The data encoding structure is analyzed and optimized for different substrates that are, Rogers RT/duroid/5880, Rogers RT/duroid/5870, and Taconic TLX‐0 over the miniaturized footprint of 22.8 × 16 mm². The presented tag is robust, novel, compact, and flexible exhibiting a stable response to impinging electromagnetic waves at various angles of incidence.     

Selenium (Se) improves drought tolerance in crop plants – a myth or fact?

Climate change has emerged as one of the most complex challenges of the 21st century and has become an area of interest in the past few decades. Many countries of the world have become extremely vulnerable to the impacts of climate change. The scarcity of water is a serious concern for food security of these countries and climate change has aggravated the risks of extreme events like drought. Oxidative stress, caused by a variety of active oxygen species formed under drought stress, damages many cellular constituents, such as carbohydrates, lipids, nucleic acids and proteins, which ultimately reduces plant growth, respiration and photosynthesis. Se has become an element of interest to many biologists owing to its physiological and toxicological importance. It plays a beneficial role in plants by enhancing growth, reducing damage caused by oxidative stress, enhancing chlorophyll content under light stress, stimulating senesce to produce antioxidants and improving plant tolerance to drought stress by regulating water status. Researchers have adopted different strategies to evaluate the role of selenium in plants under drought stress. Some of the relevant work available regarding the role of Se in alleviating adverse effect of drought stress is discussed in this paper. © 2015 Society of Chemical Industry     

Force Transmission Error Analysis for a High-Pressure Single-Sinker Magnetic Suspension Densimeter

The magnetic suspension densimeter (MSD) is a sophisticated, state-of-the-art device that provides extremely accurate results for density measurements. The MSD uses a magnetic technique to couple a mass inside a measurement cell with an external mass balance for mass measurement. This article presents a force transmission error (FTE) analysis for a high-pressure, single-sinker MSD. Due to the magnetic working principle of the apparatus, magnetic properties of the high-pressure cell and external magnetic fields affect the measurements slightly. For the analysis, McLinden et al. suggest making measurements using two different sinkers, a titanium sinker and a copper sinker, having the same mass. The measurements cover densities for methane, ethane, carbon dioxide and nitrogen over the temperature range from 265 K to 450 K (±5 mK stability) up to 180 MPa (uncertainty of 0.01 % full scale: 200 MPa). Comparing and manipulating the measurements permit determination of apparatus and fluid specific effects that contribute to the FTE. For this MSD, the apparatus effect is about 200 ppm, which effectively masks any fluid specific effect. A comprehensive analysis of the FTE produces a uniform deviation for density values of about 0.05 % at 2σ across the full range of pressure.     

Prediction of in-service microstructural degradation of A106 steel using eddy current technique

In-service microstructural degradation of ASTM A106 steel occurs by the spheroidising and coarsening of pearlite. The specimens of the A106 have been exposed at 710 °C for different durations to simulate service conditions. The resultant pearlite coarsening was evaluated by measuring eddy current inductive reactance and resistance; phase angles were measured using these values and compared with results of optical microscopy, image analysis and resistivity measurements. It was observed that the eddy current phase angle has a linear relation with pearlite variations. It can further be used for in-situ eddy current evaluation of microstructural degradation of pipes or steel vessels. A mathematical model has been proposed to assist such field investigations.     

Antioxidant and anticholinesterase evaluation of selected Turkish Salvia species

Since Salvia species (Lamiaceae) have been recorded to be used against memory loss in European folk medicine, we herein examined in vitro anticholinesterase and antioxidant activities of 56 extracts prepared with petroleum ether, chloroform, ethyl acetate and methanol obtained from 14 Salvia species (Salvia albimaculata Hedge and Hub, Salvia aucheri Bentham var. canescens Boiss and Heldr, Salvia candidissima Vahl. ssp. occidentalis, Salvia ceratophylla L., Salvia cryptantha Montbret and Bentham, Salvia cyanescens Boiss and Bal., Salvia frigida Boiss, Salvia forskahlei L., Salvia halophilaHedge, Salvia migrostegia Boiss and Bal., Salvia multicaulis Vahl., Salvia sclarea L., Salvia syriaca L., Salvia verticillata L. ssp. amasiaca) growing in Turkey. The antioxidant activities were assessed by both chemical and enzymatic methods against 1,1-diphenyl-2-picrylhydrazyl (DPPH) radical-scavenging and xanthine/xanthine oxidase (XO) system generated superoxide anion radical inhibition. Anticholinesterase effect of the extracts was tested against both acetylcholinesterase (AChE) and butyrylcholinesterase (BChE) at concentrations of 0.2 and 1 mg/ml using a microplate-reader assay based on the Ellman method. Most of the extracts did not show any activity against AChE at 0.2 mg/ml, while the chloroform extracts had noticeable inhibition against BChE between 47.7% and 74.7%. The most active extracts at 1 mg/ml for AChE inhibition were observed to be petroleum ether extract of Salvia albimaculata (89.4%) and chloroform extract of Salvia cyanescens (80.2%), whereas ethyl acetate extracts of Salvia frigida and Salvia migrostegia, chloroform extracts of Salvia candidissima ssp. occidentalis and Salvia ceratophylla, as well as petroleum ether extract of Salvia cyanescens were found to inhibit potently BChE (92.2%, 89.6%, 91.1%, 91.3%, and 91.8%, respectively). Particularly, the ethyl acetate and methanol extracts were observed to be highly active against both DPPH and XO. Our data indicates that nonpolar extracts of Salvia species for anticholinesterase activity and the polar extracts for antioxidant activity are worth further phytochemical evaluation for identifying their active components.     

Variable VCC design techniques forbattery-operated DRAMs

Wide-voltage-range DRAMs with extended data retention are desirable for battery-operated or portable computers and consumer devices. The techniques required to obtain wide operation, functionality, and performance of standard DRAMs from 1.8 V (two NiCd or alkaline batteries) to 3.6 V (upper end of LVTTL standard) are described. Specific techniques shown are: (1) a low-power and low-voltage reference generator for detecting V_CC level; (2) compensation of DC generators, V_BB and V_PP, for obtaining high speed at reduced voltages; (3) a static word-line driver and latch-isolation sense amplifier for reducing operating current; and (4) a programmable V_CC variable self-refresh scheme for obtaining maximum data retention time over a full operating range. A sub-50-ns access time is obtained for a 16 M DRAM (2 M×8) by simulation     

Biofilm reduction,cell proliferation,anthelmintic and cytotoxicity effect of green synthesised silver nanoparticle using Artemisia vulgaris extract

Infectious diseases are caused by etiological agents. Nanotechnology has been used to minimise the effect of clinical pathogens which have resistance to antibiotics. In current research synthesis, characterisation and biological activities of green synthesised nanoparticles using Artemisia vulgaris extract have been done. The characterisation of AgNPs was carried out using Fourier transform infrared spectroscopy, UV‐Vis spectrophotometry, and scanning electron microscopy. Anti‐biofilm, cell viability, antibacterial, brine shrimp lethality, and deoxyribonucleic acid protection effects have been screened. UV‐Vis spectra showed the absorption peak of synthesised nanoparticles at 400 nm. FT‐IR indicated the involvement of the functional group in the preparation of AgNPs. SEM showed the spherical shape of AgNPs with 30 nm diameter. Biological screening results revealed the antibacterial effect against clinical bacterial pathogens. Biofilm reduction and cell viability assay also supported the antibacterial effect. Cytotoxicity effect was recorded as 100% at 200 μg/ml through brine shrimp lethality assay. Protein kinase inhibition zones recorded for AgNPs (16 mm bald) compared with A. vulgaris extract (11 mm bald). It has been concluded that green synthesised AgNPs are more effective against infectious pathogens and could be used as a potential source for therapeutic drugs.Inspec keywords: cellular biophysics, toxicology, silver, nanoparticles, nanomedicine, diseases, microorganisms, ultraviolet spectra, visible spectra, Fourier transform infrared spectra, enzymes, molecular biophysicsOther keywords: biofilm reduction, cell proliferation, anthelmintic effect, cytotoxicity effect, green synthesised silver nanoparticle, Artemisia vulgaris extract, infectious diseases, aetiological agents, Fourier transform infrared spectroscopy, UV‐Vis spectrophotometry, scanning electron microscopy, SEM, antibiofilm, cell viability, brine shrimp lethality, deoxyribonucleic acid protection effects, AgNP, cytotoxicity, protein kinase inhibition zones, therapeutic drugs