Rapid Aging as a Key to Understand Deactivation of Ni/Al2O3 Catalysts Applied for the CO2 Methanation

Catalysis Letters - We developed a rapid aging method for Ni/Al2O3 methanation catalysts mimicking the real aging in the actual application. The method is based on hydrothermal deactivation of the...     

Spatio-temporal evolution of the deformation around the Rio-Patras fault (Greece) observed by synthetic aperture radar interferometry from 1993 to 2017

We analysed the ground deformation across two blocks defined by the Rio-Patras fault from 1993 to 2017 using multi-temporal Synthetic Aperture Radar Interferometry (InSAR) techniques. Our main objective was to contribute to the assessment of seismic hazard near the large city of Patras. Multiple data-sets were used, each one covering different temporal periods. Descending and ascending acquisitions, providing different viewing geometries contribute to fully determine the ground displacement in 3D. The data-sets used are from the European Space Agency’s (ESA) European Remote Sensing (ERS), Environmental Satellite (ENVISAT) and SENTINEL-1 as well as German Aerospace Center (DLR) ’s TERRASAR-X missions. Considering ESA’s missions covering both acquisition geometries and long periods, the southern block, showing lack of a sufficient number of scatterers does not allow the displacement characterization. In contrary, the northern block is characterized by a high number of scatterers having values of maximum likehood ranging from ?3.5 to ?4.3 mm year^?1 for ascending geometry and from ?1.6 to ?2.7 mm year^?1 for the descending one. The fact that both geometries show negative values of displacements are consistent with downlift movement and at the same time the quantitative differentiation probably indicates an horizontal component as well.     

Investigations on the Corrosion Properties of Sn–1Cu–1Ni–xAg Lead Free Solders in 3.5% NaCl Solution

Protection of Metals and Physical Chemistry of Surfaces - Due to the directions and environmental legislations from RoHS (Restrictions of Hazardous Substances), WEEE (World Electrical and...     

Three-dimensional weft-knitted textile fabrics-based capacitors

Wearable electronics have evolved from electronic components secured on the human body with straps and belts to partial electronic components integration onto textile structures. Cables and standard components defeat the purpose of the wearable approach by being bulky, rigid and especially not being able to withstand standard textile cleaning/care methods (washing, dry-cleaning, etc.). New 3D textile structures can provide a promising solution. In this research project, we examined the capacitive behaviour of specially prepared 3D weft knitted textile fabrics. The samples knitted specially for this project incorporated conductive outer layers and an insulating inner layer. The outer layers form the plates of the capacitor and the insulating layer plays a role of the dielectric material between the two plates. The structure of these 3D knits allows for inherent capacitive behaviour of the material. These 3D weft-knitted fabrics can be produced on usual existing knitting machines, without any need of dedicated, specialized or expensive equipment. The expected values of the capacitance, based on theoretical calculations, satisfactorily approach the values derived from the measuring process. The ability to customize the structure and hence the capacitance of the 3D fabrics-based capacitors is a positive point towards the design of the textile-based electronics systems in the future. Therefore, the development of textile capacitors based on the 3D fabrics is expected to be an essential contribution to the integration of the wearable system concept.     

Design of biorefinery systems for conversion of corn stover into biofuels using a biorefinery engineering framework

Unlocking the potential and value of lignocellulosic residues is an important step in making biorefineries economically and environmentally promising. This calls for a holistic and systematic approach in designing sustainable industrial systems. In this work, biorefinery systems via biochemical route (acetone–butanol–ethanol or ABE system) and thermochemical route (gasification and mixed alcohols or GMA system) for converting corn stover into biofuels have been designed using a Sustainable Engineering Framework. The framework involves eight main steps: (1) design problem definition, (2) data collection, (3) process synthesis and simulation, (4) process integration, (5) resource recovery from residues, (6) utility system design, (7) economic and environmental modelling and (8) economic value and environmental impact margin analysis for decision making. Consideration of resource recovery from biorefinery waste streams has proven to be the key in making biorefineries self-sustaining and with low environmental impacts. Simultaneous economic and environmental feasibility assessment at the early stage of process design is highly envisaged. The cost of biofuel production in the ABE system has been found to be 49.2 US$/GJ and 69.9 US$/GJ in the GMA system. The greenhouse gas emissions are 46.2 g CO₂-eq/GJ for ABE and 19.0 g CO₂-eq/GJ for GMA, lower than gasoline (85 g CO₂-eq/GJ). The GMA system is not economically compelling though with high environmental benefit, while the ABE system has shown to be both economically and environmentally feasible.     

The potential of surface water utilization for domestic purposes in Jordan

Two main problems seem to face the use of surface water for domestic purposes in semi‐arid regions. These problems are eutrophication of surface water bodies and the formation of chlorinated hydrocarbons during water treatment. Both problems develop as direct of indirect results of anthropogenic activities. The eutrophication problem will be discussed with reference to King Talal Reservoir, whereas the formation of chlorinated hydrocarbons will be illustrated when discussing the use of the East Ghor Canal water for domestic purposes.     

Gradient material mechanics: Perspectives and Prospects

This is a modest contribution dedicated to the work and virtue of George Weng, a prominent figure in material mechanics and a dear intellectual friend. The paper starts with the basics of gradient theory as applied to elasticity, plasticity and dislocation dynamics by introducing weak non-locality in the constitutive equations through Laplacian terms and corresponding deterministic internal lengths (ILs) characterizing the dominant deformation mechanisms. It then considers the interaction of such deterministic ILs with surface effects associated with internal or external surfaces, as well as stochastic effects associated with pre-existing or deformation-induced random microstructures. Experimentally observed stress drops and strain bursts are interpreted through combined gradient-stochastic models. Statistical features of corresponding deformation processes that cannot be fitted with Boltzmann–Gibbs–Shannon entropy statistics are interpreted by Tsallis q-entropy statistics. Some benchmark novel experiments for the direct determination of ILs for plasticity (by testing bulk specimens with gradient grain size) and dislocation dynamics (by testing thin films in TEM with gradient dislocation density) are proposed.