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1.
An addition of boron largely increases the ductility in polycrystalline high-temperature Co–Re alloys. Therefore, the effect of boron on the alloy structural characteristics is of high importance for the stability of the matrix at operational temperatures. Volume fractions of ε (hexagonal close-packed—hcp), γ (face-centered cubic—fcc) and σ (Cr2Re3 type) phases were measured at ambient and high temperatures (up to 1500 °C) for a boron-containing Co–17Re–23Cr alloy using neutron diffraction. The matrix phase undergoes an allotropic transformation from ε to γ structure at high temperatures, similar to pure cobalt and to the previously investigated, more complex Co–17Re–23Cr–1.2Ta–2.6C alloy. It was determined in this study that the transformation temperature depends on the boron content (0–1000 wt. ppm). Nevertheless, the transformation temperature did not change monotonically with the increase in the boron content but reached a minimum at approximately 200 ppm of boron. A probable reason is the interplay between the amount of boron in the matrix and the amount of σ phase, which binds hcp-stabilizing elements (Cr and Re). Moreover, borides were identified in alloys with high boron content.  相似文献   
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In software engineering, modeling with unified modeling language and object constraint language became industry standards and are supported by many computer-aided software engineering tools. The increasing number of the modeled functionalities results in complex models that need more and more textual constraints to express the hidden restrictions applied to the systems. During the metamodel development, rebuilding all the constraints is unnecessary when only a few changes have been applied due to the iterative, incremental manner of modifications. In this paper, we present a family of algorithms that handles the changes in constraints incrementally on the expression level; thus, the required rebuilds are kept to a minimum. Incremental variable reference resolving and type checking are performed as a part of the incremental semantic analysis. Balancing between the incremental and standard compilation is also considered, heuristics are given to select the faster method of compilation at each iteration. With the achieved results the duration of metamodel development can be decreased; thus, the efficiency of the environment is improved.  相似文献   
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Phenylalanine ammonia‐lyase (PAL), found in many organisms, catalyzes the deamination of l ‐phenylalanine (Phe) to (E)‐cinnamate by the aid of its MIO prosthetic group. By using PAL immobilized on magnetic nanoparticles and fixed in a microfluidic reactor with an in‐line UV detector, we demonstrated that PAL can catalyze ammonia elimination from the acyclic propargylglycine (PG) to yield (E)‐pent‐2‐ene‐4‐ynoate. This highlights new opportunities to extend MIO enzymes towards acyclic substrates. As PG is acyclic, its deamination cannot involve a Friedel–Crafts‐type attack at an aromatic ring. The reversibility of the PAL reaction, demonstrated by the ammonia addition to (E)‐pent‐2‐ene‐4‐ynoate yielding enantiopure l ‐PG, contradicts the proposed highly exothermic single‐step mechanism. Computations with the QM/MM models of the N‐MIO intermediates from l ‐PG and l ‐Phe in PAL show similar arrangements within the active site, thus supporting a mechanism via the N‐MIO intermediate.  相似文献   
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Biohydrogen production from synthetic wastewater as substrate was studied in anaerobic small scale batch reactors. Enriched anaerobic mixed consortia sampled from various environments were used as parent inocula to start the bioreactors. Selective enrichments were achieved by various physical and chemical pretreatments and changes in the microbial communities were monitored by metagenomic and molecular diagnostics approaches. Experimental data showed the feasibility of biohydrogen production using synthetic wastewater as substrate. The hydrogen generation capability of the different mixed consortia is clearly dependent on the pretreatment methods. The described approach opens the possibility for an alternative way towards simultaneous wastewater treatment and renewable energy generation.  相似文献   
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The increasing popularity of both small and large private clouds and expanding public clouds poses new requirements to data center (DC) architectures. First, DC architectures should be incrementally scalable allowing the creation of DCs of arbitrary size with consistent performance characteristics. Second, initial DC deployments should be incrementally expandable supporting small-scale upgrades without decreasing operation efficiency. A DC architecture possessing both properties satisfies the requirement of free-scaling.Recent work in DC design focuses on traditional performance and scalability characteristics, therefore resulting in symmetric topologies whose upgradability is coarse-grained at best. In our earlier work we proposed Scafida, an asymmetric, scale-free network inspired DC topology which scales incrementally and has favorable structural characteristics. In this paper, we build on Scafida and propose a full-fledged DC architecture achieving free-scaling called FScafida. Our main contribution is threefold. First, we propose an organic expansion algorithm for FScafida; this combined with Scafida’s flexible original design results in a freely scalable architecture. Second, we introduce the Effective Source Routing mechanism that provides near-shortest paths, multi-path and multicast capability, and low signaling overhead by exploiting the benefits of the FScafida topology. Third, we show based on extensive simulations and a prototype implementation that FScafida is capable of handling the traffic patterns characteristic of both enterprise and cloud data centers, tolerates network equipment failures to a high degree, and allows for high bisection bandwidth.  相似文献   
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