Identification of valence shifts in Au during the water-gas shift reaction

In situ X-ray absorption spectroscopy (XAS) has been performed to investigate the active site on Au-based catalysts in the water-gas shift (WGS) reaction. The surface area and hence the WGS activity is higher for AuTiO₂ catalysts supported on carbon nanofibres (CNF) than TiO₂. The WGS reaction rate depends on the Au coordination number with an apparent maximum close to eight which corresponds to a particle size of approximately 2.5–3.0 nm. A likely cause for the changes in the electronic structure of Au is the adsorption of CO on the surface, which also creates a small positive charge in the Au atoms. The catalytic activity significantly improves when titania is present compared to Au deposited directly on CNF.     

Effects of carbon content and solidification rate on thermal conductivity of grey cast iron

The thermal conductivity or diffusivity of pearlitic grey irons with various carbon contents is investigated by the laser flash method. The materials are cast in controlled thermal environments and produced in three dissimilar cooling rates. The cooling rate together with the carbon content largely influence the thermal conductivity of grey iron. Linear relationships exist between the thermal conductivity and the carbon content, the carbon equivalent and the fraction of former primary solidified austenite transformed into pearlite. The work shows that optimal thermal transport properties are obtained at medium cooling rates. Equations describing the thermal conductivity of pearlite,solidified as pre-eutectic austenite, and the eutectic of grey iron are derived. The thermal conductivity of pearlitic grey iron is modeled at both room temperature and elevated temperature with good accuracy.     

Slips and falls in a cold climate: underfoot surface, footwear design and worker preferences for preventive measures

Slips and falls and associated outdoor injuries are prevalent in cold climates. The objectives of this field investigation were to describe the consequences of slips and falls on ice and snow and the associated injuries, to assess the risks of various icy and snowy surfaces, to identify design needs of footwear, and to ascertain preventive measure preferences of outdoor workers. The organizations investigated were a newspaper delivery service, a military regiment, mining and construction industries. The results showed that fall events occur most frequently on ice covered with snow. This is due to the difficulty of perceiving hidden risks in order to adjust gait strategies. The professional footwear provided does not provide enough protection against slips and falls. Slip resistant properties are ranked as one of the top requirements by the users. Their most preferred preventive measures are footwear with anti-slip properties and the application of anti-slip materials, such as sand or salt.     

Classification of metabolic and respiratory demands in fire fighting activity with extreme workloads

Fire fighting work comprises work tasks requiring an energy yield at maximal or close to maximal levels of the individual. Due to the very nature of fire fighting more complex physiological variables are difficult to measure. We measured metabolic and respiratory responses in 15 male, professional fire fighters during simulated work tasks on a test ground. Work time was on the average 22 min with individual components of work tasks lasting 2-4 min. The mean oxygen consumption for the whole exercise (22 min) was 2.75+/-0.29 l/min. The most demanding work task demanded an oxygen uptake of 3.55+/-0.27 l/min. Corresponding values for respiratory minute volumes were 82+/-14 and 102+/-14l/min, respectively. Heart rates averaged 168+/-12 for the whole test and 179+/-13 beats/min for the heaviest work task. Two new classes for classification of intensive and exhausting, short term physical work are proposed for inclusion in ISO8996 and values for relevant parameters are proposed.     

Potential contribution of geothermal energy to climate change adaptation: A case study of the arid and semi-arid eastern Baringo lowlands,Kenya

The impacts of recurrent droughts have increased vulnerability and reduced the adaptive capacity of the people living in arid and semi-arid lands (ASALS) of Kenya. Current interventions are short-term and curative in nature, hence unsustainable. Some of the most arid and semi-arid lands are located within the Kenyan Rift system, which has an estimated geothermal potential of about 7000 to 10,000 MWe, out of which only 200 MWe has been developed, and about 5000 MWe planned by 2030. Recent power sector reforms have built institutional structures that will accelerate development of geothermal energy. The paper analyses the potential use of geothermal energy resources in eastern Baringo lowlands between Lake Bogoria and Silali prospects, which has an estimated potential of >2700 MWe, in creating the necessary adjustments needed to adapt to the impacts of recurrent droughts by locals. Opportunities for direct and indirect uses of geothermal energy exist in climate vulnerable sectors, such as, agriculture, fisheries, water, livestock production as well as alternative income generating activities such as, tourism, micro enterprises, aloe, honey and beeswax production, fabric dyeing and others using resources sourced from within a 50 km radius. The possibility of accelerated geothermal development and proposed utilisation schemes in causing maladaptation if unsustainably implemented is also discussed. The paper draws a Lindal diagram adapted to the study area showing potential utilisation in the above sectors, and new flow diagram showing potential for cascaded use of geothermal hot water through the different processes. An estimated capacity of 100 MWt and 100 MWe can be used in the potential utilisation schemes discussed in this article to meet local adaptation and lighting needs and much less in a cascaded process. Potential barriers and possible solutions are also discussed. The study concludes that geothermal energy is a vital option for adaptation in the study area if sustainably used.     

Multiple protein sequence alignment using double-dynamic programming

A method of multiple sequence alignment is described based on the double dynamic programming (DDP) algorithm previously used for treating structural constraints encountered in structure comparison and threading. Following these applications, the inconsistencies that emerge when trying to combine pair-wise alignments into a multiple alignment are reconciled by summing all the, possibly inconsistent, paths (low-level alignments) into a matrix which is then used to provide a final (high-level) alignment. This process is applied to all sequence pairs and the pair-wise results combined in a simple multiple sequence alignment program. From this alignment, further constraints are selected to bias the low-level alignments in the DDP algorithm and the process iterated. The results, however, showed that this overall iteration was not needed and one-pass gave results at least as good as the 'standard' progressive method of multiple sequence alignment. Further applications of the method are discussed.     

Change in contact temperature of finger touching on cold surfaces

This study deals with human fingers touching cold surfaces of four materials (aluminium, steel, nylon and wood) at different surface temperatures (−20°C, −15°C, −10°C, −4°C, 0°C and 2°C). Contact finger skin-surface interface temperature and subjective responses on thermal and pain sensations were determined during touching. Type of material and their surface temperature clearly affected the contact cooling of the finger. Individual variation in finger contact cooling was significant. Contact temperature limits for human fingers touching cold surfaces are suggested according to the experimental results. In addition, time to reach a critical temperature (7°C, 5°C or 0°C) when contacting a cold metallic surface is discussed.

Relevance to industry

The outcome of this experimental study supplies as a basis for the development of an ergonomics database to determine temperature limit values for cold touchable surfaces. The critical temperatures are relevant to all industries where cold surfaces cause a risk of finger contact cooling for the manual protection in the cold operations.     

A Novel internally heated Au/TiO2 carbon-carbon composite structured reactor for low-temperature CO oxidation

A compact, internally heated, catalytic reactor is demonstrated for the low-temperature oxidation of carbon monoxide. Carbon nanofibres were grown on carbon felt and used as a support material for Au/TiO₂ catalysts. The carbon composite plays two roles; as a support material for the catalyst and for providing heat to the reaction by the Joule effect. The internal heating offers a stable reactor system with quick temperature response at relatively low energy input. Comparison between external and internal heating shows higher conversion of CO in the low-temperature range when using internal heating. The Au/TiO₂ catalyst supported on the carbon-carbon composite shows good stability at 250°C.