In-chain functionalization by alternating anionic copolymerization of styrene and 1-(4-dimethylaminophenyl)-1-phenylethylene

Anionic copolymerizations of styrene (M₁) with excess 1-(4-dimethyl-aminophenyl)-1-phenylethylene (M₂) were conducted in benzene at 25°C for 24h, using sec-butyllithium as initiator. Narrow molecular weight distribution copolymers with M?;_n = 16.1 × 10³ g/mol (M?_w/M?_n = 1.04) and 38.2 × 10³g/mol (M?_w/M?_n = 1.05), and 24 and 38 moles of M₂ per macromolecule, respectively, were characterized by size exclusion chromatography, ¹H NMR spectroscopy and DSC. The monomer reactivity ratio, r₁ = 5.6, was obtained from the copolymer composition at complete consumption of M₁, assuming that the rate constant k₂₂ =0,i.e. r₂ =0. The polymers exhibited T_g values of 128 and 119°C, respectively, which correspond to an estimated T_g = 217°C for the hypothetical homopolymer of M₂.     

Compressed Sensing Projection and Compound Regularizer Reconstruction for Hyperspectral Images

压缩感知理论提供了一种新的数据获取和压缩思路,能有效地把计算负担从编码端转移到解码端.高光谱数据具备数据稀疏性、空间相关性和谱间相关性,结合这3类先验知识,提出了一种基于复合正则化的高光谱图像压缩感知投影与重构方法.该方法的编码端只需要一个简单的投影操作;在重构算法实现中,基于变量分裂的思想,把具备多个正则项的优化问题转化成多个简单的优化问题,并用迭代方式求解.实验结果表明,本文算法在高光谱图像重构上能获得更高的峰值信噪比和更好的重构效果.该方法具备极低的编码复杂度,适用于资源受限的机载和星载高光谱成像平台.     

Analysis of junction temperatures in high-power GaN-based LEDs

We presented the analysis of the incomplete conduction in bonding medium in high power GaN-based light-emitting diode (LED) packages. A numerical study was carried out with parametric model to understand the junction temperature variation due to bonding medium defects. Transient thermal measurement was performed to evaluate LED’s junction temperature. Thermal resistance from chip to lead frame was 20 K/W in our sample LED. It was suggested that only 60% of the surface area of the bonding medium was involved...     

光谱法研究Ni[S2P（OCH2CH2Ph）2]2与α,α＇-联吡啶加合反应

利用紫外光谱法研究了Ni[S2P（OCH2CH2Ph）2]2与α,α-联吡啶的加合反应。研究发现Ni[S2P（OCH2CH2Ph）2]2与α,α-联吡啶形成1∶1型加合物,在25℃的苯溶剂中,加合物的离解度α=0.07,稳定常数K稳^θ=2.1×10^6。     

资源生产供应链履行社会责任的内在动力研究

运用博弈论的基本思想,通过构造一个资源生产供应链,从资源保护这个角度出发,以资源生产供应链中的节点企业——资源开采商开采自然资源为例,对资源生产供应链履行社会责任的内在动力进行了研究。结果表明：对资源开采商合作开采带来的收益增量进行合理分配,既能使资源开采商进行合作,又能实现供应链系统与各资源开采商的帕累托最优。     

Attack Technology Research for Web Service

Web service is characterized by its isomerism and loose coupling;thus greatly fa- cilitate the application of operation in distributed situation, but its disadvantages cause seri- ous safety problems. The principium and characteristic of Web service classical attack tech- nology are expatiated, classical attack techniques are classified, and attack technology is sim- ulated, and then, the directions and the future of Web security are discussed.     

基于层次分析法的第三方支付系统风险评价模型

研究第三方支付系统风险综合评价问题,需建立风险评价模型。第三方支付系统风险评价是依据非金融机构支付服务业务系统检测相关标准,对系统风险进行多层次、全方位评价的复杂过程,评价指标体系的建立和权重的确定是科学合理评价系统风险的难点和关键。结合第三方支付系统的实际情况,建立了基于层次分析法的风险评价模型。     

一类Level Set和VOF的耦合界面捕捉方法

该文根据Level Set方法和VOF方法各自的优缺点,提出一种耦合的界面捕捉方法.该方法利用混合网格的体积份额确定混合网格的距离函数,从而达到提高Level Set方法捕捉运动界面的分辨率、改善守恒性的目的.通过给出的旋转流场和剪切流场的数值算例,说明了本文所提方法的有效性.     

基于混沌系统和极化恒等式的数字图像加密算法

混沌系统具有初值敏感性,参数敏感性和类随机性等特性。将图像分成大小为8 8的图像子块,利用经典的Logistic方程产生的混沌序列并对其排序生成匹配模板来改变图像子块的位置,然后利用极化恒等式内积分解加密算法改变图像像素的值。因此,基于混沌系统和极化恒等式的数字图像加密算法使图像的像素的位置和值都发生了变化,实现了图像的混淆和扩散。仿真实验表明该方法进行图像加密具有可行性和安全性。