Mixed oxide supported hydrodesulfurization catalysts—a review

Support effects form important aspect of hydrodesulfurization (HDS) studies and mixed oxide supports received maximum attention in the last two decades. This review will focus attention on studies on mixed oxide supported Mo and W catalysts. For convenience of discussion, these are divided into Al₂O₃ containing mixed oxide supports, TiO₂ containing mixed oxide supports, ZrO₂ containing mixed oxide supports and other mixed oxide supports containing all the rest. TiO₂ containing mixed oxides received maximum attention, especially TiO₂–Al₂O₃ supported catalysts. A brief discussion about their prospects for application to ultradeep desulfurization is also included. An overview of the available literature with emphasis on research carried out in our laboratory form the contents of this publication.     

Analysis of spring softening effect on the collapse voltage of capacitive MEMS ultrasonic transducers

Microsystem Technologies - This paper explained the dependency of collapse voltage on semiconductor device structural features (membrane diameter, membrane thickness and the vertical distance...     

Effect of phosphorus on activity of hydrotreating catalyst of Maya heavy crude

The effect of phosphorus on physical properties of the catalyst and on activity of hydrotreating of Maya crude was studied in this work. Catalysts were prepared by the co-impregnation method. Alumina-titania binary oxide was used as a support material. The presence of phosphorus in the catalyst decreases the percentage of micropores, and it results in a decrease of specific surface area. Temperature program reduction (TPR) shows that phosphates reduce metal support interaction. It leads to the formation of polymolybdate phases in expense of strongly bonded tetrahedral molybdates. At higher P loading, polymolybdates may be present with quasi crystalline MoO₃. However, the TPR experiment is not sufficiently sensitive to distinguish several phases present on the catalysts used by the authors. A slight increment of HDM activity is observed, but HDS activity is lower in the P containing catalyst compared with the P free catalyst. The changes of physical properties of the spent catalysts are mainly due to the coke formation on the catalyst. The presence of phosphorus on hydrotreating catalysts inhibits coke formation during the hydrotreating reaction.     

Electrical conductivity of a novel cast 6351 Al–Al4SiC4 in situ composite

In this research work, electrical conductivity of a novel cast 6351 Al–Al₄SiC₄ composite has been studied for varying Al₄SiC₄ particle content (2–7 vol%). Analytical models were developed on the basis of free electron theory and local resistance approach in order to predict electrical conductivity of metal matrix composites. The electrical conductivity of cast 6351 Al–Al₄SiC₄ composite was found to decrease with increasing Al₄SiC₄ content. Overprediction of results and more % deviation of the predicted electrical conductivity from experimental value were observed for local-resistance-approach-based model. However, the model developed on the basis of electron theory considering scattering of electrons at particle–matrix interface accurately predicted the experimental electrical conductivity data.     

Comparative study on the structural make-up and mechanical behavior of silicon and silver doped amorphous carbon films

Silicon - Silicon (Si) and silver (Ag) doped amorphous carbon (a-C) thin film were deposited on chrome nitrided 316 LVM stainless steel using filtered cathodic vacuum arc (FCVA) deposition...     

Effect of Cooling Rate on Microstructure and Mechanical Properties of Eutectoid Steel Under Cyclic Heat Treatment

A systematic study has been carried out to ascertain the effect of cooling rate on structure and mechanical properties of eutectoid steel subjected to a novel incomplete austenitization-based cyclic heat treatment process up to 4 cycles. Each cycle consists of a short-duration holding (6 min) at 775 °C (above A₁) followed by cooling at different rates (furnace cooling, forced air cooling and ice-brine quenching). Microstructure and properties are found to be strongly dependent on cooling rate. In pearlitic transformation regime, lamellar disintegration completes in 61 h and 48 min for cyclic furnace cooling. This leads to a spheroidized structure possessing a lower hardness and strength than that obtained in as-received annealed condition. On contrary, lamellar disintegration does not occur for cyclic forced air cooling with high air flow rate (78 m³ h^?1). Rather, a novel microstructure consisting of submicroscopic cementite particles in a ‘interweaved pearlite’ matrix is developed after 4 cycles. This provides an enhancement in hardness (395 HV), yield strength (473 MPa) and UTS (830 MPa) along with retention of a reasonable ductility (%Elongation = 19) as compared to as-received annealed condition (hardness = 222 HV, YS = 358 MPa, UTS = 740 MPa, %Elongation = 21).     

Binary liquid–liquid equilibria of aniline–paraffin and furfural–paraffin systems

Binary liquid-liquid-equilibria data for several aniline-paraffin and furfural-paraffin systems have been taken. These data along with data for other aniline-hydrocarbon and furfural-hydrocarbon systems from literature have been correlated using UNIFAC model. The UNIFAC group interaction parameters have been found to have a linear temperature dependence. The CH₂ groups in cyclo and non cyclo paraffins require different interaction parameters. It was also found that a scaling of the combinatorial term is necessary for higher molecular weight hydrocarbons.     

Analysis of Temperature Effect in Quadruple Gate Nano-scale FinFET

Silicon - Quadruple gate FinFET is a promising candidate among other multi-gate MOS devices due to it’s better scalability and higher short channel effect suppression capability in advanced...     

A production-recycling-inventory model with learning effect

This paper develops an integrated production-recycling system over a finite time horizon. Here, the dynamic demand is satisfied by production and recycling. The used units are bought back and then either recycled or disposed of which are not repairable. The used units are collected continuously from the customers. Recycling products can be used as new products which are sold again. The rate of production and disposal are assumed to be function of time. The setup cost is reduced over time due to “Learning curve” effect. The optimum results are presented both in tabular form and graphically.     

Higher order direct model reference adaptive control with generic uniform ultimate boundedness

This paper proposes a new higher order model reference adaptive control (HO-MRAC) approach following direct adaptive control philosophy, which estimates unknown time-varying parameters. This approach leads to a Lyapunov based conventional MRAC update law, augmented by an observer type parameter predictor dynamics. The predictor dynamics are composed of a stable known part, a feedback of the parameter error and unknown higher order parameters, which are updated using a Lyapunov based adaptive design. So, this HO-MRAC can cope with rapidly changing parameters, due to estimation of their time derivatives. Moreover, for stability analysis, a Lyapunov based generic ultimate boundedness theorem is presented, which allows for a computation of separate bounds for each state vector partition. Furthermore, this theorem formulates the explicit specification of transient and ultimate bounds, reaching time on the ultimate bounds and a set of admissible initial conditions. Two challenging illustrative examples demonstrate the effectiveness of the proposed approach.