Optical study of twin‐tanked ICS solar heaters combined with asymmetrical CPC‐type reflectors

The distribution of solar irradiance on the absorbing surface of a typical integrated collector storage (ICS) system combined with reflector troughs is commonly studied by means of ray tracing techniques. A conceptually different alternative is offered by the method of the average number of reflections (ANR). In the present work, the latter is employed for the systematic optical study of realistic ICS models. In all cases, the solar devices consist of twin cylindrical storage tanks which are mounted on top of stationary asymmetrical CPC‐type reflectors. The emphasis of the current research is mainly placed on the evaluation of the ANR reliability for the calculation of the optical efficiency of the related twin‐tanked devices. Additionally, useful operational parameters, such as the optical performance of the proposed geometries, are also determined. The behavior of the tested ICS systems reveals that the optical efficiency may vary in the range of 0.75 to 0.91, exhibiting a strong dependence on the geometric parameters of the solar devices. The highest efficiency is achieved by the systems which combine large reflecting area and storage tanks in close proximity.     

Between the Local and the Global: History of Science in the European Periphery Meets Post‐Colonial Studies

The aim of this paper is to discuss two historiographical issues pertaining to the history of science in the European periphery. The first issue concerns the wide use of the centre‐periphery dichotomy in historical accounts discussing the diffusion and institutionalization of science across the world. The second issue concerns the use of appropriation (instead of transfer, or adaptation) as a means to overcome the diffusionist model in history of science. Recent work at the intersection of history of science with post‐colonial studies will provide the framework for reassessing these matters. As it will be shown, theoretical discussions about the history of science in post‐colonial context can help historians overcome the centre‐periphery dichotomy and turn European periphery into a privileged standpoint for showing the actual diversity of ‘European science.’ At the same time, the experience of post‐colonial studies can also help sharpen the historiographical tool of appropriation. The assumption that will be made is that by focusing on appropriation rather than on discovery and innovation (the favourite categories of much of mainstream historiography), or on transfer and adaptation (the favourite categories of the diffusionist model), historians of science can not only set aside the artificial distinctions of the diffusionist model, but also bring forward the re‐inventions, the conceptual shifts and the cultural adjustments, which are responsible for the emergence of science as a global phenomenon in the periphery. Especially concerning European periphery, the use of appropriation may bring forward the particular historical circumstances under which certain knowledge patterns gained universal epistemic authority as constitutive elements of an imagined European intellectual identity.     

Development of [60] fullerene supported on silica catalysts for the photo-oxidation of alkenes

Simple or successive incipient wetness impregnation followed by heating at 180 °C is proved an efficient preparation method for dispersing effectively onto the silica surface various amounts of C₆₀ in the range 1–4% (w/w). BET, XRD, DRS, TGA, microelectrophoresis and photoluminescence have been used to characterize the photocatalysts prepared. A high dispersion was obtained for the quite stable supported C₆₀ phase, comprised mainly from relatively small or medium size C₆₀ clusters/aggregates. The photocatalytic activity was assessed in the singlet oxygen oxidation of alkenes by examining the photo-oxygenation of 2-methyl-2-heptene as a probe reaction. The catalytic tests were carried out at 0–5 °C in CH₃CN, under oxygen atmosphere and using a 300 W xenon lamp as the light source. The heterogeneous catalysts obtained were proved to be active in the photocatalytic oxidation of olefins via a ¹O₂ ene reaction. The catalysts exhibited significant conversion, turnover number and turnover frequency values, substantially higher than those achieved over the unsupported C₆₀. The conversion increases with the amount of the supported C₆₀ up to a value equal to 3% (w/w) and then it decreases whereas turnover number and turnover frequency decreases monotonically as the amount of the supported C₆₀ increases. The easy separation of these solid catalysts from the reaction mixture, the high activity and stability as well as the retained activity in subsequent catalytic cycles, make these supported catalysts suitable for a small-scale synthesis of fine chemicals.     

Business Process Modelling and Design — A Formal Model and Methodology

This paper presents a formal framework for representing enterprise knowledge. The concepts of our framework (objectives and goals, roles and actors, actions and processes, responsibilities and constraints) allow business analysts to capture knowledge about an enterprise in a way that is both intuitive and mathematically formal. It also outlines the basic steps of a methodology that allows business analysts to go from high-level enterprise objectives, to detailed and formal specifications of business processes that can be enacted to realise these objectives. The formal language used means that the specifications can be verified as having certain correctness properties, e.g. that responsibilities assigned to roles are fulfilled, and constraints are maintained as a result of process execution.     

Decatungstate catalyst supported on silica and γ-alumina: Efficient photocatalytic oxidation of benzyl alcohols

Four supported catalysts with the same tungsten loading were prepared by depositing decatungstate species W₁₀O⁴⁻₃₂, through wet impregnation, on the surface of γ-alumina and silica at different pH values. The prepared samples were characterized using BET measurements as well as XRD, UV–vis DR, and XP spectroscopies. Higher dispersion of W(VI) oxo-species was obtained in the silica-supported catalysts compared with the corresponding alumina-supported ones. Within the same support, the dispersion was higher when the impregnation pH is lower than the point of zero charge (pzc) of the support. The decatungstate anions were present mainly on the silica surface without any modification, whereas these underwent a partial depolymerization on their deposition on the γ-alumina surface. The extent of depolymerization was less in the sample prepared at pH above pzc. These findings were explained in terms of the mode of deposition of the W(VI) species from the solution onto the support surface. The photocatalytic activity of the aforementioned catalysts, concerning the photooxidation of 1-phenylethanol, depends on the fraction of the W₁₀O⁴⁻₃₂ supported species rather than on the W(VI) dispersion. Thus, extremely high conversions have been obtained over the silica-based catalysts and also over the γ-alumina-based catalyst prepared at relatively high pH. These catalysts also are very effective in the photooxidation of a series of secondary and primary benzyl alcohols, in which benzyl ketones and benzoic acids were formed as the only or major products, respectively. The easy separation of the solid catalyst from the reaction mixture, the high activity, selectivity, and stability as well as the retained activity in subsequent catalytic cycles, make these supported catalysts suitable for a small-scale synthesis. Based on product analysis and kinetic data on the heterogeneous oxidation of benzyl alcohols, we suggest that a hydrogen abstraction transfer (HAT) mechanism predominates with respect to an electron transfer (ET) one in these reactions.     

Numerical investigation of the evaporation of two-component droplets

A numerical model for the complete thermo-fluid-dynamic and phase-change transport processes of two-component hydrocarbon liquid droplets consisting of n-heptane, n-decane and mixture of the two in various compositions is presented and validated against experimental data. The Navier-Stokes equations are solved numerically together with the VOF methodology for tracking the droplet interface, using an adaptive local grid refinement technique. The energy and concentration equations inside the liquid and the gaseous phases for both liquid species and their vapor components are additionally solved, coupled together with a model predicting the local vaporization rate at the cells forming the interface between the liquid and the surrounding gas. The model is validated against experimental data available for droplets suspended on a small diameter pipe in a hot air environment under convective flow conditions; these refer to droplet’s surface temperature and size regression with time. An extended investigation of the flow field is presented along with the temperature and concentration fields. The equilibrium position of droplets is estimated together with the deformation process of the droplet. Finally, extensive parametric studies are presented revealing the nature of multi-component droplet evaporation on the details of the flow, the temperature and concentration fields.