Synthesis of 2,7‐Carbazolenevinylene‐Based Copolymers and Characterization of Their Photovoltaic Properties

New electroactive and photoactive conjugated copolymers consisting of alternating 2,7‐carbazole and oligothiophene moieties linked by vinylene groups have been developed. Different oligothiophene units have been introduced to study the relationship between the polymer structure and the electronic properties. The resulting copolymers are characterized by UV‐vis spectroscopy, size‐exclusion chromatography, and thermal and electrochemical analyses. Bulk heterojunction photovoltaic cells from different copolymers and a soluble fullerene derivative, [6,6]‐phenyl‐C₆₁ butyric acid methyl ester, have been fabricated, and promising preliminary results are obtained. For instance, non‐optimized devices using poly(N‐(4‐octyloxyphenyl)‐2,7‐carbazolenevinylene‐alt‐3″,4″‐dihexyl‐2,2′;5′,2″;5″,2″′;5″′,2″″‐quinquethiophenevinylene 1″,1″‐dioxide) as an absorbing and hole‐carrier semiconductor exhibit power conversion efficiency up to 0.8 % under air mass (AM) 1.5 illumination. These features make 2,7‐carbazolenevinylene‐based and related polymers attractive candidates for solar‐cell applications.     

Clinical trial of retrograde warm blood reperfusion versus standard cold topical irrigation of transplanted hearts

BACKGROUND: A prospective, randomized clinical study involving 34 patients undergoing heart transplantation compared myocardial preservation of donor hearts maintained with continuous reperfusion with retrograde warm blood cardioplegia during surgical implantation versus the standard cold topical irrigation. METHODS: Hearts in both groups were arrested with a standard crystalloid solution and maintained in a cold saline solution during transportation. In the retrograde group, cardioplegia was administered through a catheter in the coronary sinus during surgical implantation. An average of 471 +/- 30 mL of hyperkalemic crystalloid solution diluted 1:4 in warm blood from the oxygenator was infused. In the standard group, the heart was kept cold by topical irrigation of cold saline solution and was reperfused only when the ascending aorta was unclamped. RESULTS: Preoperative characteristics of donors and recipients were similar in the two cohorts. Ischemic time average 139 +/- 12 minutes in the retrograde group compared with 130 +/- 11 minutes in the standard group (p = 0.57). Cardiopulmonary bypass time averaged 89 +/- 4 minutes in the retrograde group and 110 +/- 12 minutes in the standard group (p = 0.12). Defibrillation at reperfusion was performed in 4 patients (4/17, 24%) in the retrograde group and 12 patients (12/18, 67%) in the standard group (p = 0.01). There were no deaths in the retrograde group (0/17), whereas in the standard group, 3 patients (3/17) died of early graft failure (p = 0.11). Four early graft failures occurred in the standard group (p = 0.06). Two patients (2/17, 12%) were weaned from bypass with ventricular assist devices in the standard group. The number of subendocardial necrotic cells in the first two weekly endomyocardial biopsy specimens averaged 2.7 +/- 0.8 cells/mm2 in the retrograde group and 5.9 +/- 2.4 cells/mm2 in the standard group (p = 0.12). CONCLUSIONS: Retrograde warm blood reperfusion appears to improve the initial recovery of transplanted hearts. The technique is easy to use and may be a useful approach to graft protection during surgical implantation.     

Performance analysis of a COFDM/FM in-band digital audiobroadcasting system

In this paper, we present a performance analysis of a coded orthogonal frequency division multiplexing DAB system that is power multiplexed over a commercial FM station. We model the mobile channel with a time-frequency scattering function. Results show that the performance of the FM demodulator is crucial, since the level of the residual FM signal has a strong influence on the BER performance of the COFDM system. As with other mobile communication systems, the use of interleaving greatly enhances the performances     

Monitoring non-carbonated (‘still’) mineral waters for aerobic colonization

Fifty samples each of two leading brands of French, non-carbonated (‘still’) mineral waters, packed in plastic bottles, were stored in the dark for one month at approximately 20°C to allow marked proliferation of their autotrophic microbial flora. Upon completion of this challenge test 1250 ml per bottle were filtered through five membranes, which were subsequently cultured on 1/10 strength nutrient agar for 48 h at a temperature favouring the growth of thermotrophic organisms only, i.e. 42 ± 0.5°C. The numbers of colonies per one litre were below 10³ in all samples and did not exceed 200 in 56–80%, depending on the brand. Identification of the isolates demonstrated strong inhibition of the psychrotrophic. Gram-negative types, predominating in the association flora of stored still waters and preponderance of Gram-positive, catalase-positive, facultatively anaerobic cocci. Consequently, a Reference Value for the thermotrophic autotrophic colony count per 1 ml in still, commercial mineral waters of the order m = 1 and M = 5 seems justified. It is emphasized that, besides examining for these trivial organism, the usual tests for marker bacteria (Escherichia coli and Lancefield group D streptococci) and Pseudomonas aeruginosa should always be carried out.     

The local structure of image discontinuities in one dimension

The detailed structure of intensities in the local neighborhood of an edge can often indicate the nature of the physical event givinig rise to that edge. We argue that the limit, as we approach arbitrarily close to either side of an edge, of such image parameters as type of texture, texture gradient, color, appropriate directional derivatives of intensity, etc., is a key aspect of this structure. However, the general problem of capturing this local structure is surprisingly complex. Thus, we restrict ourselves in this paper to a relatively simple domain?one-dimensional cuts through idealized images modeled by piecewise smooth (C1) functions corrupted by Gaussian noise. Within this domain, we define local structure to be the limit of the uncorrupted intensity and of its derivatives as we approach arbitrarily close to either side of a discontinuity. We develop a technique that captures this local structure while simultaneously locating the discontinuities, and demonstrate that these tasks are in fact inseparable. The technique is an extension, using estimation theory, of the classical definition of discontinuity. It handles, in a consistent fashion, both jump discontinuities in the function and jump discontinuities in its first derivative (so-called step-edges are a special case of the former and roof-edges of the latter). It also integrates, again in a consistent fashion, information derived from a number of different neighborhood sizes.     

Coupling of polystyrene to a silane-treated mica

This paper deals with the coupling of polystyrene to a closely packed and highly ordered cationic vinylbenzyl silane (CVBS) on mica. It is shown that a thermal treatment is required for maximum retention of polystyrene on treated mica. Moreover, a thermal treatment at 250°C is much more effective than one at 170°C. The effect of the number of silane monolayers on mica was investigated. In general, one monolayer of CVBS gave optimum retention of polystyrene. The addition of peroxides further improved this retention and at the same time allowed the use of lower treatment temperatures. Some data are presented which consider the importance of the silane solution concentration and silane functional groups.     

Efficient Binary Tomographic Reconstruction

Tomographic reconstruction of a binary image from few projections is considered. A novel heuristic algorithm is proposed, the central element of which is a nonlinear transformation ψ(p)=log(p/(1?p)) of the probability p that a pixel of the sought image be 1-valued. It consists of backprojections based on ψ(p) and iterative corrections. Application of this algorithm to a series of artificial test cases leads to exact binary reconstructions, (i.e., recovery of the binary image for each single pixel) from the knowledge of projection data over a few directions. Images up to 10⁶ pixels are reconstructed in a few seconds. A series of test cases is performed for comparison with previous methods, showing a better efficiency and reduced computation times.     

The nutritive value of refined rapeseed oils: A review

Recent findings on the nutritive value of rapeseed oil (RSO) with high erucic acid content have been compared to those of canbra oil (CO), an oil extracted from newly bred Canadian rapeseed with no erucic acid. Erucic acid in diets retards animal growth even if food consumption is not altered. Growth performances of CO are as good as olive or peanut oil. The unbalanced ratio of palmitic acid to monoethylenic acids of CO does not affect rat growth rate. Because of its glyceride structure and high content of erucic acid, RSO has a lower digestibility (81%) than CO (96%) in the rat. Unabsorbed erucic acid is not preferentially excreted as calcium soaps. Interesterification of RSO which converts 31.7% of the erucic chains to the 2 position improves digestibility of erucic acid. 2-Monoerucin is more efficiently absorbed than the free acid. In vivo metabolic conversion of erucic to oleic acid has been proved in the rat. β-oxidation of injected 14-¹⁴C labeled erucic acid proceeded at the same rate as oleic acid but the over-all yield of the reaction was lower. Fatty acid composition of tissues in animals fed RSO or CO is influenced on one hand by erucic and gadoleic (C_20∶1) acids of RSO, and on the other hand by the unbalanced ratio of palmitic-monoethylenic acids and the linolenic acid content of both oils. Nonnegligible amounts of erucic acid are deposited in the body fats of rats, chickens, turkeys, lambs and found in the milk of female rats fed RSO. Almost no erucic acid is incorporated in liver and testicles in the rat and it is not recovered in chicken egg yolk. The effect of RSO on rat reproduction has been re-examined. Dietary lipid and vitamin levels are of great importance in the results obtained. RSO induces myocarditis in several animal species. Similar lesions, although less frequent and severe, have been observed also with CO in the rat. Some authors have reported that erucic acid of RSO was responsible for the effect on heart muscle. Common fatty acid patterns to both RSO and CO have to be further investigated to explain the persisting effect of CO. One of 9 papers presented at the Symposium, “Cruciferous Oil-seeds,” ISF-AOCS World Congress, Chicago, September 1970.     

Application of a glyphosate-based herbicide to Phragmites australis: Impact on groundwater and near-shore lake water at a beach on Georgian Bay

During the past decade, the invasive Phragmites australis (common reed) has established itself along beaches of the Great Lakes, causing detrimental impacts to both the natural ecological integrity of the shoreline and the recreational value of beaches. The herbicide Roundup®, containing the active ingredient glyphosate, was applied to Phragmites along a beach on the southern shore of Georgian Bay, Canada, to eradicate the Phragmites which was destroying the natural beach ecosystem. Groundwater and lake water were tested to determine if glyphosate enters the groundwater and lake at the beach and how long glyphosate will persist. Two days after application, the geometric mean concentration of glyphosate in the groundwater below the Phragmites was 0.060 μg/L with a maximum of 12.50 μg/L. Concentrations rapidly declined over the next two to three weeks to below minimum detection limits (< 0.020 μg/L). Glyphosate was also detected in the nearshore lake water with concentrations peaking at a geometric mean of 0.14 μg/L one week after application, and declining to 0.039 μg/L four weeks after application. Concentrations of glyphosate never exceeded the Canadian water quality guideline for the protection of aquatic life (65 μg/L) in either the groundwater or lake water. An approximate half-life for the dissipation of glyphosate by degradation and dilution/flushing as groundwater flows toward the lake, assuming a first order kinetic reaction, yielded a half-life of 3.5 during the 4 weeks after the herbicide was applied. The application of Roundup® resulted in an 90% reduction in the size of the stand of Phragmites.