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排序方式: 共有313条查询结果,搜索用时 203 毫秒
1.
Nibal Hijazi Nicolas Le Moigne Elisabeth Rodier Martial Sauceau Thierry Vincent Jean‐Charles Benezet Jacques Fages 《Polymer Engineering and Science》2019,59(Z1):E350-E360
Structured and fully bio‐based polymer assemblies based on chitosan micro‐ and nano‐particles and poly(lactic acid) (PLA) were developed using a continuous cast‐film extrusion process. The microstructure and thermal properties of the resulting biocomposite films are studied. Dispersion and size distribution of chitosan particles within the films were analyzed by optical microscopy and laser diffraction. Results show a homogeneous dispersion with no particles agglomeration, due to favorable physico–chemical interactions between chitosan particles and PLA and weak particle cohesion within the agglomerates. Differential scanning calorimetry experiments evidence a pronounced nucleating effect as well as an enhanced crystal growth rate, and a great increase in crystallinity of PLA in the presence of chitosan particles. Furthermore, in the case of chitosan nanoparticles, no reduction of PLA molecular weight occurred as revealed by gel permeation chromatography. The dispersion of nanosized chitosan particles in PLA thus appears to be an efficient way to control its crystallization behavior without degrading its molecular characteristics. POLYM. ENG. SCI., 59:E350–E360, 2019. © 2018 Society of Plastics Engineers 相似文献
2.
Martial Degbia Bruno Schmaltz Johann Bouclé Juozas V Grazulevicius François Tran‐Van 《Polymer International》2014,63(8):1387-1393
The synthesis of new organic hole transporting materials (HTMs) based on 3,6‐disubstituted 9H‐carbazole‐3,6‐diamine,N,N,N′,N′‐tetraphenyl‐9‐(4‐methoxyphenyl) derivatives and their applications in solid state dye sensitizer solar cells (DSSCs) are described. The effect of the methoxy group localized on the para position of the diphenylamine moieties on the thermal, electronic and electrochemical properties and photovoltaic performance is discussed. In solid state DSSCs, utilization of the aforementioned HTMs in combination with the dye D102 (TiO2/D102/HTM/Au) shows a positive influence of the methoxy group on the photovoltaic conversion efficiency compared with unsubstituted diphenylamine grafted groups. A study on the concentration of the HTM is also carried out and shows an optimal concentration around 200 mg mL?1. Without further optimization, the best device gives a power conversion efficiency of 1.75% under AM 1.5 solar irradiation (100 mW cm?2). 相似文献
3.
In this study, the outcome of operating conditions of extrusion assisted by supercritical CO2 for the manufacture of poly(lactic acid) foams was investigated. It was found that the temperature before and inside the die was the most prominent parameter to tune the foam properties. Foam porosity as high as 96% could be obtained (for die temperature between 109 and 112 °C), representing a total expansion exceeding 30. In this temperature range, low crystallinity (≈6%) was induced giving foams with high radial expansion i.e., large diameters and open porosity. At 112 °C, the CO2 was able to greatly expand the foams, providing 73% of its potential blowing effect. On the other hand, a low die temperature (below a die temperature of 107 °C) induces a significantly higher level of crystallinity resulting in foams with closed‐porosity and a large longitudinal expansion due to higher strength of the polymer melt. © 2017 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2017 , 134, 45067. 相似文献
4.
Ausra Tomkeviciene Gabija Puckyte Juozas Vidas Grazulevicius Martial Degbia Francois Tran-Van Bruno Schmaltz Vygintas Jankauskas Johann Bouclé 《Synthetic Metals》2012
The synthesis and properties of glass-forming diphenylamino-substituted derivatives of 9-phenylcarbazole with methoxy groups in the different position of diphenylamino moieties are reported. A comparative study on their thermal, optical, photoelectrical and electrochemical properties is presented. The synthesized compounds exhibit high thermal stability with 5% weight loss temperatures ranging from 344 to 475 °C. The derivatives absorb electromagnetic irradiation in the range of 225–425 nm with the band gaps of 2.94–3.08 eV. The ionization energies of the synthesized compounds range from 5.04 to 5.56 eV. The lowest ionization energies and band gaps are observed for compounds containing para methoxy-substituted phenyl rings of diphenylamino moieties and for disubstituted carbazole derivatives. Charge-transporting properties of the selected compounds were tested by time-of-flight technique. Hole drift mobilities in the amorphous layers of the materials reach 10−3 cm2/V s at high electric fields. The derivatives were tested as hole transport materials in solid-state dye sensitized solar cells and showed conversion efficiency up to 0.54%. 相似文献
5.
6.
C. Philippot M. Bellavoine M. Dumont K. Hoummada J. Drillet V. Hebert P. Maugis 《Metallurgical and Materials Transactions A》2018,49(1):66-77
Compared with other dual-phase (DP) steels, initial microstructures of cold-rolled martensite-ferrite have scarcely been investigated, even though they represent a promising industrial alternative to conventional ferrite-pearlite cold-rolled microstructures. In this study, the influence of the heating rate (over the range of 1 to 10 K/s) on the development of microstructures in a microalloyed DP steel is investigated; this includes the tempering of martensite, precipitation of microalloying elements, recrystallization, and austenite formation. This study points out the influence of the degree of ferrite recrystallization prior to the austenite formation, as well as the importance of the cementite distribution. A low heating rate giving a high degree of recrystallization, leads to the formation of coarse austenite grains that are homogenously distributed in the ferrite matrix. However, a high heating rate leading to a low recrystallization degree, results in a banded-like structure with small austenite grains surrounded by large ferrite grains. A combined approach, involving relevant multiscale microstructural characterization and modeling to rationalize the effect of the coupled processes, highlights the role of the cold-worked initial microstructure, here a martensite-ferrite mixture: recrystallization and austenite formation commence in the former martensite islands before extending in the rest of the material. 相似文献
7.
Yu Jin Xiangli Cui Udai P. Singh Alexander A. Chumanevich Brook Harmon Philip Cavicchia Anne B. Hofseth Venkata Kotakadi Brandy Stroud Suresh R. Volate Thomas G. Hurley James R. Hebert Lorne J. Hofseth 《Molecular nutrition & food research》2010,54(10):1506-1514
Chronic inflammation contributes to an increased risk for developing chronic conditions such as cardiovascular disease, diabetes, and cancer. A high “inflammatory load” is defined as elevated inflammation markers in blood or other tissues. We evaluated several markers of systemic inflammation from healthy adults and tested the hypothesis that two formulations of encapsulated fruit and vegetable juice powder concentrate with added berry powders (FVB) or without (FV) could impact markers of inflammatory load. Using a double‐blind, placebo‐controlled approach, 117 subjects were randomly assigned to receive placebo, FV, or FVB capsules. Blood was drawn at baseline and after 60 d of capsule consumption. We measured inflammatory markers (high sensitivity C‐Reactive Protein, Monocyte Chemotactic Protein‐1, Macrophage Inflammatory Protein 1‐β, and Regulated upon Activation, Normal T cell Expressed and Secreted), superoxide dismutase, and micronutrients (β‐carotene, vitamin C, and vitamin E). Results showed Monocyte Chemotactic Protein‐1, Macrophage Inflammatory Protein 1‐β, and RANTES levels were significantly reduced and superoxide dismutase and micronutrient levels were significantly increased in subjects consuming both FV and FVB, relative to placebo. Data suggest a potential health benefit by consuming either formulation of the encapsulated juice concentrates through their anti‐inflammatory properties. 相似文献
8.
Chuanbing Rong Ying Zhang Narayan Poudyal Izabela Szlufarska Rainer J. Hebert M. J. Kramer J. Ping Liu 《Journal of Materials Science》2011,46(18):6065-6074
Fabrication of bulk nanocomposite materials, which contain a magnetically hard phase and a magnetically soft phase with desired
nanoscale morphology and composition distribution has proven to be challenging. Here we demonstrate that SmCo/Fe(Co) hard/soft
nanocomposite materials can be produced by distributing the soft magnetic α-Fe(Co) phase particles homogenously in a hard
magnetic SmCo phase matrix through a combination of high-energy ball milling and a warm compaction. Severe plastic deformation
during the ball milling results in nanoscaling of the soft phase with size reduction from micrometers to ~15 nm. Up to 35%
of the soft phase can be incorporated into the composites without coarsening. This process produces fully dense bulk isotropic
nanocomposite materials with remarkable energy-product enhancement (up to 300%) owing to effective inter-phase exchange coupling. 相似文献
9.
Influence of the nature of aggregates on the behaviour of concrete subjected to elevated temperature 总被引:1,自引:0,他引:1
Zhi Xing Anne-Lise Beaucour Ronan Hebert Albert Noumowe Béatrice Ledesert 《Cement and Concrete Research》2011,41(4):392-402
An experimental study is carried out on concretes composed of three different types of aggregates: semi crushed silico-calcareous, crushed calcareous and rolled siliceous. For each aggregate type, two water/cement ratios (W/C), 0.6 and 0.3 are studied. Aggregates and concrete specimens were subjected to 300, 600 and 750 °C heating–cooling cycles. We analyse the evolution of thermal, physical and mechanical properties of concrete in terms of behaviour and physical characteristic evolutions of aggregates with temperature. The study of thermal behaviour of aggregates showed the importance of initial moisture state for the flints. The crystallisation and microstructure of quartz play an important role in the thermal stability of siliceous aggregates. The residual mechanical behaviour of concrete varies depending on the aggregate and the influence of aggregates is also dependent on paste composition. This study allowed to better understand the influence of chemical and mineralogical characteristics of aggregates on the thermomechanical behaviour of concrete. 相似文献
10.
Enam Alsrayheen Eric McLeod Richard Rateick Jr. Hebert Molero Viola Birss 《Electrochimica acta》2011,(17):6041
An ac/dc spark anodization method was used to deposit an oxide film (6 ± 3 μm in thickness) on the Al–Cu alloy AA2219. The oxide films were formed at 10 mA/cm2 for 30 min in an alkaline silicate solution, showing three main stages of growth. Scanning electron microscopy and electron microprobe analysis revealed that the oxide films are not uniform and consist of three main layers, an inner Al-rich barrier layer (∼1 μm), an intermediate Al–Si mixed oxide layer (∼2 ± 1 μm), and an outer porous Si-rich layer (∼3 ± 3 μm). In addition, microscopic analysis showed that the Al2Cu intermetallics present in the alloy have not been excessively oxidized during the anodization process and thus are retained beneath the oxide film, as desired. The coating passivity and corrosion resistance, evaluated using linear sweep voltammetry (LSV) in pH 7 borate buffer solution and electrochemical impedance spectroscopy (EIS) in 0.86 M NaCl solution, respectively, were both significantly improved after spark-anodization. 相似文献