Environmental Control of Triplet Emission in Donor–Bridge–Acceptor Organometallics

Carbene‐metal‐amides (CMAs) are a promising family of donor–bridge–acceptor molecular charge‐transfer (CT) emitters for organic light‐emitting diodes. A universal approach is demonstrated to tune the energy of their CT emission. A blueshift of up to 210 meV is achievable in solid state via dilution in a polar host matrix. The origin of this shift has two components: constraint of thermally‐activated triplet diffusion, and electrostatic interactions between guest and polar host. This allows the emission of mid‐green CMA archetypes to be tuned to sky blue without chemical modifications. Monte‐Carlo simulations based on a Marcus‐type transfer integral successfully reproduce the concentration‐ and temperature‐dependent triplet diffusion process, revealing a substantial shift in the ensemble density of states in polar hosts. In gold‐bridged CMAs, this shift does not lead to a significant change in luminescence lifetime, thermal activation energy, reorganization energy, or intersystem crossing rate. These discoveries offer new insight into coupling between the singlet and triplet manifolds in CMA materials, revealing a dominant interaction between states of CT character. The same approach is employed using materials which have been chemically modified to alter the energy of their CT state directly, shifting the emission of sky‐blue chromophores into the practical blue range.     

The stiffness of laser stake welded T-joints in web-core sandwich structures

The purpose of this paper is to describe experiments carried out on laser stake welded T-joints of web-core steel sandwich structures. A special test setup was developed to measure the shear-induced rotation at the T-joint. The ratio of the shear force to rotation angle gave the joint stiffness. This stiffness was measured for specimens with two different face-plate thicknesses. The influence of weld thickness, root gap and occurrence of contact were further investigated with finite element simulations. Finally, the shear stiffness of the sandwich structure transverse to the web plate direction was determined using the experimentally obtained average joint stiffness value. The validation of the shear stiffness was carried out by considering a beam in four-point bending. The agreement between calculated deflection and stress and experimental results was found to be good.     

化学分离法分析大型纸浆发电厂废渣中生物质底灰和飞灰成分(英文)

采用三步分离法,其中第一步用水,第二步用乙酸铵,第三步用盐酸,提取纸浆发电厂生物质飞灰和底灰的组分,以评估这些残渣的浸出行为。除了Mo、S、Na以及那些浓度低于检测范围的元素外,在这两种灰份中,对于其他元素这三种浸出剂的浸出能力从弱到强的顺序为:水、乙酸铵和盐酸。采用三步分离法处理的废渣中元素浓度比前期用BCR连续提取法得到的低。     

Multi-channel energy detection under phase noise: analysis and mitigation

For the development of highly integrated, flexible and low-cost cognitive radio (CR) devices, simple transceiver architectures, like direct-conversion receiver, are expected to be deployed and provide viable radio frequency (RF) spectrum sensing solutions for practical implementation. Yet, this can be very challenging task especially if spectrum sensing and down-conversion are conducted over multiple RF channels simultaneously for improved efficiency in channel scans. Then, the so-called dirty RF problem that degrades link performance of traditional transmission systems starts to be influential from spectrum sensing perspective as well. The unavoidable RF impairments, e.g., oscillator phase noise in direct-conversion receiver, could generate crosstalk between multiple channels that are down-converted simultaneously, and thus considerably limit the spectrum sensing capabilities. Most of the existing spectrum sensing studies in literature assume an ideal RF receiver and have not considered such practical RF hardware problem. In this article, we study the impact of oscillator phase noise on energy detection (ED) based spectrum sensing in multi-channel direct-conversion receiver scenario. With complex Gaussian primary user (PU) signal models, we first derive the detection and false alarm probabilities in closed-form expression. The analytical results, verified through extensive simulations, show that the wideband multi-channel sensing receiver is very sensitive to the neighboring channel crosstalk induced by oscillator phase noise. More specifically, it is shown that the false alarm probability of multi-channel energy detection increases significantly, compared to the ideal RF receiver case. The exact performance degradation depends on the power of neighboring channels as well as statistical characteristics of the phase noise in the deployed receiver. In order to prevent such performance degradation in spectrum identification, an enhanced energy detection technique is proposed. The proposed technique calculates the leakage power from neighboring channels for each channel and improves the sample energy statistics by subtracting this leakage power from the raw values. An analytical expression is derived for the leakage power which is shown to be a function of power spectral levels of neighboring channels and 3-dB bandwidth of phase noise process. Practical schemes for estimating these two quantities are discussed. Extensive computer simulations show that the proposed enhanced detection yields false alarm rates that are very close to those of an ideal RF receiver and hence clearly outperforms classical energy detection.     

T–T–T behaviour of bioactive glasses 1–98 and 13–93

In this work crystallization kinetics of bioactive glasses 1–98 and 13–93 are discussed. Within a certain temperature–time window these glasses can be hot worked into various products without interfering with crystallization. The crystallization was studied isothermally by heating glass plates at different temperatures for different times. Phases in the samples were studied through XRD and SEM analyses. The nucleation-like curves and crystallization characteristics were measured with DTA. The temperature of maximum nucleation was measured for glass 1–98 at 725 °C and for 13–93 at 700 °C. The activation energy of crystallization of both glasses was 280 kJ/mol. The Johnson–Mehl–Avrami exponent and the SEM micrographs of the samples suggested surface crystallization. The primary crystalline phase was wollastonite. The growth rate of the crystallized surface layer was 1 order of magnitude higher in the plates of 1–98 than in 13–93. The results can be utilized to optimize the parameters in hot-working of the glasses.     

Quadrature ���� Modulators for Cognitive Radio��I/Q Imbalance Analysis and Complex Multiband Principle

This article discusses the applicability of quadrature ΣΔ modulator (QΣΔM) based analog-to-digital (A/D) conversion in cognitive radio (CR) receivers. First, unavoidable in-phase/quadrature (I/Q) mismatch effects, limiting the dynamic range, are analyzed in closed-form in the case of a first-order modulator. In addition, using the derived analytical converter model, it is shown that notching the signal transfer function (STF) of the modulator at the mirror frequencies of the desired signals will effectively cancel the I/Q imbalance induced mirror-frequency interference in case of the modulator feedback mismatch. In practice, such STF design is easy to implement within the existing converter circuitry, as will be demonstrated in this article. The latter part of the article proposes a novel complex multiband QΣΔM scheme, particularly aimed for the CR receivers. This multiband scheme allows parallel reception of scattered frequency chunks in the CR context and is stemming from the additional degrees of freedom in noise transfer function (NTF) design, provided by the QΣΔM principle. Here multiple noise shaping notches on distinct frequencies are effectively realized through proper design of complex NTF. The modulator structure also allows flexible reconfigurability of the notches with straightforward parameterization of the modulator transfer functions. When combined with the above mirror-frequency rejecting STF design, the concept is demonstrated and proved effective and robust against I/Q imbalances using practical radio signal simulations in realistic received signal conditions.