最低点火温度条件下煤粉自燃特性试验研究

火电厂及煤化工行业中需要将原煤加工成煤粉,煤粉在制备及输送过程中具有粒度小、环境温度高和供氧条件充分等特点,易发生自燃现象。最低点火温度Tm指在一定条件下煤粉能够发生自燃的最低环境温度,是衡量煤粉自燃危险性的重要参数。因此,研究煤粉在最低点火温度下的自燃特性参数及热动力学行为,对了解在最低点火温度时煤粉自燃行为、建立相应的预警机制具有重要意义。以3种不同变质程度的煤粉(张家卯弱黏煤ZJM、兖州气煤YZ和长治贫瘦煤CZ)为研究对象,采用油浴程序控温试验装置对煤样自燃特性进行测试,确定了3种煤粉的Tm和延迟点火时间ti;得出最低点火温度下各煤样耗氧速率、CO及C2H4产生量的变化规律;采用热动力学分析方法计算了3种煤粉的表观活化能。试验结果表明:①ZJM、YZ和CZ煤粉的最低点火温度分别为120、130、164℃,随变质程度的增加而增加;煤的变质程度越高,内部活性基团数量越少,自燃需要热量更多,导致高变质程度煤的最低点火温度较高;3种煤粉在最低点火温度处的延迟点火时间均约为20 min。②耗氧速率呈现出先增加后缓慢减少的趋势,在试验后期由于氧气浓度较低,引起煤粉氧化反应强度降低,最终导致耗氧速率出现缓慢下降;最低点火温度处的CO产生量随时间呈现出先升高后降低趋势,当煤粉温度约120℃时,产生C2H4。③最低点火温度处ZJM、YZ和CZ煤粉的表观活化能分别为24.33、29.50和18.67 kJ/mol,其中变质程度最高的CZ煤粉的表观活化能低于另外2个煤样,这表明高变质程度煤样的最低点火温度高,初期氧化反应速率较高。     

户内热转印粉末涂料用混合型聚酯树脂的合成研究

通过分析热转印性能的影响因素合成了不同结构的聚酯树脂，研究了树脂酸值对热转印性能的影响，同时研究了部分单体对聚酯树脂热转印性能的影响。采用 DSC热分析法研究了固化促进剂对粉末涂料固化行为的影响，结果表明：选择合适的固化促进剂对涂层转印性能的提高有至关重要的作用。     

石墨烯复合功能材料及其在重金属离子检测的电化学研究与应用

石墨烯(GR)是典型的单原子碳纳米材料,具有独特的二维共辄平面结构,其高活性的比表面积和突出的导电性能,在电催化和敏感材料制备领域已得到广泛的应用。氧化石墨烯(GO)作为GR的前驱体,存在大量的含氧官能团,具有良好的水溶分散性。大量GO含氧官能团的介入会破坏其K-7T共辘结构,导致其电学性能变差。GO通过化学、水热合成或直接电化学还原方法可有效修复其共辄平面结构,得到导电性良好的还原氧化石墨烯(rGO),即GR.单组分的GR材料在实际应用中仍存在某些局限性,如电学活性相对较弱,与其它材料加工复合性能较差等。将GR、G O材料与其它功能材料进行复合,可进一步改善复合物的物理或化学性能,如分散性、加工修饰和电催化活性等。综述了石墨烯材料与金属及其氧化物纳米粒子、聚合物、掺杂原子、导电离子液体、碳纳米材料等功能材料复合后,能形成可调控的微结构,具有改性的化学性质和协同发挥的电学效应,表现出显著的电子传递能力及其功能性作用。论述了GR功能化修饰的复合材料作为敏感界面,构筑基于重金属离子检测的电化学生物传感器,可以实现对Pb2+,Hg2+,C『+等多种重金属离子的同时或分别检出,提出了GR复合制备材料的纳米结构特征、功能修饰作用对于提高传感器的电催化活性和选择性性能等方面的应用,并对该研究领域进行了总结与展望。     

改性橡胶混凝土在复合盐冻融循环-风沙冲蚀作用下损伤研究

使用15％(质量分数)NaOH溶液对橡胶颗粒浸泡改性处理,研究普通混凝土、未改性橡胶混凝土和改性橡胶混凝土力学性能变化,采用模拟风沙环境侵蚀实验系统对复合盐冻融循环后的混凝土试件进行冲蚀试验,探究改性橡胶混凝土在复合盐冻融循环-风沙冲蚀作用下的损伤机理.结果表明:15％(质量分数)NaOH溶液改性橡胶混凝土较未改性橡胶混凝土强度提高,弹性模量进一步降低,韧性有所提高;改性橡胶混凝土在抗风沙冲蚀性能方面仍表现出脆性材料特性;80目(0.18 mm)橡胶混凝土抗复合盐冻融循环性能最优,10目(2.00 mm)橡胶混凝土抗风沙冲蚀性能最佳,NaOH溶液对不同粒径橡胶混凝土不同性能的改性作用也不同;改性橡胶混凝土对抗复合盐冻融循环性能和抗冲蚀性能均有一定的改善作用,通过微观形貌分析其主要原因为改性橡胶颗粒与混凝土基体粘结作用更强,弹性变形更大.     

Achievable working range for solid all-desiccant air-conditioning systems under specific space comfort requirements

Solid desiccant air-conditioning systems present a promising solution, in terms of performance level and environmental protection, pointing out their potential to be coupled with thermal solar or waste heat energy source. Nevertheless, these systems are characterized by constraints to the load they can satisfy, through the trade-off between the dehumidification cooling capacity and the latent load of the conditioned space. On that level, one has to note that, for steady environmental conditions, the conditioned space does not present unique value of load, but range of load, corresponding to an array of acceptable temperature and (usually relative) humidity values. In this work a methodology is proposed for the definition of the system's achievable working range under specific set of space (comfort) requirements. Through this approach, the systems present greater potential for covering the space requirements, thus presenting more possibilities on a design basis, and more flexible control strategies, as well. The proposed methodology is presented and discussed through the case study of a solar desiccant air-conditioning system coupled to a typical residential building.     

国家体育馆双向张弦结构预应力施工模型试验研究

通过模型试验研究了国家体育馆屋盖双向张弦结构的预应力施加方法。从索力大小、钢结构应力和竖向位移及其变化幅度等方面对比分析了两种张拉方法的优缺点。最后得出适合国家体育馆的预应力施工方案,所得结论对双向张弦结构预应力施工方法具有实际借鉴意义。     

采空区渗透率演化规律及卸压开采效果研究

为了研究保护层开采过程中采空区渗透率的演化规律、分布特征以及对被保护层卸压增透效果,在充分利用淮南某矿1242(1)工作面抽采监测数据的基础上对地面钻井抽采卸压煤层及采空区瓦斯的流量计算模型进行了简化,结合达西定律给出了采空区等效渗透率的计算模型。在此基础上,通过拟合被保护层瓦斯抽采量得出各钻井的瓦斯衰减系数,并引入瓦斯涌出衰减系数减小倍数来反映保护层卸压增透效果。研究结果表明:1)采空区渗透率随着保护层工作面的推进经历急剧升高、缓慢降低以及稳定3个阶段,前2个阶段对应的工作面推进长度分别为19.24,186.2 m;工作面回采结束后,采空区中部渗透率最低,向边缘逐渐增大,呈横"O"型分布。2)被保护层瓦斯抽采同样经历3个阶段:急剧升高阶段、衰减阶段以及稳定阶段,前2个阶段经历的平均时间分别为10 d和125 d。3)1#钻井的瓦斯涌出衰减系数减小倍数高达7.7,表明了保护层卸压效果十分显著。     

Insight into the selective oxidation mechanism of glycerol to 1,3-dihydroxyacetone over AuCu–ZnO interface

Directional regulation of polyol oxidation selectivity by constructing active sites with specific structure is a critical yet challenging problem. Herein, the specific Au-based catalyst with efficient Au–Cu–ZnO interfacial active sites was successfully designed to promote selective oxidation of glycerol to 1,3-dihydroxyacetone under mild conditions. X-ray absorption spectroscopy revealed that the increased electron transfer between Au and Cu increases the content of Au⁺, resulting in the higher catalytic activity (turnover frequency: 402.5 h⁻¹). Meanwhile, small AuCu alloy nanoparticles (ca., 2.7 nm) could be inserted into the ZnO lattice with the formation of Au(Cu)–O–Zn linkages, resulting in the enrichment of interfacial oxygen vacancies. These interfacial oxygen vacancies induce the activation and adsorption of the secondary hydroxyl group of glycerol on the interfacial active sites, improving the selectivity of 1,3-dihydroxyacetone (83.4%). Furthermore, in situ Fourier transform infrared, structure-dependent kinetics and density functional theory calculation demonstrated that Au–Cu–ZnO interfacial active sites could enhance the participation of OH* and oxygen vacancies in activating the O H and C H bonds, respectively, promoting the improvement of the catalytic performance. The outcome of this work offers new insights for the rational design of high effective catalyst for the selective oxidation of polyol.     

低温脱硝催化剂研究进展

在传统选择性催化还原技术（SCR）催化剂的基础上,分别以钒-钛系催化剂、固溶体催化剂和新型MnO _x 催化剂为重点介绍了近些年低温SCR催化剂的研究进展,综述了不同活性组分的复合型催化剂的制备方法、元素掺杂、反应机理和抗性等,并通过分析不同复合型催化剂的表征总结了催化剂的性能状况以及低温脱硝效率,着重阐述了新型MnO _x 催化剂所具有的优异脱硝特性,认为通过改性提高新型MnO _x 的抗水抗硫性将会成为该领域未来的发展方向和研究热点,最后介绍了不同负载体对新型MnO _x 催化剂的催化效率的影响规律,发现二氧化钛负载体具有良好的抗水性,三氧化二铝负载体能显著增强催化活性,二氧化铈负载体的热稳定性较好。     

Optimization of optical single sideband configurations for radio over fiber transmission and multi-type data communication over a DWDM link

Two new optical single side band (OSSB) configurations for radio frequency (RF) transmission of data are proposed based on the structures that have been designed for baseband digital data transmission. The performances of these schemes are evaluated based on the relevant eye diagrams and bit error rate (BER). The proposed configurations are studied and analyzed mathematically. Eye diagrams and BER’s indicate an acceptable performance for the suggested structures. Feasible settings for the RF electrical power of the links are considered and the link performance for each setting is evaluated. A 4-dense wavelength division multiplexing (4-DWDM) link is considered for transmitting different types of data over a single mode fiber (SMF). Baseband digital data in the format of OSSB and RF-OSSB signals are transmitted over a 4-DWDM link. Furthermore, the link performance is considered for different electrical power settings of OSSB signal in order to achieve efficient transmission for DWDM network.