Electrically and thermally conductive elastomer/graphene nanocomposites by solution mixing

The greatest challenge in developing polymer/graphene nanocomposites is to prevent graphene layers stacking; in this respect, we found effective solution-mixing polymers with cost-effective graphene of hydrophobic surface. Since graphene oxide is hydrophilic and in need of reduction, highly conducing graphene platelets (GnPs) of ∼3 nm in thickness were selected to solution-mix with a commonly used elastomer – styrene–butadiene rubber (SBR). A percolation threshold of electrical conductivity was observed at 5.3 vol% of GnPs, and the SBR thermal conductivity enhanced three times at 24 vol%. Tensile strength, Young's modulus and tear strength were improved by 413%, 782% and 709%, respectively, at 16.7 vol%. Payne effect, an important design criteria for elastomers used in dynamic loading environment, was also investigated. The comparison of solution mixing with melt compounding, where the same starting materials were used, demonstrated that solution mixing is more effective in promoting the reinforcing effect of GnPs, since it provides more interlayer spacing for elastomer molecules intercalating and retains the high aspect ratio of GnPs leading to filler–filler network at a low volume fraction. We also compared the reinforcing effect of GnPs with those of carbon black and carbon nanotubes.     

Retraining local and global buckling behavior of steel plastic hinges using CFRP

Carbon fiber-reinforced polymer (CFRP) composites have been shown to be particularly well suited for external strengthening of reinforced concrete members. However, there is limited information about how they can be used to strengthen steel structures that are susceptible to local and global instabilities. This paper discusses test results of full-scale steel flexural specimens subjected to reversed cyclic loading, some of which are wrapped with CFRP in the plastic hinge region. The main variables investigated are lateral bracing, to study the effect of CFRP wrapping on local buckling and lateral torsional buckling, wrapping scheme, and number of layers of fibers. The test results show that application of CFRP in the plastic hinge region of flexural members has substantial benefits. In particular, the CFRP wraps can increase the size of the yielded plastic hinge region, slow down the occurrence of local buckling, and delay lateral torsional buckling. These benefits reduce strain demands in the critical plastic hinge region and substantially improve energy dissipation capacity within the plastic hinge region.     

Pushdown resistance as a measure of robustness in progressive collapse analysis

This paper presents a technique termed ‘pushdown analysis’ that can be used to investigate the robustness of building systems by computing residual capacity and establishing collapse modes of a damaged structure. The proposed method is inspired by the pushover method commonly used in earthquake engineering. Three variants of the technique, termed uniform pushdown, bay pushdown and incremental dynamic pushdown, are suggested and exercised using nonlinear analysis on 10-story steel moment frames designed for moderate and high levels of seismic risk. Simulation results show that the frame designed for high seismic risk is more robust than the corresponding one designed for moderate seismic risk. The improved performance is attributed to the influence of seismic detailing, specifically, the presence of reduced beam sections and stronger columns. It is shown that the dynamic impact factors associated with column removal are significantly lower than the commonly used value of 2.0 and are in line with lower values in the guidelines recently proposed by the US Department of Defense. The study suggests that seismic ‘fuses’ can play a role in the design for robustness and a discussion of the implications of this observation is provided.     

Behavior of bridge girders with corrugated webs under monotonic and cyclic loading

The focus of this study is to investigate the behavior of plate girders with trapezoidally corrugated webs under fatigue loading. Six girders were tested under both monotonic and cyclic four-point loading arrangements. A relationship between the stress range, F_r, and the number of cycles to failure, N, was developed for the girders. The results from the fatigue tests were related to the current AASHTO specifications and compared with the test results of different types of girders carried out by others. Nonlinear finite element analyses were conducted to study the effects of the different geometrical parameters of this type of girders on the stress concentrations at different locations and to explain the findings of the experimental study. Two sources of stress concentration leading to fatigue cracking were isolated and evaluated; one is dependent on the radius of curvature between the web folds and the other depends on the inclination angle of the inclined fold. An analytical technique based on fracture mechanics is also proposed to enable designers to determine the fatigue life of corrugated web steel girders.     

Online model-based diagnosis to support autonomous operation of an advanced life support system

This article describes methods for online model-based diagnosis of subsystems of the advanced life support system (ALS). The diagnosis methodology is tailored to detect, isolate, and identify faults in components of the system quickly so that fault-adaptive control techniques can be applied to maintain system operation without interruption. We describe the components of our hybrid modeling scheme and the diagnosis methodology, and then demonstrate the effectiveness of this methodology by building a detailed model of the reverse osmosis (RO) system of the water recovery system (WRS) of the ALS. This model is validated with real data collected from an experimental testbed at NASA JSC. A number of diagnosis experiments run on simulated faulty data are presented and the results are discussed.     

Microwave-Assisted Synthesis of the Flexible Iron-based MIL-88B Metal–Organic Framework for Advanced Energetic Systems

The 3D metal–organic framework (MOF), MIL-88B, built from the trivalent metal ions and the ditopic 1,4-Benzene dicarboxylic acid linker (H₂BDC), distinguishes itself from the other MOFs for its flexibility and high thermal stability. MIL-88B was synthesized by a rapid microwave-assisted solvothermal method at high power (850 W). The iron-based MIL-88B [Fe₃.O.Cl.(O₂C–C₆H₄–CO₂)₃] exposed oxygen and iron content of 29% and 24%, respectively, which offers unique properties as an oxygen-rich catalyst for energetic systems. Upon dispersion in an organic solvent and integration into ammonium perchlorate (AP) (the universal oxidizer for energetic systems), the dispersion of the MOF particles into the AP energetic matrix was uniform (investigated via elemental mapping using an EDX detector). Therefore, MIL-88B(Fe) could probe AP decomposition with the exclusive formation of mono-dispersed Fe₂O₃ nanocatalyst during the AP decomposition. The evolved nanocatalyst can offer superior combustion characteristics. XRD pattern for the MIL-88B(Fe) framework TGA residuals confirmed the formation of α-Fe₂O₃ nanocatalyst as a final product. The catalytic efficiency of MIL-88B(Fe) on AP thermal behavior was assessed via DSC and TGA. AP solely demonstrated a decomposition enthalpy of 733 J g^?1, while AP/MIL-88B(Fe) showed a 66% higher decomposition enthalpy of 1218 J g^?1; the main exothermic decomposition temperature was decreased by 71 °C. Besides, MIL-88B(Fe) resulted in a decrease in AP decomposition activation energy by 23% and 25% using Kissinger and Kissinger–Akahira–Sunose (KAS) models, respectively.

     

Optimal throughput performance in full-duplex relay assisted cognitive networks

Wireless Networks - In this paper, we study a full-duplex cooperative cognitive radio network with multiple full-duplex secondary users acting as potential relays for transmitting the packets of a...     

Ultra-high performance concrete and fiber reinforced concrete: achieving strength and ductility without heat curing

Ultra-high performance concrete (UHPC) and ultra-high performance fiber reinforced concrete (UHP-FRC) were introduced in the mid 1990s. Special treatment, such as heat curing, pressure and/or extensive vibration, is often required in order to achieve compressive strengths in excess of 150 MPa (22 ksi). This study focuses on the development of UHP-FRCs without any special treatment and utilizing materials that are commercially available on the US market. Enhanced performance was accomplished by optimizing the packing density of the cementitious matrix, using very high strength steel fibers, tailoring the geometry of the fibers and optimizing the matrix-fiber interface properties. It is shown that addition of 1.5% deformed fibers by volume results in a direct tensile strength of 13 MPa, which is 60% higher than comparable UHP-FRC with smooth steel fibers, and a tensile strain at peak stress of 0.6%, which is about three times that for UHP-FRC with smooth fibers. Compressive strength up to 292 MPa (42 ksi), tensile strength up to 37 MPa (5.4 ksi) and strain at peak stress up to 1.1% were also attained 28 days after casting by using up to 8% volume fraction of high strength steel fibers and infiltrating them with the UHPC matrix.     

On business process monitoring using cross-flow coordination

This paper presents an approach for monitoring the execution progress of business processes. The monitoring focuses on the exceptions that could arise during this execution and, hence, could make the processes fail if not handled properly and timely. The approach relies on three flows known as control, communication, and navigation. The control flow connects tasks together with respect to a certain business logic. The communication flow captures the messages exchanged between persons/machines when they perform tasks of processes. Finally, the navigation flow captures the interactions between specialized networks that offer solutions to exceptions. These networks are built upon relations between tasks, between persons, and between machines. The coordination of control, communication, and navigation flows focuses on both the actions that are taken and the messages that are exchanged when handling exceptions. A system demonstrating flow development and coordination is, also, presented in the paper.