首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   543篇
  免费   16篇
  国内免费   2篇
电工技术   4篇
化学工业   77篇
金属工艺   27篇
机械仪表   10篇
建筑科学   33篇
矿业工程   2篇
能源动力   14篇
轻工业   61篇
水利工程   2篇
石油天然气   3篇
无线电   65篇
一般工业技术   75篇
冶金工业   43篇
原子能技术   8篇
自动化技术   137篇
  2023年   3篇
  2022年   2篇
  2021年   7篇
  2020年   9篇
  2019年   8篇
  2018年   11篇
  2017年   7篇
  2016年   16篇
  2015年   10篇
  2014年   18篇
  2013年   35篇
  2012年   24篇
  2011年   24篇
  2010年   35篇
  2009年   36篇
  2008年   19篇
  2007年   21篇
  2006年   23篇
  2005年   18篇
  2004年   18篇
  2003年   29篇
  2002年   14篇
  2001年   9篇
  2000年   13篇
  1999年   15篇
  1998年   9篇
  1997年   9篇
  1996年   5篇
  1995年   5篇
  1994年   11篇
  1993年   2篇
  1992年   8篇
  1991年   2篇
  1990年   3篇
  1989年   4篇
  1988年   4篇
  1987年   6篇
  1986年   5篇
  1985年   7篇
  1984年   5篇
  1982年   3篇
  1981年   2篇
  1980年   3篇
  1979年   7篇
  1978年   6篇
  1977年   10篇
  1976年   4篇
  1975年   3篇
  1974年   5篇
  1970年   5篇
排序方式: 共有561条查询结果,搜索用时 125 毫秒
1.
The structural role of V in 28Li2O–72SiO2 (in mol%) lithium silicate glass doped with 0.5 mol% V2O5 was assessed using 29Si and 51V Nuclear Magnetic Resonance (NMR), Fourier-transform infrared (FTIR), and X-ray photoelectron (XPS) spectroscopy techniques. Despite the low amount of V2O5 used, the structural information obtained or deduced from the statistical analysis of the NMR data could explain the evolution of glass properties after V2O5 addition. The XPS results indicated that all vanadium exists in 5+ oxidation state. Both the 29Si NMR and FTIR data point toward an increase in the polymerization of the silicate network, caused by the V2O5 acting as network former, capable to form various tetrahedral units (for n = 0, 1, and 2) in the glasses. These units, which are similar to phosphate units, scavenge the Li+ ions and cause the silicate network to polymerize. However, in an overall balance, the entire glass network is depolymerized due to the additional nonbridging oxygens contributed by the vanadium polyhedra. The addition of vanadium causes the network to expand and increases the ionic conductivity.  相似文献   
2.
Two-dimensional transistors are promising candidates for the next generation of nanoscale devices. Like the other alternatives, they also encounter problems such as instability under standard condition (STP), low channel mobility, small band gaps, and difficulty to integrate metal contacts. The latter poses a great challenge since metal/semiconductor interface significantly affects the transistor‘s performance. Some of these obstacles can be solved by using two-dimensional transition metal di-chalcogenides (TMDC) materials. In this study, we performed charge transport calculation based on density functional theory (DFT) followed by wave dynamics to evaluate the performance of six two-dimensional TMDC metal/semiconductor/metal systems. Each semiconductor monolayer was laterally connected, at both ends to metal contacts consisting of VS2 or FeS2 monolayers. We found that charge transport was more efficient in systems containing a CrS2 semiconductor monolayer compared to systems with MoS2 or WS2 as the semiconductor monolayer. The electronic characterization of the monolayer TMDC materials by DFT estimates well the trend in charge transport efficiency calculated using wave packet dynamics.  相似文献   
3.
4.
This article deals with some high-order approximations of the three-phase-lag heat transfer model aiming, at first, to identify the restrictions that make them well-posed consistence. Consequently, a first result about the uniqueness and continuous dependence of the solutions with respect to the given initial data and to the supply term is established for the related initial boundary value problems. Subsequently, to provide a more comprehensive analysis of the model, some further spatial decay results are established, this time conveniently relaxing the hypotheses about the delay times and the thermal conductivities. More precisely, a theorem of influence domain is proved for the wave propagating models and an exponential decaying estimate of Saint-Venant type is established for the diffusive models.  相似文献   
5.
Disbudding is a routine practice in many dairy herds due to the effort to decrease the risk of injuries. Although the disbudding practice is regulated, it can vary among farms. The variation may be caused by many factors, such as herd size or type of breed, but also by farmers' perception of pain caused by disbudding. Hence, the aim of this study was to specify the disbudding practice on dairy farms in the Czech Republic and to assess these practices, including the use of pain mitigation medication, by breed, herd size, and sex of the disbudded calves. We analyzed data from 106 Czech dairy farms, which were collected by a trained interviewer at dairy meetings in 2014–2015. The farmers answered questions regarding the farm's basic characteristics, disbudding practice, and his/her attitude to the pain caused by disbudding. To test the influence of breed, herd size, and sex of disbudded calves on different variables, logistic regression models were used. Disbudding was performed in 92.5% of the surveyed farms; 63.3% of dairy calves were disbudded before 4 wk of age, and Czech Fleckvieh calves were 2.8 times more likely to be disbudded before 4 wk of age than Holstein calves. The hot-iron method was the most used method (69.4%). Calves were 4.5 times more likely to be disbudded by hot iron in herds where both heifers and bulls were disbudded than in herds where only heifers were disbudded. Most (>90%) surveyed farms did not use any pre- or post-procedure medication to mitigate the pain caused by disbudding. The disbudding procedure was performed mainly by farm personnel (94.9%), who were trained by a veterinarian or veterinary technician (46.9%) or by other farm personnel (37.8%) or were not trained (15.3%). Two-thirds of farmers observed behavioral changes in calves after disbudding. Most farmers estimated the pain caused by disbudding to be mild or moderate (20.4 or 45.9%, respectively) and 15.3% of farmers estimated it to be severe. Almost a quarter of interviewed farmers were unable to assess the duration of pain, 39.8% farmers estimated that the pain lasts only several minutes, and 20.4% estimated that the pain lasts up to 6 h. We detected a tendency that farmers of larger herds estimated pain duration to be shorter (odds ratio = 1.2). To improve calves' welfare, training is needed in disbudding practice, focusing on the advantage of pain mitigation.  相似文献   
6.
There has been a growing interest in plant proteins due to their beneficial health effects, low cost and variety of applications in food industries. The low solubility of lentil proteins (LPs) is one of the significant factors that limit their use in food applications. Quinoa proteins (QPs), which have high water solubility, were combined with LPs at pH 12 to generate LP-QP complexes to generate pH-based soluble protein compounds. The LP-QP complexes demonstrated a large surface charge with an increase solubilisation of the protein complexes by more than 85%, together with resistance to protein aggregation. The combination of LPs to QPs led to a significant increase (P < 0.05) in unique tertiary and secondary protein structures as determined by the protein–protein interaction (PPI) technique involving pH recycling. Interactions between LPs and QPs affected the surface morphology of the protein complexes formed. Electrostatic interactions, hydrophobic forces and hydrogen bonding were indicated to play key roles in the PPIs. The capacity of pH cycling to illustrate the above protein interactions shows that this is a robust approach for assessing the emulsion and foaming properties of food proteins.  相似文献   
7.
Gadolinium iron garnet was obtained from two different precursors, homogenized in isopropyl alcohol and in an aqueous environment with a fixed pH. In the first case, it was a mixture of goethite (FeO(OH)) and gadolinium oxide (Gd2O3); in the second, a mixture of GdIP (GdFeO3) and α-Fe2O3. Conditions of homogenization in the aqueous environment were selected based on the zeta (ξ) potential measurements as the function of pH. DSC measurements of the output powder mixtures allowed the identification of the effects observed during the temperature rise. In the case of the material obtained from a mixture of goethite (FeO(OH)) and gadolinium oxide, with the increasing temperature, we observe three effects, the first of which corresponds to the phase transformation of goethite into α-Fe2O3, the second corresponds to the reaction of gadolinium iron perovskite (GdIP) formation, and the third to the reaction in which a gadolinium iron garnet (GdIG) is formed. However, in the case of heat treatment of the mixture of GdIP and α-Fe2O3, we only observe the effect responsible for a solid state reaction leading to the formation of gadolinium iron garnet. Dilatometric measurements allowed to determine the changes in linear dimensions at various stages of reaction sintering. The resulting materials were sintered at temperatures of 1200, 1300, and 1400 °C. In the case of the material obtained from a mixture of perovskite and iron (III) oxide, already at the temperature of 1300 °C, a density has been obtained at around 95% of the theoretical density, and the temperature of 1400 °C allowed achieving a density of 97% of the theoretical density. Whereas, for the material obtained from a mixture of goethite (FeO(OH)) and gadolinium oxide, a density above 95% of theoretical density was achieved only at 1400 °C.  相似文献   
8.
The objectives of this study were to examine varying extraction conditions of Thymus vulgaris L. as related to phenolic content and profiles of the extracts and their antioxidant, antihypertensive and antidiabetic properties. Phenolics were extracted under various conditions pertaining to free and bound phenolics, solvent type and combination of extraction time and temperature, and these extracts were evaluated in terms of their antioxidant activities and inhibitory activities of angiotensin‐converting enzyme (ACE), α‐glucosidase and α‐amylase. The acetone–water solvent mixture (1:1; v/v) produced the extract with the greatest phenolic content, antioxidant activity and inhibitory activities of ACE and α‐glucosidase. The optimal extraction temperature for maximum phenolic content and antioxidant activity associated with methanol extraction was 60 °C, whereas a lower temperature at 40 °C was required to maximise inhibitory activities for ACE, α‐glucosidase and α‐amylase. An inverse relationship was seen between antioxidant and glucosidase inhibitory activities vs. the ACE and α‐amylase inhibitory activities, which suggests the need for extractions to be directed to specific bioactivities of thyme extracts. Generally, the results indicate major differences in phenolic profiles among the tested extraction conditions with thymol as the predominant phenolic seen in most extractions, while gallic acid, rosmarinic acid or diosmin also predominated in other extracts. Extracts with the same predominant phenolic compound and similar phenolic content showed major disparities in their ACE, glucosidase and α‐amylase inhibitory activities, indicating that the major phenolic profiles of thyme extracts may not be necessarily related to the degree of inhibition of ACE, glucosidase and α‐amylase enzymes.  相似文献   
9.
Given a Feynman parameter integral, depending on a single discrete variable NN and a real parameter εε, we discuss a new algorithmic framework to compute the first coefficients of its Laurent series expansion in εε. In a first step, the integrals are expressed by hypergeometric multi-sums by means of symbolic transformations. Given this sum format, we develop new summation tools to extract the first coefficients of its series expansion whenever they are expressible in terms of indefinite nested product–sum expressions. In particular, we enhance the known multi-sum algorithms to derive recurrences for sums with complicated boundary conditions, and we present new algorithms to find formal Laurent series solutions of a given recurrence relation.  相似文献   
10.
This paper details the adaptation and implementation of a proposed hierarchical model to the reliability assessment of LED-based luminaires. An Edison base ? 6 in., compatible can, downlight ? LED replacement bulb, cooled by active synthetic jets, is used as the test vehicle. Based on the identified degradation mechanisms and the experimentally obtained degradation rate of the cooling device, the reduction in the heat sink enhancement factor, and thus the increase in the LED junction temperature, is determined as a function of time. The degradation mechanisms of the dual-function power electronics – providing constant power to the LEDs and to the drivers of a series of synthetic jets – are also analyzed and serve as the basis for a hybrid model which combines these two effects on the luminaire lifetime. The lifetime of a prototypical luminaire is predicted from LED lifetime data using the degradation analyses of the synthetic jet and power electronics.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号