Emissions of DEHP‐free PVC flooring

Degrading 2‐ethylhexyl‐containing PVC floorings (eg DEHP‐PVC floorings) and adhesives emit 2‐ethylhexanol (2‐EH) in the indoor air. The danger of flooring degradation comes from exposing occupants to harmful phthalates plasticisers (eg DEHP), but not from 2‐EH as such. Since the EU banned the use of phthalates in sensitive applications, the market is shifting to use DEHP‐free and alternative types of plasticisers in PVC products. However, data on emissions from DEHP‐free PVC floorings are scarce. This study aimed at assessing the surface and bulk emissions of two DEHP‐free PVC floorings over three years. The floorings were glued on the screed layer of concrete casts at 75%, 85%, and 95% RH. The volatile organic compounds (VOCs) were actively sampled using FLEC (surface emissions) and micro‐chamber/thermal extractor (µ‐CTE, bulk emissions) onto Tenax TA adsorbents and analyzed with TD‐GC‐MS. 2‐EH, C9‐alcohols, and total volatile organic compound (TVOC) emissions are reported. Emissions at 75% and 85% RH were similar. As expected, the highest emissions occurred at 95% RH. 2‐EH emissions originated from the adhesive. Because the two DEHP‐free floorings tested emitted C9‐alcohols at all tested RH, it makes the detection of flooring degradation harder, particularly if the adhesive used does not emit 2‐EH.     

Chlorate Formation in Chlorine Dioxide Delignification—An Analysis via Elementary Kinetic Modeling

Abstract

Elementary kinetic modeling was used to study the mechanism of chlorate formation in chlorine dioxide delignification. Reaction conditions reflecting typical industrial processes (T = 50°C, pH 1.5–4) were examined. Fe mediated Cl(III) decomposition and a reaction between hypochlorous acid and chlorous acid (or their equilibrium counterparts) were found to be the major reaction routes responsible for chlorate formation at pH < 3. The latter route accounts for chlorate formation at pH ≥ 3. The rate of chlorous acid (HClO₂) self-decomposition was too slow either to compete against the other routes (pH < 3) or to yield notable amounts of chlorate within the given time frame (pH ≥ 3). The results suggest that chlorate formation could be suppressed, without adverse effects on chlorine dioxide regeneration, by aiming for end pH 3–3.5, ensuring a moderate chloride ion concentration and by favoring concentrated solutions/suspensions.     

A Model for Chlorine Dioxide Delignification of Chemical Pulp

Abstract

A phenomenon based model for chlorine dioxide delignification of chemical pulp is introduced. The pulp suspension environment is modeled using the concept of two liquid phases, one inside and the other external to the fiber wall. Physico-chemical processes taking place during delignification are implemented with thermodynamic, mass transfer and reaction kinetic models. A broad library of chemical reactions is introduced. Inclusion of each reaction is justified. The model response is tested against experimental laboratory delignification results (o-delignified birch pulp). The experimental data consists of kappa number, hexenuronic acid, inorganic oxy-chlorine compound, and organochlorine (AOX, OX) measurements at several time points during five delignification experiments. The model predictions are mainly in good agreement with the experimental results. The predictions regarding hypochlorous acid driven processes (HexA removal, organochlorine formation, chlorite and chlorate concentration) are somewhat incoherent, indicating that knowledge regarding the intermediately formed hypochlorous acid is presently insufficient.     

Hippocampal theta-band activity and trace eyeblink conditioning in rabbits.

The authors examined the relationship between hippocampal theta activity and trace eyeblink conditioning. Hippocampal electrophysiological local field potentials were recorded before, during, and after conditioning or explicitly unpaired training sessions in adult male New Zealand White rabbits. As expected, a high relative power of theta activity (theta ratio) in the hippocampus predicted faster acquisition of the conditioned response during trace conditioning but, contrary to previous results obtained using the delay paradigm, only in the initial stage of learning. The presentation of the conditioned stimulus overall elicited an increase in the hippocampal theta ratio. The theta ratio decreased in the unpaired group as a function of training, remained high throughout conditioning in the fast learners, and rapidly increased in the slow learners initially showing a low theta ratio. Our results indicate a reciprocal connection between the hippocampal oscillatory activity and associative learning. The hippocampal theta ratio seems to reflect changes and differences in the subjects’ alertness and responsiveness to external stimuli, which affect the rate of learning and are, in turn, affected by both conditioning and unpaired training. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Behavioral and neural characteristics of short-latency and long-latency conditioned responses in cats.

Studied head movements to a tone to the left ear (conditioned stimulus [CS]) in 6 cats. An attempt was made to differentiate an orienting, short-latency (alpha) response from the long-latency conditioned (delayed) response. The unconditioned stimulus (UCS) was a brain stimulation to the lateral hypothalamus eliciting a specific, stereotypical head movement. These behavioral characteristics of the unconditioned head movement were used for differentiating it from the conditioned short-latency head movement. Paired conditioning and randomly unpaired control sessions (5 daily sessions each) were given in balanced order to each S. Evoked neural responses in the hippocampus and cingulate cortex were recorded simultaneously to compare the time–amplitude characteristics of evoked responses to earlier findings in multiple-unit recordings. The results supported the differentiation of the behavioral responses. The time–amplitude course of the evoked neural responses showed complex changes, appearing as an increase in the negativity during the alpha-response period and as an increase in the positivity during the long-latency period on omitted-UCS (CS-alone test) trials. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Exit pupil expander with a large field of view based on diffractive optics

Abstract— The field of view is an important parameter of a near‐to‐eye display. To achieve an immersive viewing experience, the field of view should be as high as possible. Presently, in most of the commercially available devices the field of view is between 15° and 30°. In this paper, a large‐field‐of‐view exit pupil expander that is based on diffractive optics was demonstrated. Usually these types of diffractive expanders cannot have a field of view much more than 25°. Here, an exit pupil expander with an extended field of view, based on two stacked plates, was demonstrated. The expander is designed for green light and it achieves a field of view of more than 40°.     

MEMS助力推动下一代无线通信

未来的无线通信系统将具备各种新功能并高度微型化。而且,3代和4代多模/多波段无线终端设备将为新业务、互联网与Mcommerce(移动电子商务)数据、以及静态/视频图象提供网络连接。此外,终端设备也应具备更多新功能来吸引更多终端用户。微电子 机械(microelectromechanical,MEM)元件与系统可提高创新性3代产品的集成化水平,并可调整器件的特性和工作方式,因此可降低3代 图 产品的尺寸和成本。它们还将为 　　　无线系统带来新的体系结构和功耗管理特征。此外,MEMS还将推动新功能、传感器、执行器在无线终端设备上的集成。用户接口需要采用新的技术解决方案。微机械传感器和麦克风已经有元件形式的产品,它们可以被看作是更复杂、包括若干集成化传感器元件的智能系统的一个组成部分。对移动终端来说,娱乐和游戏功能是新功能开发的重要推动力,传感器和执行器也是如此。微反射镜和微透镜为照相机和显示器的实现带来了新的可能,如投影显示。因此MEMS将极大地促进未来无线系统的发展。本文将对 MEMS 在无线通信发展 中的应用进行探讨,首先讨论微系统 化、多功能器件在紧凑系统中的集成、...     

Effect of A-site metal on methane combustion on 2% Pd / AMn1-x Fe x O3 (A = Ba, La, Pr; x = 0.4, 0.6, 1) perovskites

Barium, lanthanum, and praseodymium perovskites were prepared by malic acid complexation. Surface areas of the La and Pr perovskites were between 17.1 and 21.6 m² g⁻¹. The moderate low surface areas (5.7 m² g⁻¹) observed for corresponding barium perovskites were due to the high calcination temperatures. The calcination temperature also affected the shapes and sizes of the perovskite particles. According to SEM images the nanoparticles of the La and Pr perovskites were spherical, whereas those of barium perovskites were flakes. The conversion of methane increased in the order of A-site metal Ba < Pr < La. The CH₄ conversion after SO₂ treatment correlated with size of the perovskite particles: the smaller the particles the better the activity. The highest methane conversion after SO₂ treatment was achieved with lanthanum perovskite with B-site metal combination Mn_0.4Fe_0.6.