Effect of Proximity and Dimension of Two Artificial Pitting Holes on the Fatigue Endurance of Aluminum Alloy AISI 6061-T6 Under Rotating Bending Fatigue Tests

This work deals with the study of the two artificial pitting holes effects, caused by their dimensions and proximity, on the fatigue endurance of aluminum alloy AISI 6061-T6 under rotating bending fatigue tests. Stress concentration induced by artificial pitting holes is analyzed and correlated with the experimental fatigue life. It is found that the stress concentration increases exponentially when the two pitting holes approach, and this induces an important reduction in the fatigue life. Concerning the diameter variation of one pitting in regard to the second, no important influence was observed on fatigue life for a given separation between them; this implies that the separation between the two artificial pitting holes and the associated stress concentration is the principal parameter on the fatigue life under these conditions. Finally, results are discussed and conclusions are presented involving the fatigue life, proximity, and dimension of pitting holes, stress concentration factor, and fracture surfaces where the failure origin is identified.     

Synthesis of α‐cellulose/polypyrrole composite for the removal of reactive red dye from aqueous solution: Kinetics and equilibrium modeling

In this work, a composite from α‐cellulose coated with conducting polypyrrole by in situ polymerization using potassium persulfate as oxidant was obtained. The composite was characterized by fourier transform infrared (FTIR) spectroscopy, cyclic voltammetry, UV/Vis spectroscopy, and scanning electron microscopy (SEM) analysis showed homogeneous coating of α‐cellulose with polypyrrole (PPy) to produce a composite with a conductivity of 3.5 × 10⁻⁵ S/m. Batch aqueous adsorption experiments of the reactive red 120 (RR120) dye onto the synthesized material were conducted. The results showed that this composite is an efficient adsorbent for RR120 dye removal. For the adsorption experiments set to an initial pH of 3.9, the adsorption capacity was 15.6 mg of dye/g of composite for an equilibrium concentration (in the liquid) of RR120 dye equal to 1,000 mg/L, whereas a value of 96.1 mg of dye/g of composite was obtained when the solution pH was set to 2.0 for the same equilibrium concentration. When performing adsorption experiments using pure α‐cellulose, dye adsorption was insignificant at any pH value. Adsorption isotherm for RR120 was described by a typical Freundlich model. The transient adsorption of RR120 on the synthesized composite was described by a general three‐resistance model that includes the transport on the film that surrounds the composite particles, diffusion inside the particles, and adsorption on the surface of the particles. A fitting of the uptake curves was performed allowing the estimation of values for the effective diffusivity, D₀, and the adsorption rate coefficient, k₁. For the adsorption experiments with an initial pH value set to 3.9, D₀ was estimated as 1.05 × 10⁻¹⁰ m²/s, whereas k₁ was 1.65 × 10⁻⁴ Lⁿ/g mg^{n − 1} s; the corresponding values of k₁ at pH = 2 and 9.0 were 3.18 × 10⁻⁴ and 5.16 × 10⁻⁵, respectively. POLYM. COMPOS., 36:312–321, 2015. © 2014 Society of Plastics Engineers     

Changes in coping style and treatment outcome following motor vehicle accident.

Background: Motor vehicle accidents (MVAs) are highly prevalent and can result in a complex interplay of physical injury, disability, and emotional distress. It has been suggested that the manner in which individuals cope with pain experienced after injury may determine how much recovery of function can be achieved. Only a limited number of studies have examined this process in the context of a rehabilitation program, and to date few studies have examined both functional and quality of life outcomes in MVA recovery in a tertiary level program as a function of coping style. Methods: A sample of 96 consecutive referrals to a tertiary-level multidisciplinary functional restoration program completed physical performance measures pre- and post-treatment, as well as a standardized self-report measure of quality of life (QOL) at the same time points and 6-month follow-up. Results: Findings suggested that improvements from pre- to post-treatment were evident on the 6-minute walk test, left and right grip strength, and most QOL measures. Increases in active coping during treatment were associated with pre- to post-treatment increases in QOL across most domains, and improvements in performance on the 6-minute walk test. Likewise, decreases in passive coping during the course of treatment were associated with improved performance on the 6-minute walk test, right-handed standing reach test, and most QOL indicators. Conclusion: Findings suggest that those who adopt an active approach (and avoid taking a passive approach) to rehabilitation following complex musculoskeletal injury benefit along both QOL and functional dimensions relative to those who do not. (PsycINFO Database Record (c) 2011 APA, all rights reserved)     

A connectionist model of septohippocampal dynamics during conditioning: Closing the loop.

Septohippocampal interactions determine how stimuli are encoded during conditioning. This study extends a previous neurocomputational model of corticohippocampal processing to incorporate hippocamposeptal feedback and examines how the presence or absence of such feedback affects learning in the model. The effects of septal modulation in conditioning were simulated by dynamically adjusting the hippocampal learning rate on the basis of how well the hippocampal system encoded stimuli. The model successfully accounts for changes in behavior and septohippocampal activity observed in studies of the acquisition, retention, and generalization of conditioned responses and accounts for the effects of septal disruption on conditioning. The model provides a computational, neurally based synthesis of prior learning theories that predicts changes in medial septal activity based on the novelty of stimulus events. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Recent advances in cancer therapy

The treatment of cancer has developed substantially from its conception in the first years of the 20th century. Since the introduction of alkylating agents during second World War, the oncology specialty has markedly grown. In the recent years, new drugs have been approved for the treatment of cancer. Such examples include the taxanes (Docetaxel and Paclitaxel), Vinorelbine, Irinotecan, Topotecan, Gemcitabine and Gliadel. We will discuss these new chemotherapuetic agents, their pharmacology, indications, toxicity and appropriate dosing. There is no doubt that further clinical research is needed to determine the optimal use of these agents.     

Parameter Uncertainty and Policy Intensity: Some Extensions and Suggestions for Further Work

The effects of parameter uncertainty on optimal policy have been a matter of interest for academics, and even for some policymakers, for a long time. Two lines of literature have developed analytical results on this matter. The first line uses static models and the second dynamic models. In this dynamic line most of the results are confined to models with a single state and a single control variable. In this paper we want to encourage the analysis of more general dynamic cases. To do so, the results in the dynamic line are extended from one-state and one-control finite horizon models to models with a pair of control variables. We then discuss some of the hurdles which must be surmounted for the results to be made more general and suggests some lines for further research. JEL classification: C61; E61     

The Timing of Uncertainty and the Intensity of Policy

This article analyzes the trade-off between `caution' and `intensity' in the use of the control variable in a one-state one-control dynamic stochastic quadratic linear optimization problem with discount factor. It studies the effects that changes in uncertainty of the control parameter have on the optimal first period response of the control variable, showing that the trade-off between `caution' and `intensity' depends on the timing of the uncertainty. Given an increase in current uncertainty and an equal increase in future uncertainty, caution will always prevail over intensity. Moreover, the prevalence of caution will be enlarged as the increase in future uncertainty moves farther away into the future, while this prevalence will be reduced as the increase in future uncertainty expands into the future. Finally, for the infinite horizon case, caution is the optimal policy response.     

Computational Economics: Help for the Underestimated Undergraduate

Our concern in this paper is that the capability of economics undergraduates is substantially underestimated in the design of the present college curriculum and that our students are insufficiently challenged and motivated. Students enter our classrooms with substantial previous knowledge about computers and computation and we are not taking full advantage of this opportunity. We suggest a set of examples from computational economics which are challenging enough to motivate students and simple enough that they can master them within a few hours. By encouraging the students to modify the models in directions of their own interest, avenues for creative endeavor are opened which deeply involve the students in their own education.     

Methane Transformation using Light Gasoline as Co-Reactant over Zn/H-ZSM11

The catalytic conversion of methane (C1) to aromatic hydrocarbons (AH) such as benzene, toluene and xylenes (BTX) over a Zn/H-ZSM-11 catalyst using Light Gasoline (C5+C6) as co-reactant was studied. AH yields were as high as 30 %mol at 500 °C, w/f = 40 g h mol⁻¹ at C1 molar fraction = 0.20. The contact time and time-on-stream effects on the product distribution, were analyzed in detail in order to obtain information about the evolution of different species. The C1 conversion reached 36 mol% C using Zn/HZSM-11 with content of 2.13 mol of Zn²⁺ per cell unit.