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1.
A strategy for creating potent and pan-genotypic stimulator of interferon genes (STING) agonists is described. Locking a bioactive U-shaped conformation of cyclic dinucleotides by introducing a transannular macrocyclic bridge between the nucleic acid bases leads to a topologically novel macrocycle-bridged STING agonist (MBSA). In addition to substantially enhanced potency, the newly designed MBSAs, exemplified by clinical candidate E7766 , exhibit broad pan-genotypic activity in all major human STING variants. E7766 is shown to have potent antitumor activity with long lasting immune memory response in a mouse liver metastatic tumor model. Two complementary stereoselective synthetic routes to E7766 are also described.  相似文献   
2.
This paper considers the issue of recycling of waste printed circuit boards (WPCBs) containing precious and base metals in appreciable amounts. High-pressure oxidative leaching (HPOL) with dilute sulfuric acid resulted in removal of a significant amount of base metals from a WPCB ash sample obtained by incineration at 800°C. The parameters investigated in the precious metal leaching from WPCB residue after HPOL included the sulfuric acid concentration, thiourea concentration, oxidant concentration, leaching temperature, and leaching time. Recovery of gold, silver, and palladium of 100%, 81%, and 13% from the WPCB residue sample was achieved by thiourea leaching under optimized conditions. The results show that the efficiency of precious metal dissolution from the WPCB sample using thiourea solution depended strongly on the concentration of both thiourea and oxidant.  相似文献   
3.
Among a variety of solar cell types, thin-film solar cells have been rigorously investigated as cost-effective and efficient solar cells. In many cases, flexible solar cells are also fabricated as thin films and undergo frequent stress due to the rolling and bending modes of applications. These frequent motions result in crack initiation and propagation (including delamination) in the thin-film solar cells, which cause degradation in efficiency. Reliability evaluation of solar cells is essential for developing a new type of solar cell. In this paper, we investigated the effect of layer delamination and grain boundary crack on 3D thin-film solar cells. We used finite element method simulation for modeling of both electrical performance and cracked structure of 3D solar cells. Through simulations, we quantitatively calculated the effect of delamination length on 3D copper indium gallium diselenide (CIGS) solar cell performance. Moreover, it was confirmed that the grain boundary of CIGS could improve the solar cell performance and that grain boundary cracks could decrease cell performance by altering the open circuit voltage. In this paper, the investigated material is a CIGS solar cell, but our method can be applied to general polycrystalline solar cells.  相似文献   
4.
Graphene-reinforced aluminum (Gr-Al) matrix nanocomposites (NCs) have attracted strong interest from both research and industry in high-performance weight-sensitive applications. Due to the vastly different bonding characteristics of the Al matrix (metallic) and graphene (in-plane covalent?+?inter-plane van der Waals), the graphene phase has a general tendency to agglomerate and phase separate in the metal matrix, which is detrimental for the mechanical and chemical properties of the composite. Thus, synthesis of Gr-Al NCs is extremely challenging. This review summarizes the different methods available to synthesize Gr-Al NCs and the resulting properties achieved in these NCs. Understanding the effect of processing parameters on the realized properties opens up the possibility of tailoring the synthesis methods to achieve the desired properties for a given application.  相似文献   
5.
6.
Benchmarking is a tool available to furnace operators to evaluate their tap-hole life-cycle management practices against those of their peers. It allows furnace operators to challenge their own practices in order to increase furnace utilization. To facilitate the benchmarking process, it is necessary to define the variables to be considered and how they relate to one another. This article develops, from the literature and industry interviews, a holistic conceptualization of the variables that form part of tap-hole lifecycle management and performance. Specifically, the article focuses on the variables related to coke-bed-based processes (FeCr, SiMn, and HCFeMn) applying SAF technology of circular design.  相似文献   
7.
The microstructures and mechanical properties of 66(NixAl)-28Cr-6Mo (x?=?1.0, 1.5, 2.0, 2.5, 3.0, and 3.5) alloys were investigated using scanning electron microscopy, energy dispersive spectroscopy, transmission electron microscope, microhardness, and compression tests. The microstructure of NiAl-28Cr-6Mo (Ni1.0) eutectic alloy consists of NiAl and Cr(Mo) phases. With increasing the Ni content to 2.0, the microstructure changes from eutectic (Ni1.0) to eutectic?+?primary NiAl dendrite (Ni1.5 and Ni2.0), and the morphologies of part of precipitates in primary NiAl dendrite evolve from granular to needle-like. When the Ni content increases further, besides eutectic and primary NiAl dendrite, the gray phase forms and is identified as an ordered FCC (L12) (Ni,Cr)3(Al,Mo) phase. Moreover, the more needle-like precipitates emerge in the primary NiAl dendrite of Ni2.5, Ni3.0, and Ni3.5 alloys, and the precipitate is identified as a bcc Cr(Mo) phase. The deep etching reveals that the three-dimensional morphology of Cr(Mo) precipitate is not needle-like but lath-like. Among the investigated alloys, both Ni2.0 and Ni2.5 alloys possess the higher fracture strength and microhardness. The relevant strengthening mechanisms are discussed.  相似文献   
8.
Antimony and bismuth recovery from copper electrorefining electrolyte could reduce the impacts of these problem elements and produce a new primary source for them. Two proprietary phosphonic acid ester extractants were examined (REX-1 and REX-2) for the removal of antimony and bismuth from copper electrorefining electrolytes. Experimentation included shakeout and break tests to determine the basic parameters for the extractants in terms of maximum loading, break times, and extraction and stripping efficiency. Five permutations of extractant mixtures (100 wt.% REX-1 and 25 wt.%, 50 wt.%, 75 wt.% and 100 wt.% REX-2) were studied. It was determined that REX-2 was able to extract Sb and Bi from the electrolyte, but required some mixture with REX-1 to better facilitate stripping with 400 g/L sulfuric acid. The laboratory electrorefining electrolyte containing glue had faster disengagement times than a synthetic solution without glue.  相似文献   
9.
This research proposes a simple yet highly sensitive method based on electrical resonance of an eddy-current probe to detect delamination of thermal barrier coating (TBC). This method can directly measure the mechanical characteristics of TBC compared to conventional ultrasonic testing and infrared thermography methods. The electrical resonance-based method can detect the delamination of TBC from the metallic bond coat by shifting the electrical impedance of eddy current testing (ECT) probe coupling with degraded TBC, and, due to this shift, the resonant frequencies near the peak impedance of ECT probe revealed high sensitivity to the delamination. In order to verify the performance of the proposed method, a simple experiment is performed with degraded TBC specimens by thermal cyclic exposure. Consequently, the delamination with growth of thermally grown oxide in a TBC system is experimentally identified. Additionally, the results are in good agreement with the results obtained from ultrasonic C-scanning.  相似文献   
10.
In this study, YSZ coatings were deposited on different substrate materials (stainless steel and aluminum) using suspension plasma spray technique. The effects of substrate properties (material, surface topology, temperature, and thickness) on the formation of coatings were investigated. The results showed that, with the identical spray parameters, the porosity is higher for the coatings deposited on aluminum than that on stainless steel due to the high thermal transfer ability of the former substrate material. The SEM results revealed that the microstructure of as-prepared coatings could be tailored from the vertical cracked structure to the columnar structure by increasing the substrate surface roughness and their formation mechanisms were discussed. The substrate preheating temperature has an influence on the microstructure of the coatings, especially in the interfacial region. Increasing the substrate temperature is an effective means for reducing the interface defects and for improving the adhesion of the coatings. With the increase in the substrate thickness, the quantity of the vertical cracks in the coatings is reduced and their width becomes narrower.  相似文献   
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