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排序方式: 共有7159条查询结果,搜索用时 15 毫秒
1.
Matrix Manipulation of Directly-Synthesized PbS Quantum Dot Inks Enabled by Coordination Engineering
Fei Li Yang Liu Guozheng Shi Wei Chen Renjun Guo Dong Liu Yaohong Zhang Yongjie Wang Xing Meng Xuliang Zhang You Lv Wei Deng Qing Zhang Yao Shi Yifan Chen Kai Wang Qing Shen Zeke Liu Peter Müller-Buschbaum Wanli Ma 《Advanced functional materials》2021,31(45):2104457
The direct-synthesis of conductive PbS quantum dot (QD) ink is facile, scalable, and low-cost, boosting the future commercialization of optoelectronics based on colloidal QDs. However, manipulating the QD matrix structures still is a challenge, which limits the corresponding QD solar cell performance. Here, for the first time a coordination-engineering strategy to finely adjust the matrix thickness around the QDs is presented, in which halogen salts are introduced into the reaction to convert the excessive insulating lead iodide into soluble iodoplumbate species. As a result, the obtained QD film exhibits shrunk insulating shells, leading to higher charge carrier transport and superior surface passivation compared to the control devices. A significantly improved power-conversion efficiency from 10.52% to 12.12% can be achieved after the matrix engineering. Therefore, the work shows high significance in promoting the practical application of directly synthesized PbS QD inks in large-area low-cost optoelectronic devices. 相似文献
2.
Miao Zhang Yi Zuo Tonghui Li Min Liu Hong Yang Xinwen Guo 《American Institute of Chemical Engineers》2021,67(8):e17261
A thorough experimental investigation on the kinetic behavior of liquid-phase propylene epoxidation over TS-1 and tetrapropylammonium hydroxide (TPAOH) treated TS-1 catalysts was conducted in a fixed-bed reactor. The amounts of different coordinated Ti species in the catalysts were quantified by spectroscopies, and their catalytic performances of the epoxidation and alcoholysis of propylene oxide were measured by kinetic modeling. The study shows that the TPAOH treatment converted some of the tetrahedrally coordinated Ti to octahedrally coordinated Ti, and both species were active for the epoxidation and alcoholysis. The superior catalytic performance observed over the TPAOH treated TS-1 is due to two factors, the increased percentage of active sites, and reduced energy barrier for epoxidation on the octahedrally coordinated Ti. In addition, as the H2O2 conversion increases, the adsorption equilibrium constant of propylene oxide plays a more decisive role than the activation energy for the selectivity of propylene glycol monomethyl ethers. 相似文献
3.
Ningyu Chen Jintang Zhou Zhengjun Yao Yiming Lei Ruiyang Tan Yuxin Zuo Wenjian Zheng Zibao Jiao 《Ceramics International》2021,47(8):10545-10554
The electromagnetic materials are featured by good magnetic permeability and dielectric constant characteristics, which are of significant importance in solving the pollution problem of electromagnetic. In this study, after the complete of the use of sol-gel method, argon gas was then introduced for calcination, and eventually a new type of MWCNTs/Ni0.5Zn0.5Nd0.04Fe1.96O4 composites was synthesized after the above mentioned procedures. The synthesized MWCNTs were able to be adsorbed on the surface of Ni0.5Zn0.5Nd0.04Fe1.96O4 and could form a good conductive work of 3D. Also, the effect of additional MWCNTs on microwave absorption properties of MWCNTs/Ni0.5Zn0.5Nd0.04Fe1.96O4 composites were also observed in this study. The results indicate that the additional MWCNTs function to significantly improve the microwave absorption property of MWCNTs/Ni0.5Zn0.5Nd0.04Fe1.96O4. Through altering the amount of MWCNTs, the microwave attenuation performance and impedance matching coefficient of this electromagnetic materials can be effectively improved. The S2 sample presented a minimum reflection loss of ?35.05 dB when its thickness reached 1.6 mm, meanwhile, the effective absorption bandwidth achieved 4.55 GHz. The prepared composites perform well in microwave absorption, which can attribute to the reasonable ratio of composites as well as its interaction with both of the magnetic and dielectric components. This research paved the way for novel ideas to be put in the electromagnetic absorption materials with high-efficient. 相似文献
4.
中心锥对液态燃料旋转爆轰发动机工作过程与性能的影响 总被引:2,自引:0,他引:2
为分析中心锥对液态燃料旋转爆轰发动机(RDE)工作特性的影响,在环形阵列式RDE上,以汽油/富氧空气为工质,开展了液态燃料RDE实验研究。测量发动机在不同中心锥位置l/L(l为燃烧室内壁面等直段末端与燃烧室外壁面末端的距离,L为燃烧室外壁面长度)和中心锥锥角θ时的一维推力,分析了推力和燃料比冲的变化趋势。实验结果表明:改变l/L和θ未对旋转爆轰波传播模态产生影响,各工况下旋转爆轰波均为双波对撞模态;受预爆轰管切向喷注孔的影响,双波对撞点无法稳定于预爆轰管出口附近;爆轰波传播速度和频率随中心锥位置的前移呈下降趋势,当l/L=0%、θ=20°时,推力和燃料比冲分别为951.6 N和1 151.8 s, 为所有实验工况中最大值;随着l/L或θ增大,爆轰产物轴向膨胀距离变短,中心锥头部突扩位置处膨胀波影响增强,外流场中心锥型面约束作用减弱且高温燃气径向膨胀增强,发动机出口高温燃气轴向分速度逐渐减小,发动机推力和燃料比冲逐渐减小;当l/L>25.5%或θ>40°时,受熄爆再起爆和膨胀波增强影响,发动机推力和燃料比冲下降速率增大。 相似文献
5.
针对目前资源型城市脆弱性研究角度和研究对象单一导致研究成果缺乏对比性的问题,以淮南、铜陵和马鞍山市为例,从"资源-生态环境-经济-社会"角度,构建矿产资源型城市综合脆弱性评价指标体系,采用熵值法和综合指数评价法对其各子系统和综合脆弱性动态演变特征进行研究.结果表明:(1)2007-2017年淮南市、铜陵市和马鞍山市综合脆弱性及各子系统脆弱性均呈下降趋势,其脆弱性等级均由较强脆弱度向较低脆弱度过渡;(2)2007~2017年淮南市、铜陵市和马鞍山市各子系统脆弱性中社会脆弱性均最大,其次均为经济脆弱性和生态环境脆弱性,资源脆弱性均最小;(3)从综合脆弱性下降幅度来看,马鞍山市综合脆弱性指数下降幅度最大,淮南市次之,铜陵市最小;从各子系统脆弱性下降幅度来看,三个城市社会脆弱性下降幅度均最大,经济脆弱性下降幅度均最小.该研究为丰富资源型城市脆弱性理论、资源型城市绿色转型和可持续发展提供科学依据. 相似文献
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8.
针对目前注水井测调工作量大以及周期长的问题,提出基于管柱压力波的注水井无线通信方法。开展了基于管柱压力波双向通信的分层注水控制方法研究,探索了压力波控制信号生成和响应的特征,建立了压力波的编码和解码方法,进行了冀东油田模拟井试验。研究结果表明:该方法中压力波进行数据传输过程不需要停止注水,通过操作井口和井下的调节阀即可实现压力波编码;定义了数据帧格式,并且可以根据实际情况扩展数据帧;该方法具有信号无线传输,井下工具简单,测调工作量小,实时测调和测试数据多等优势;模拟试验实现了井口与井下配水器的通信,达到了最优控制。建立的压力波编码和解码方法可以为注水油田智能化管理发展提供基础理论依据。 相似文献
9.
240×10^4 t/a柴油精制装置在连续2次开工过程中,均出现反应器压降快速升高并致装置停工。分别从原料、垢物、催化剂等方面排查分析,确定造成压降快速升高的主要原因为:系统内存在硫化亚铁腐蚀物,开工引油后带入反应器,造成催化剂板结、堵塞;DCC轻油的多环芳烃含量较高,易引起缩合生焦副反应,在系统内沉积,垢物和缩合物形成黏糊状结垢物,随原料油进入反应器,积聚在催化剂床层,造成压降升高。通过对进料换热器、加热炉等系统爆破吹扫、冷油冲洗、更换新鲜催化剂及新型进料分配盘等措施,装置开工运行正常。 相似文献
10.
Zhongpei Du Dongxu Yao Yongfeng Xia Kaihui Zuo Jinwei Yin Hanqin Liang Yu-Ping Zeng 《International Journal of Applied Ceramic Technology》2021,18(3):830-837
The highly porous Si3N4 ceramic foams were prepared by direct foaming with mixed surfactants. The surface tension and viscosity of slurries were tailored by different carbon chain length of surfactants and different mean Si3N4 particle size to achieve the pore size controlling. The nearly linear relationship between the pore size and the ratio of surface tension to viscosity was observed, which indicates that the pore size could be precisely tailored by the slurry properties. Si3N4 ceramic foams with porosity of nearly 94%, mean pore size of 110–230 µm, and compressive strength of 1.24–3.51 MPa were obtained. 相似文献