Direct writing of textured ceramics using anisotropic nozzles

Direct writing is a unique means to align anisotropic particles for the fabrication of textured ceramics by templated grain growth (TGG). We show that alignment of tabular barium titanate (BT) template particles (20–40 μm width and 0.5–2 μm thickness) in a PIN-PMN-PT matrix powder (d₅₀ = 280 nm) is significantly improved during direct writing using anisotropic nozzles at high printing rates. The particle orientation distribution in as-printed filaments, and the texture orientation distribution in sintered ceramic filaments are shown to directly correlate with COMSOL Multiphysics-predicted torque distributions for direct writing with aspect ratio 2, 3 and 5 oval nozzles. Electromechanical strain properties of the textured piezoelectric ceramics significantly improved relative to random ceramics when printed with anisotropic nozzles. Simulations of aspect ratio 20 nozzles and nozzles with interior baffles demonstrate significantly increased torque and near elimination of constant shear stress cores (i.e. plug flow).     

TRU-NET: a deep learning approach to high resolution prediction of rainfall

Machine Learning - Climate models (CM) are used to evaluate the impact of climate change on the risk of floods and heavy precipitation events. However, these numerical simulators produce outputs...     

Glycosylation in Indolent,Significant and Aggressive Prostate Cancer by Automated High-Throughput N-Glycan Profiling

The diagnosis and treatment of prostate cancer (PCa) is a major health-care concern worldwide. This cancer can manifest itself in many distinct forms and the transition from clinically indolent PCa to the more invasive aggressive form remains poorly understood. It is now universally accepted that glycan expression patterns change with the cellular modifications that accompany the onset of tumorigenesis. The aim of this study was to investigate if differential glycosylation patterns could distinguish between indolent, significant, and aggressive PCa. Whole serum N-glycan profiling was carried out on 117 prostate cancer patients’ serum using our automated, high-throughput analysis platform for glycan-profiling which utilizes ultra-performance liquid chromatography (UPLC) to obtain high resolution separation of N-linked glycans released from the serum glycoproteins. We observed increases in hybrid, oligomannose, and biantennary digalactosylated monosialylated glycans (M5A1G1S1, M8, and A2G2S1), bisecting glycans (A2B, A2(6)BG1) and monoantennary glycans (A1), and decreases in triantennary trigalactosylated trisialylated glycans with and without core fucose (A3G3S3 and FA3G3S3) with PCa progression from indolent through significant and aggressive disease. These changes give us an insight into the disease pathogenesis and identify potential biomarkers for monitoring the PCa progression, however these need further confirmation studies.     

Evaluating demand response opportunities for power systems resilience using MILP and MINLP Formulations

While peak shaving is commonly used to reduce power costs, chemical process facilities that can reduce power consumption on demand during emergencies (e.g., extreme weather events) bring additional value through improved resilience. For process facilities to effectively negotiate demand response (DR) contracts and make investment decisions regarding flexibility, they need to quantify their additional value to the grid. We present a grid-centric mixed-integer stochastic programming framework to determine the value of DR for improving grid resilience in place of capital investments that can be cost prohibitive for system operators. We formulate problems using both a linear approximation and a nonlinear alternating current power flow model. Our numerical results with both models demonstrate that DR can be used to reduce the capital investment necessary for resilience, increasing the value that chemical process facilities bring through DR. However, the linearized model often underestimates the amount of DR needed in our case studies. Published 2018. This article is a U.S. Government work and is in the public domain in the USA. AIChE J, 65: e16508, 2019     

Autonomous industrial assembly using force,torque, and RGB-D sensing

ABSTRACT

We present algorithms and results for a robotic manipulation system that was designed to be easily programable and adaptable to various tasks common to industrial setting, which is inspired by the Industrial Assembly Challenge at the 2018 World Robotics Summit in Tokyo. This challenge included assembly of standard, commercially available industrial parts into 2D and 3D assemblies. We demonstrate three tasks that can be classified into ‘peg-in-hole’ and ‘hole-on-peg’ tasks and identify two canonical algorithms: spiral-based search and tilting insertion. Both algorithms use hand-coded thresholds in the force and torque domains to detect critical points in the assembly. After briefly summarizing the state of the art in research, we describe the strategy and approach utilized by the tested system, how it's design bears on its performance, statistics on 20 experimental trials for each task, lessons learned during the development of the system, and open research challenges that still remain.     

Processing and electromechanical properties of high-coercive field ZnO-doped PIN-PZN-PT ceramics

This study explores sintering and piezoelectricity of ZnO-doped perovskite Pb(In_1/2Nb_1/2)O₃-Pb(Zn_1/3Nb_2/3)O₃-PbTiO₃ (PIN-PZN-PT) ceramics. The enhanced densification of ZnO-doped PIN-PZN-PT is attributed to the formation of oxygen vacancies by the incorporation of Zn²⁺ into the perovskite B-site and increased rate of bulk diffusion relative to undoped PIN-PZN-PT. Incorporation of Zn²⁺ into the perovskite lattice increased the tetragonal character of PIN-PZN-PT as demonstrated by tetragonal peak splitting and increased Curie temperature. Sintering in flowing oxygen reduced the solubility of Zn²⁺ in the perovskite lattice and resulted in rhombohedral PIN-PZN-PT. Sintering in oxygen prevented secondary phase formation which resulted in a high-piezoelectric coefficient (d₃₃ – 550 pC/N), high-coercive field (E_c – 13 kV/cm), and high-rhombohedral to tetragonal phase transition temperature (T_r-t – 165°C). We conclude that ZnO-doped PIN-PZN-PT ceramics are excellent candidates for high-power transducer applications.     

Estimating underground mine ventilation friction factors from low density 3D data acquired by a moving LiDAR

Ventilation system analysis for underground mines has remained mostly unchanged since the Atkinson method was made popular by Mc Elroy in 1935. Data available to ventilation technicians and engineers is typically limited to the quantity of air moving through any given heading. Because computer-aided modelling, simulation, and ventilation system design tools have improved, it is now important to ensure that developed models have the most accurate information possible. This paper presents a new technique for estimating underground drift friction factors that works by processing 3 D point cloud data obtained by using a mobile Li DAR. Presented are field results that compare the proposed approach with previously published algorithms, as well as with manually acquired measurements.     

Syntheses and Structures of Octamethylmetallocenes of Osmium

The reaction of sodium hexachloroosmate(IV) hydrate with five equivalents of tetramethylcyclopentadiene (C₅Me₄H₂) in refluxing ethanol yielded the novel coordination compound bis(tetramethylcyclopentadienyl)chloroosmocinium(IV) hexachloroosmate, [(η ⁵-C₅Me₄H)₂OsCl]₂[OsCl₆] (1). Compound 1 has been characterized by NMR spectroscopy, elemental analysis and single-crystal X-ray diffraction. The cationic complex of 1 [(η ⁵-C₅Me₄H)₂OsCl]⁺, adopts a bent geometry with a ring centroid-osmium-ring centroid angle of 146.2° and an eclipsed conformation of its two tetramethylcyclopentadienyl rings. The addition of zinc powder to sodium hexachloroosmate(IV) hydrate and five equivalents of tetramethylcyclopentadiene in refluxing ethanol produced the known compound, bis(tetramethylcyclopentadienyl)osmium, (η ⁵-C₅Me₄H)₂Os (2). The crystal structure of 2 has been determined and it reveals an eclipsed arrangement of the tetramethylcyclopentadienyl rings in the solid state. The average Os–C_ring bond length in octamethylosmocene 2 (2.187 Å) is in accordance with corresponding bond lengths in osmocene, (η ⁵-C₅H₅)₂Os (2.19 Å) and decamethylosmocene, (η ⁵-C₅Me₅)₂Os (2.18 Å).     

Book reviews

Selling the Welfare State: The Privatisation of Public Housing. Ray Forrest and Alan Murie. London: Routledge, 1988. 279pp. £35.00.

Affordable Housing and the Homeless. Jurgen Friedrichs (ed). Walter de Gruyter: Berlin and New York.

The Homeless in Contemporary Society. Richard D. Bingham, Roy E. Green and Sammis B. White. £29.95 cloth, £12.95 paper.     

Chemically-speciated on-road PM2.5 motor vehicle emission factors in Hong Kong

PM_2.5 (particle with an aerodynamic diameter less than 2.5 µm) was measured in different microenvironments of Hong Kong (including one urban tunnel, one Hong Kong/Mainland boundary roadside site, two urban roadside sites, and one urban ambient site) in 2003. The concentrations of organic carbon (OC), elemental carbon (EC), water-soluble ions, and up to 40 elements (Na to U) were determined. The average PM_2.5 mass concentrations were 229 ± 90, 129 ± 95, 69 ± 12, 49 ± 18 µg m^− 3 in the urban tunnel, cross boundary roadside, urban roadside, and urban ambient environments, respectively. Carbonaceous particles (sum of organic material [OM] and EC) were the dominant constituents, on average, accounting for ∼ 82% of PM_2.5 emissions in the tunnel, ∼ 70% at the three roadside sites, and ∼ 48% at the ambient site, respectively. The OC/EC ratios were 0.6 ± 0.2 and 0.8 ± 0.1 at the tunnel and roadside sites, respectively, suggesting carbonaceous aerosols were mainly from vehicle exhausts. Higher OC/EC ratio (1.9 ± 0.7) occurred at the ambient site, indicating contributions from secondary organic aerosols. The PM_2.5 emission factor for on-road diesel-fueled vehicles in the urban area of Hong Kong was 257 ± 31 mg veh^− 1 km^− 1, with a composition of ∼ 51% EC, ∼ 26% OC, and ∼ 9% SO₄⁼. The other inorganic ions and elements made up ∼ 11% of the total PM_2.5 emissions. OC composed the largest fraction (∼ 51%) in gasoline and liquid petroleum gas (LPG) emissions, followed by EC (∼ 19%). Diesel engines showed higher emission rates than did gasoline and LPG engines for most pollutants, except for V, Br, Sb, and Ba.