Colossal dielectric response and relaxation behavior in novel system of Zr4+ and Nb5+ co-substituted CaCu3Ti4O12 ceramics

In this work, we developed a novel system of isovalent Zr⁴⁺ and donor Nb⁵⁺ co-doped CaCu₃Ti₄O₁₂ (CCTO) ceramics to enhance dielectric response. The influences of Zr⁴⁺ and Nb⁵⁺ co-substituting on the colossal dielectric response and relaxation behavior of the CCTO ceramics fabricated by a conventional solid-phase synthesis method were investigated methodically. Co-doping of Zr⁴⁺ and Nb⁵⁺ ions leads to a significant reduction in grain size for the CCTO ceramics sintered at 1060 °C for 10 h. XRD and Raman results of the CaCu₃Ti_3.8-xZr_xNb_0.2O₁₂ (CCTZNO) ceramics show a cubic perovskite structure with space group Im-3. The first principle calculation result exhibits a better thermodynamic stability of the CCTO structure co-doped with Zr⁴⁺ and Nb⁵⁺ ions than that of single-doped with Zr⁴⁺ or Nb⁵⁺ ion. Interestingly, the CCTZNO ceramics exhibit greatly improved dielectric constant (~10⁵) at a frequency range of 10²–10⁵ Hz and at a temperature range of 20–210 °C, indicating a giant dielectric response within broader frequency and temperature ranges. The dielectric properties of CCTZNO ceramics were analyzed from the viewpoints of defect-dipole effect and internal barrier layer capacitance (IBLC) model. Accordingly, the immensely enhanced dielectric response is primarily ascribed to the complex defect dipoles associated with oxygen vacancies by co-doping Zr⁴⁺ and Nb⁵⁺ ions into CCTO structure. In addition, the obvious dielectric relaxation behavior has been found in CCTZNO ceramics, and the relaxation process in middle frequency regions is attributed to the grain boundary response confirmed by complex impedance spectroscopy and electric modulus.     

Enhanced electromagnetic microwave absorption of Fe/C/SiCN composite ceramics targeting in integrated structure and function

The Fe/C/SiCN composite ceramics were synthesized by polymer-derived method to obtain the integration of structure and functions. The electromagnetic waves (EMW) absorption properties at X and Ku bands were investigated. The addition of nano-sized Fe particles improved the magnetic loss and impedance matching, and the carbon nanotubes generated by the iron in-situ catalysis increased the internal relaxation polarization and interfacial polarization, which together improved the EMW absorption properties significantly. In particular, the Fe/C/SiCN-9 showed the optimum reflection loss (RL) of ?31.06 dB at 10.03 GHz with an effective absorption bandwidth (EAB, RL < ?10 dB) of 3.03 GHz at 2.51 mm, indicating the excellent EMW absorption properties of Fe/C/SiCN composite ceramics.     

The microstructure and magnetic properties of Ca2+ ion doped GdCrO3

In this paper, the crystal structure, vacancy defect, local electron density and magnetic properties of Gd_1-xCa_xCrO₃ (0 ≤ x ≤ 0.3) polycrystalline samples were investigated systematically. The crystal structural analyses show that all the samples are orthorhombic phase and a structural distortion happens around x = 0.3. Due to the formation of Cr⁴⁺ ions, both the lattice constant and the Cr–O bond length decrease. The results of positron annihilation spectrum reveals that the vacancy defect concentration increases and the local electron structure changes with the introduction of Ca²⁺ ions. The field-cooled (FC) and zero-field cooled (ZFC) curves of Gd_1-xCa_xCrO₃ samples measured under H = 100 Oe exhibits negative magnetization characteristics due to the interaction between Gd³⁺ and Cr³⁺ ions, and the magnetism can be affected by the structural distortion.     

Enhanced thermal conductivity and stability of boron nitride/phenyl silicone rubber composites via surface modification and grain alignment

Journal of Materials Science - With the extensive use of high-power electronic appliances, polymer-based thermal insulation composites with excellent thermal properties are utilized in the field of...     

Changes in the content and antioxidative activity of β-carotene and its metabolite vitamin A during gastrointestinal digestion and absorption and optimisation of HPLC-based detection

The β-Carotene (BC), an important precursor of vitamin A (VA), possesses antioxidant activity but is fat-soluble and has low bioavailability. In previous in-vitro assays evaluating antioxidant and 2,2′-azobis(2-amidinopropane) dihydrochloride (AAPH) free radical scavenging, both BC and VA showed a strong ability to scavenge radicals and protected cells from oxidative stress. Here, we used artificially simulated gastrointestinal digestion and Caco-2 cell absorption models to evaluate the bioavailability of the BC during gastrointestinal digestion and absorption using high-performance liquid chromatography (HPLC) analysis. We observed high absorptive and transfer rates of BC and detected retinol metabolites (Vitamin A). Therefore, BC can be detected in the acidic gastrointestinal environment using HPLC. Optimised method provided better separation of BC and VA in the column, improving the accuracy of the test results.     

In Situ Anchoring Ultra Small Au Nanoparticles by Conformal Coating of Carbon Layer within the Micro-Environments of Mesoporous Silica for Highly Efficient Catalytic Reduction of 4-nitrophenol

Catalysis Letters - For the noble-metal based catalysts, the metal dispersion and sinter resistance of the metal nanoparticles (NPs) are the most vital factors for their application in series...     

Non-keyhole Friction Stir Welding for 6061-T6 Aluminum Alloy

A novel non-keyhole friction stir welding technique was proposed to weld the butt joint of 6061-T6 aluminum alloy with the thickness of 6 mm. A sound joint was obtained by this technique, simultaneously eliminating the flash, shoulder mark and keyhole defects. The sleeve directly affected zone (SDAZ) and the sleeve indirectly affected zone (SIAZ) were divided into the joint according to the plunging position of the hollow sleeve. The lack of root penetration defect was avoided when the plunging depth of the hollow sleeve was only 4.2 mm, because the hollow part inside the sleeve improved the material flow below the sleeve. An S-shaped line was left at the SIAZ, and the height of it had the minimum value of 1.47 mm at 20 mm/min. Whether the failure location of the joint was in SIAZ/SDAZ or the heat-affected zone (HAZ) depended on the height and bonding strength of the S-shaped line. The joint fracture location changed from the SIAZ/SDAZ at 35 mm/min to the HAZ at 20 and 30 mm/min. The maximum tensile strength of 224.3 MPa was obtained at 30 mm/min which was 73.7% of that of the base material. The fracture surface morphology exhibited the typical ductile fracture.     

Preparation of broadband transparent Si3N4-SiO2 ceramics by digital light processing (DLP) 3D printing technology

Wave-transmitting materials are a kind of multi-functional materials that protect the normal operation of communication and guidance systems of spacecraft in harsh environments. In this paper, we fabricate a broadband microwave transparent Si₃N₄-SiO₂ composite ceramic with excellent performance through digital light processing (DLP) 3D printing technology. The influences of sintering temperature on the weight increase rate, density, dimensional shrinkage, phase composition, microstructure, bending strength and dielectric properties of Si₃N₄-SiO₂ ceramic were all systematically studied. The strength of Si₃N₄-SiO₂ ceramic sintered at 1350 ℃ was 77 ± 5 MPa. The relative permittivity of the ceramic is within the range of less than 4, and the loss tangent can be below 0.003. The 3D printed Si₃N₄-SiO₂ ceramic material exhibited excellent wave-transparent performance.