Structural Characterization of Different Asphaltenes of Kuwaiti Origin

Asphaltenes obtained by precipitation from crude Kuwaiti oils have been analyzed by proton magnetic resonance (¹H-NMR), carbon-13 nuclear magnetic resonance (¹³C-NMR) and Infrared (IR) spectral techniques. The molecular weight and elemental analysis were also determined. These combined analytical data were used for the characterization of these Kuwaiti oils. The asphaltenes molecular weights range from approximately 4200-6500 with an H/C ratio of 0.91-1.1 with an average 45-71% aromatic carbons. The average side chain length was of 4-6 carbons. It can also be concluded that the asphaltenes under investigation contain 5-9 sets of condensed aromatic rings joined together by bridges of alkyl chains or other hetero atoms and the average number of each of these sets of condensed aromatic rings is nearly 7. There are a number of alicyclic rings and condensed alicyclic rings in asphaltene. The IR spectra showed main molecular groups including OH, NH, SH, C=O and aliphatic and aromatic C-H's.     

The Impact of Metastable Intermolrecular Nanocomposite Particles on Kinetic Decomposition of Heterocyclic Nitramines Using Advanced Solid‐Phase Decomposition Models

Journal of Inorganic and Organometallic Polymers and Materials - Surface oxygen of oxide catalyst has low coordination number; they are negatively charged. Surface oxygen can act active site for...     

The MORPHEUS Heterogeneous Dynamically Reconfigurable Platform

Reconfigurable computing offers a wide range of low cost and efficient solutions for embedded systems. The proper choice of the reconfigurable device, the granularity of its processing elements and its memory architecture highly depend on the type of application and their data flow. Existing solutions either offer fine grain FPGAs, which rely on a hardware synthesis flow and offer the maximum degree of flexibility, or coarser grain solutions, which are usually more suitable for a particular type of data flow and applications. In this paper, we present the MORPHEUS architecture, a versatile reconfigurable heterogeneous System-on-Chip targeting streaming applications. The presented architecture exploits different reconfigurable technologies at several computation granularities that efficiently address the different applications needs. In order to efficiently exploit the presented architecture, we implemented a complete software solution to map C applications to the reconfigurable architecture. In this paper, we describe the complete toolset and provide concrete use cases of the architecture.     

Structural and Magnetic Studies of Rare-Earth Substituted Nickel Ferrites

Polycrystalline ferrites NiFe₂O₄ and NiFe_1.99R_0.01O₄ (R=Sm, Gd, Eu, and La) samples were prepared by usual ceramic method. The structural and the magnetic properties of the samples were characterized by X-ray powder diffraction (XRD), Mössbauer Effect (ME) spectroscopy, and vibrating sample magnetometer (VSM). Indexed XRD patterns confirm the formation of pure cubic spinel phase. The lattice parameters (a) of the rare earth (R) doped samples were smaller than that of the pure Ni-ferrite. Mössbauer effect spectroscopy was used to study the distribution of cations in tetrahedral (A) and octahedral [B] sites of the spinel. The hysteresis loops indicated that the saturation magnetization and coercivity increased with R-substitution and appeared to be greatly affected by the nature of R ions. The obtained results are interpreted based on the rearrangement of cations between the A-site and B-site.     

A new real-time retinal tracking system for image-guided laser treatment

A new system is proposed for tracking sensitive areas in the retina for computer-assisted laser treatment of choroidal neovascularization (CNV). The system consists of a fundus camera using red-free illumination mode interfaced to a computer that allows real-time capturing of video input. The first image acquired is used as the reference image and utilized by the treatment physician for treatment planning. A grid of seed contours over the whole image is initiated and allowed to deform by splitting and/or merging according to preset criteria until the whole vessel tree is demarcated. Then, the image is filtered using a one-dimensional Gaussian filter in two perpendicular directions to extract the core areas of such vessels. Faster segmentation can be obtained for subsequent images by automatic registration to compensate for eye movement and saccades. An efficient registration technique is developed whereby some landmarks are detected in the reference frame then tracked in the subsequent frames. Using the relation between these two sets of corresponding points, an optimal transformation can be obtained. The implementation details of proposed strategy are presented and the obtained results indicate that it is suitable for real-time location determination and tracking of treatment positions.     

Determination of trace isoflavone phytoestrogens in biological materials by capillary electrochromatography

Capillary electrochromatography using a specialty monolithic matrix was utilized in developing a rapid and highly efficient separation of isoflavones in biological materials. Without a preconcentration technique, it is relatively easy to reach ppm-ppb concentrations of these compounds in soy-based foods and verify them structurally using a photodiode array detector. With on-column preconcentration, we were able to measure low-ppb levels in human serum. Using blood samples from human volunteers, whose diet was supplemented by a soy-based product, the method has been validated for high-throughput screening of isoflavones in clinical studies.     

Microdeposition device interfacing capillary electrochromatography and microcolumn liquid chromatography with matrix-assisted laser desorption/ionization mass spectrometry

A sample deposition device has been constructed and optimized for interfacing CEC and capillary LC columns to MALDI mass spectrometry. For CEC analysis, the device is composed of an inlet buffer reservoir and an outlet buffer reservoir connected to a matrix reservoir through a connection sleeve. The matrix reservoir is connected to a deposition capillary via another connection sleeve. CEC eluent is transported to the matrix reservoir via a capillary that is connected to the deposition capillary by the connection sleeve inside the matrix reservoir. This connection sleeve also acts as a mixing chamber, allowing the CEC eluent to be mixed with matrix prior to deposition. Complex glycan mixtures can be separated by CEC using hydrophilic-phase monolithic columns, with capillary eluent being deposited on a standard MALDI plate along with a suitable matrix solution. Thousands of discrete, highly homogeneous dots can be generated for a subsequent mass spectrometric analysis. With minor modifications, this device is also applicable to capillary LC of peptides using gradient elution. In this configuration, the outlet of the LC column is connected to a deposition capillary inside a matrix reservoir through a connection sleeve that allows mixing of the LC effluent with an appropriate matrix. The device has been evaluated with the tryptic digests of proteins.     

Utilisation of mango seed kernel (Mangifera indica) as a source of oil

Fat extracted from mango seed kernel (Mangifera indica) was analysed for its chemical and physical constants, triglycerides, fatty acids and phospholipids; and these were compared with those of cotton seed oil, cocoa butter and two of its substitutes, namely, Croklaan Special 555 and Wesco Special E. The effects of incorporation of mango seed kernel oil in butterscotch toffee on its organoleptic properties were also studied. It was found that mango kernel oil and cocoa butter were almost identical in several of their constants, triglycerides, fatty acids and effects on taste, odour and texture of the toffee.     

Analytical wide-band modeling of high frequency resistance in integrated spiral inductors

For integrated spiral inductor synthesis, designers and design automation tools require efficient modeling techniques during the initial design space exploration process. In this paper, we introduce an analytical frequency-dependent resistance model for integrated spiral inductors. Based on our resistance formulation, we have developed a systematic technique for creating wide-band circuit models for accurate time domain simulation. The analytical resistance model provides a fast alternative to field solver-based approaches with typical errors of less than 2.6 percent while surpassing the accuracy of several other analytical modeling techniques by an order of magnitude. Furthermore, the wide-band circuit generation technique captures the frequency-dependent resistance of the inductor with typical errors of less than 3.2 percent.     

Parasitic-aware analytical modeling of integrated CMOS inductively degenerated narrow-band low noise amplifiers

In this paper, we present an analytical modeling methodology for fully integrated inductively-degenerated CMOS narrow-band cascode Low Noise Amplifiers (LNA) that captures short channel transistor effects to enable rapid design space exploration in current and future process technologies. The modeling methodology captures the impact of parasitics on passive components, ESD-protection structures, and devices to accurately predict both impedance matching and noise figure. Our modeling is suitable for numerical optimization and fully automated synthesis for LNAs. The results indicate that the methodology models ESD-protected LNA circuits with 47.9% better accuracy in noise figure when compared with several current analytical modeling techniques with four orders of magnitude improvement in simulation time over circuit-level simulation. Given its speed and accuracy, the analytical modeling methodology is well-suited for design space exploration.