Structural,magnetic and magnetostrictive properties of Co1-xLixFe2O4 synthesized by cathode materials of spent Li-ion batteries

In this study, we investigated the effects of substituting Li⁺ for Co²⁺ at the B sites of the spinel lattice on the structural, magnetic and magnetostrictive properties of cobalt ferrites. The Li⁺ substituted cobalt ferrites, Co_1-xLi_xFe₂O₄, with x varying from 0 to 0.7 in 0.1 increments, were synthesized with a sol-gel auto-combustion method using the cathode materials of spent Li-ion batteries. X-ray diffraction analysis revealed that all the Co_1-xLi_xFe₂O₄ nanopowders had a single-phase spinel structure and the lattice parameters decreased with increasing Li⁺ content, which can be proved by slight shifts towards higher diffraction angle values of the (311) peak. Field emission scanning electron microscopy was used to observe the fractured inner surface of the sintered cylindrical rods and the increased porosity resulted in a decreased magnetostriction. The oxidation states of Co and Fe in the cobalt ferrite samples were examined by X-ray photoelectron spectroscopy. High resolution transmission electron microscopy micrographs showed that most particles were roughly spherical and with sizes of 25–35?nm. Li⁺ substitution had a strong effect on the saturation magnetization and coercivity, which were characterized with a vibrating sample magnetometer. The Curie temperature was reduced due to the decrease in magnetic cations and the weakening of the exchange interactions. The magnetostrictive properties were influenced by the incorporation of Li⁺ at the B sites of the spinel structure and correlated with the changes in porosity, magnetocrystalline anisotropy and the cation distribution.     

Investigation on milling force of thin-walled workpiece considering dynamic characteristics of workpiece

Journal of Mechanical Science and Technology - The idea of integral calculus is used in traditional milling force prediction methods. In the traditional method, the milling cutter is divided into...     

CMAS对热障涂层界面裂纹和残余应力的影响

随着航空发动机涡轮叶片工作温度的提升,使得一种主要由CaO,MgO,Al₂O₃和SiO₂组成的玻璃态物质(CMAS)对热障涂层的危害越来越严重,从而对热障涂层的性能和耐久性有了更高的要求。本文以电子束物理气相沉积热障涂层为研究对象,利用有限元方法研究了CMAS的渗入对界面裂纹扩展及CMAS对陶瓷层(TC)内部残余应力的影响规律。采用波长固定、振幅变化的正弦曲线表示不同粗糙度的涂层界面,同时考虑了CMAS的弹性模量变化的影响及不同界面形貌与CMAS之间的相互作用。结果表明：CMAS弹性模量的增加对界面裂纹具有抑制作用,并且TGO幅值和厚度越小,抑制作用越明显。CMAS弹性模量对TC层最大残余应力S₂₂的影响存在临界点,在临界点之前,CMAS弹性模量的变化对TC层最大残余应力的影响较大,随着CMAS弹性模量的增加,TC层最大残余应力大幅度减小；在临界点之后,TC层最大残余应力基本不受CMAS弹性模量变化的影响。这些结果对电子束物理气相沉积喷涂的热障涂层失效机理的研究具有重要意义,可以为热障涂层界面的优化提供指导。     

磺酸磁性石墨烯固体酸的制备、表征及初步应用研究

以氧化石墨烯,Co（NO3）2·6H2O和Fe（NO3）3·9H2O为离子源利用水热法一步制备磁性石墨烯（Co Fe2O4-h GO）,用磺酸重氮盐将其重氮化制得磺酸磁性石墨烯固体酸,采用FT-IR、XRD、VSM和酸碱反滴定法测对其进行了表征。结果表明,链接石墨烯的Co Fe2O4为单相立方尖晶石结构,平均粒径为27 nm,饱和比磁化强度MS为29.7 A·m2/kg,其表面酸量为2.7 mmol/g。用乙酸与正己醇的酯化反应初步评估其催化性能：在90℃,乙酸与正丁醇摩尔比为1∶1,催化剂用量为3wt%,反应时间为4 h的条件下,乙酸转化率为59.1%。     

丙烯压缩机透平结垢原因分析及在线清洗技术

神宁煤化工烯烃装置丙烯压缩机在运行过程中,由于水质原因造成透平结垢,出现了透平调速阀逐渐开大,效率下降,蒸汽耗量增加等现象。本文科学分析了透平结垢的原因及危害,提出以无负荷湿蒸汽冲洗法对透平进行冲洗的清洁技术,并在运行过程中成功实践,有效地确保压缩机组高效、安全、稳定运行。     

液体辅助激光微孔加工研究进展

随着微孔加工技术的逐渐成熟,激光微孔加工的应用越来越广泛,但依靠单一激光束进行微孔加工仍存在一些问题,尤其是在深孔加工方面,出现了以激光束为主、多能量场辅助的复合打孔技术,并逐渐成为了热点。针对液体辅助激光微孔加工研究领域,总结了水基辅助激光打孔、水基超声振动辅助激光打孔、水基超声?磁场辅助激光打孔和电解液/水射流辅助激光打孔等方法。在水基的基础上,加入了超声、磁场和温度场,使得辅助场变得多元化,在多层面上进行复合加工。介绍了不同辅助加工方法的去除材料机理及加工后材料特性的变化,水起到冷却的作用,但在水层下会形成空化气泡,超声振动可以击溃气泡,磁场和温度场为材料残渣提供了能量,具体表现在热效应、材料去除速率、打孔深度、重铸层及裂纹等方面。影响微孔质量的因素有微孔锥度、深径比、孔的圆度、重铸层厚度、热影响区、微裂纹和粗糙度等,主要对微孔锥度、深径比及其他指标进行了分析,总结了加工方法对微孔质量的影响。     

海上倾斜PHC管桩内钻孔嵌岩工程实践

该文结合海油工程珠海深水海洋工程装备制造基地PHC管桩嵌岩施工实践,针对平台承载状况、桩靴入岩性状,采用回转全断面嵌岩工艺,对于管靴变形及管内孤石问题,制定多种非常规措施,取得了良好效果,其施工工艺和施工方法具有一定的借鉴意义。     

含多直流环节的混合结构有源配电网潮流计算方法

分布式发电和先进电力电子技术在配电层面的广泛应用将使得系统中出现大量的直流环节,极大地改变传统配电网的网架结构和运行方式,对智能电网环境下配电网的快速仿真与模拟提出更高的要求。潮流计算作为快速仿真与模拟最基本也是最关键的分析计算功能必须能够适应这种变化。为此,研究了含多种直流环节的配电网中关键设备的建模方法,提出了考虑不同控制方式的换流器稳态模型,将分布式电源分为可控性和不可控性两大类,并给出了相应的处理方法;提出了基于Zbus高斯算法的配电网混合潮流求解方法,并利用换流器实现各个交直流子系统之间的潮流信息互动;最后,基于IEEE 123节点算例设计了一个典型的配电网算例,对所提出的潮流计算方法进行了测试和验证。     

磷石膏两步法制备硫酸钾工艺研究

对以磷石膏、(NH4)2CO3、KCl为原料的两步法制备K2SO4的工艺进行了研究。实验讨论了第二步反应中(NH4)2SO4与KCl物质的量比(物料配比)、(NH4)2SO4溶液初始质量分数、反应温度、反应时间、有机溶剂种类及用量等工艺参数对原料转化率和产品质量的影响,得到适宜工艺条件,反应时间1.5h,反应温度50℃,物料配比[n(NH4)2SO4∶nKCl]为1.05∶2,(NH4)2SO4初始质量分数40%,有机溶剂质量分数为40%,该条件下使K+转化率达到80%以上,产品K2O质量分数达50.89%,K2SO4质量达GB20406-2006国家农用K2SO4一等品的标准。     

Comparative In Vitro Osteoinductivity Study of HA and α‐TCP/HA Bicalcium Phosphate

A bicalcium phosphate (BCP) bioceramic comprising α‐tricalcium phosphate (α‐TCP) and hydroxyapatite (HA) was prepared by a two‐step sintering. The microstructure of the BCP bioceramic was investigated using scanning electron microscopy (SEM), transmission electron microscopy (TEM), and X‐ray diffraction. The in vitro osteoinductivity was evaluated by culturing MG63 osteoblast‐like cells on the BCP bioceramic. Results showed that the BCP bioceramic comprising α‐TCP and HA in a moderate ratio possessed a hardness of 93.7 Hv. The cells spread faster on the BCP bioceramic than those on the commercial HA. It suggested that the BCP bioceramic can enhance osteoinductivity in vivo.