Interface-based crystal particle autoselection via membrane crystallization: From scaling to process control

Accurate crystallization control is an essential aspect for chemical engineering and separation processes. Herein, we demonstrated the novelty of membrane crystallization (MCr) on the interfacial based-crystal particle autoselection aimed for nucleation regulation and process control. With the proposed model based on a van der Waals-friction-hydrodynamic force field and classical nucleation theory, the motion mechanisms of heterogeneously induced nucleation were illustrated. The defined particle detachment criterion K revealed the control mechanism of the crystal particle motion behavior: temporary adherence, detachment, and perpetual adherence (scaling) at the membrane interface. For the first time, the function region of MCr (nucleation detection, scaling control, and crystallization regulation) was systematically illustrated and validated with the directly observed laboratory demonstration. These findings also demonstrate the potential applications of the uniform size distribution, morphology modified particle manufacture, and in situ nucleation detection. © 2018 American Institute of Chemical Engineers AIChE J, 65: 723–733, 2019     

Mesoporous Co–Mn Spinel Oxides as Efficient Catalysts for Low Temperature Propane Oxidation

Catalysis Letters - A series of mesoporous cobalt–manganese catalysts were successfully synthesized by sol–gel method as efficient catalysts for the propane oxidation. A significant...     

SAE8640合金钢280mm x325mm连铸坯的高温力学性能

采用Gleeble 1500热模拟试验机对SAE8640钢280mm×325mm连铸坯（/% : 0.41C，0.20Si，0.80Mn，0.005S，0.014P，0.46Cr，0.43Ni，0.21Mo，0.043Alt，0.0011O，0.0054N）的550~1200℃力学性能进行了测定,并应用扫描电镜观察了拉力试样的断口形貌。结果表明,SAE8640钢有明显的3个脆性区:Ⅰ脆性区＞1200℃,Ⅱ脆性区950~1000℃,Ⅲ脆性区650~750℃;该钢950~1000℃的断面收缩率为60%,拉伸断口为脆性河流状花样,应避免在该温度范围进行轧制,该钢650~750℃的断面收缩率≥65%,拉伸断口为韧性断裂,可满足连铸坯矫直时塑性的要求。     

基于光纤技术的采空区发火监测系统的应用

基于光纤技术的采空区发火监测系统由传感器、数据传输、数据分析与控制三大部分构成,研发新一代适合煤矿安全领域应用的先进传感器、并以此为基础构建新型煤矿安全灾害监测预警系统,对于实现煤矿安全发展具有十分重要的意义。     

精轧和吐丝温度对SCM435线材氧化铁皮物相结构的影响

线材的氧化铁皮起着保护线材免锈蚀的作用,但是也需要在酸洗时容易除去。影响铁皮除去或结合力的主要是铁皮的厚度和其物相结构。通过对不同轧制条件下的氧化铁皮厚度、物相结构进行检测分析,研究了精轧温度和吐丝温度对φ12 mm SCM435氧化铁皮物相结构的影响。研究表明,随着精轧温度或吐丝温度的升高,SCM435线材的氧化铁皮厚度均会增加,且在800-900℃短时间就会生成较厚(约20μm)的氧化铁皮;由于Cr的氧化选择性,精轧温度在870℃以上,吐丝温度在810℃以上时,随精轧温度或吐丝温度升高,氧化铁皮中FeO比例提高;但是吐丝温度高于860℃后,物相结构的变化趋缓,FeO的比例变化不大。     

Bamboo biochar-catalytic degradation of lignin under microwave heating

Abstract

Lignin biochar-catalytic depolymerization using biochar Fe-600, Fe-800, Ni-600, Ni-800 catalysts under microwave-heating (180?°C for 30?min) was explored in an ethanol/formic acid (1:1) media. Non-catalyst depolymerization was also studied and compared with the biochar-catalysts results. Characteristics of the bio-char catalysts were analyze by BET, XRD, and FT-IR. GPC, FT-IR, and MALDI-TOF MS spectrometry were also used to characterize the depolymerization products. The experimental results showed that the S_BET, V_t, and V_mec and average pore diameter of the biochars are considerably dependent on the preparation temperature and type of cation (Ni²⁺ or Fe³⁺). The maximum yield of bio-oil product was obtained as 85?wt% with the addition of biochar Ni-600 and the total amount of oligomers or monomers with a molecular weight of 164 to 446 reaches 80.4%.