全文获取类型
收费全文 | 580篇 |
免费 | 0篇 |
国内免费 | 11篇 |
专业分类
电工技术 | 16篇 |
综合类 | 4篇 |
化学工业 | 38篇 |
金属工艺 | 133篇 |
机械仪表 | 24篇 |
建筑科学 | 1篇 |
能源动力 | 21篇 |
石油天然气 | 1篇 |
武器工业 | 1篇 |
无线电 | 21篇 |
一般工业技术 | 302篇 |
冶金工业 | 15篇 |
原子能技术 | 2篇 |
自动化技术 | 12篇 |
出版年
2022年 | 3篇 |
2021年 | 7篇 |
2020年 | 10篇 |
2019年 | 3篇 |
2018年 | 7篇 |
2017年 | 11篇 |
2016年 | 9篇 |
2015年 | 2篇 |
2014年 | 42篇 |
2013年 | 66篇 |
2012年 | 28篇 |
2011年 | 41篇 |
2010年 | 27篇 |
2009年 | 30篇 |
2008年 | 33篇 |
2007年 | 33篇 |
2006年 | 23篇 |
2005年 | 14篇 |
2004年 | 22篇 |
2003年 | 30篇 |
2002年 | 22篇 |
2001年 | 11篇 |
2000年 | 13篇 |
1999年 | 18篇 |
1998年 | 11篇 |
1997年 | 9篇 |
1996年 | 8篇 |
1995年 | 29篇 |
1994年 | 7篇 |
1993年 | 9篇 |
1992年 | 2篇 |
1991年 | 1篇 |
1990年 | 1篇 |
1989年 | 3篇 |
1988年 | 1篇 |
1986年 | 1篇 |
1985年 | 1篇 |
1982年 | 1篇 |
1980年 | 1篇 |
1979年 | 1篇 |
排序方式: 共有591条查询结果,搜索用时 31 毫秒
1.
Ziqian Wang Yalan Chen Yating He Weidong Jiang Yan Long Guangyin Fan 《International Journal of Hydrogen Energy》2021,46(21):11587-11596
Developing high-efficiency and low-cost catalysts for hydrogen evolution from hydrolysis of ammonia borane (AB) is significant and critical for the exploitation and utilization of hydrogen energy. Herein, the in-situ fabrication of well-dispersed and small bimetallic RuNi alloy nanoparticles (NPs) with tuned compositions and concomitant hydrolysis of AB are successfully achieved by using graphitic carbon nitride (g-C3N4) as a NP support without additional stabilizing ligands. The optimized Ru1Ni7.5/g-C3N4 catalyst exhibits an excellent catalytic activity with a high turnover frequency of 901 min?1 and an activation energy of 28.46 kJ mol?1 without any base additives, overtaking the activities of many previously reported catalysts for AB hydrolysis. The kinetic studies indicate that the AB hydrolysis over Ru1Ni7.5/g-C3N4 is first-order and zero-order reactions with respect to the catalyst and AB concentrations, respectively. Ru1Ni7.5/g-C3N4 has a good recyclability with 46% of the initial catalytic activity retained even after five runs. The high performance of Ru1Ni7.5/g-C3N4 should be assigned to the small-sized alloy NPs with abundant accessible active sites and the synergistic effect between the composition-tuned Ru–Ni bimetals. This work highlights a potentially powerful and simple strategy for preparing highly active bimetallic alloy catalysts for AB hydrolysis to generate hydrogen. 相似文献
2.
The changes in surface composition of metallic alloys caused by segregation can be very efficiently studied by low-energy ion scattering (LEIS) due to the specific surface sensitivity of this technique. Investigations of single-crystal surfaces of ordered alloys are of particular interest because they provide the possibility to investigate the interplay between segregation effects and the order-disorder phase transition when passing through the transition temperature. Exemplifying these effects for bimetallic alloys we consider in particular the CuAu-system.For the quantitative interpretation of energy and angle resolved LEIS intensity distributions we compare experimental results with those from numerical simulations using the MARLOWE code which we extended with a detailed trajectory analysis. This allows us to apply various discrimination criteria, such as number of collisions, distance of closest approach, identification of the scattering crystal layer, total path length, etc. On this basis structural effects, ion survival probabilities and the influence of thermal vibrations can be studied.We demonstrate this potential by using CuAu(1 0 0) as a special example. The scattering potential parameters were calibrated with elemental single crystals of known structures and the anisotropic Debye temperatures taken from the literature showed good agreement, neutralization was of minor importance in this case. Our procedure could be successfully used for the quantitative analysis of the composition of the first and second layer as a function of temperature. These results are in good agreement with theoretical predictions. 相似文献
3.
4.
5.
This paper addresses the aging behaviour of NiCr/CuNiMn/NiCr triple layers on Al2O3 ceramics at temperatures up to 200°C for film thicknesses d0.5 μm. Investigations of the film structure and the increase of resistance and its temperature coefficient during the annealing process and studies of the dependence of this aging drift on both the film thickness and the storage temperature have been carried out. Furthermore, the film stress and the effect of substrate bending on resistance have been measured. The results can be explained by the irregular film structure (columns and small bridges between them), which causes stress and current concentrations as well as local creeping, cracking and oxidation processes in the micro-bridges. They are compared with such for structurally homogeneous films on silicon wafers. 相似文献
6.
7.
8.
曹颜顺 《有色金属材料与工程》1993,(1)
控制Si相的析出状态,会对Al-Si(1wt%)合金的性能产生不同的影响。本文阐述通过不同的热处理工艺改变了Al-Si(1wt%)合金的机械、物理性能,获得了高形变强化率、高塑性变形能力、高拉伸强度的工艺,还讨论了具有上述高拉伸强度的微细丝在半导体器件应用中所具有的优越性。 相似文献
9.
介绍一种用于铝合金的连续熔化-去气的节能装置。着重讨论了此装置的结构和操作要点以及影响铝合金质量的因素。文中对比了此装置与传统阶段式熔化系统操作上的异同点。分析了连续熔化炉的经济效益。研究表明毛坯耗电量下降85%,并可减少合金元素加入量以及坩埚和加热元件的消耗。铸件质量合格。 相似文献
10.
介绍第二届环太平洋先进材料及工艺国际会议情况,重点报导韩国钢铁工业、早期凝固过程研究、喷射成形、非晶合金、纳米材料和第三代单晶铸造高温合金等内容。 相似文献