Effect of sintering temperature on lightweight aggregates manufacturing from copper contaminated soil

Manufacturing lightweight aggregate (LWA) at high temperature is an effective way to immobilize heavy metals in solid waste. This work investigated the performance and solidification mechanism of LWA prepared from copper contaminated soil. The volume expansion of LWA could reach a maximum of 28%, and its lowest density accounted of 1.5 g/cm³, which met the standard requirements. Optical microscope and micro-CT test illustrated that the addition of Cu leaded to obvious phase separation in LWA. The Cu leaching result of LWA first increased and then dropped with the temperature. The XRD test found that the main formation phase of Cu in LWA were t-CuFe₂O₄ and amorphous phase that they had different acid resistance ability. XPS revealed that the main cause of the agglomeration of liquid phase in LWA was the chain broken reaction between Cu and Si–O tetrahedron. SEM-EDS results showed that the distribution of Cu and Si had a strong correlation, which meant that Cu mostly formed amorphous phase. This work showed the uniqueness of Cu in the high temperature immobilization and pointed out the best immobilization target phase.     

Preparation of high strength foam ceramics from sand shale and steel slag

Foam ceramics with high strength were successfully fabricated by using sand shale and steel slag as the major materials and SiC as foam agent. The influence of raw materials ratio and heat treatment temperatures on crystalline phases, porosity, mechanical properties and pore structures was investigated via XRF, XRD, SEM, DTA-TG, Micro-CT. The results indicate that the raw materials composed of 94 wt% sand shale and 6 wt% steel slag enable the fabrication of foam ceramics possessing strength of 29.98 MPa, bulk density of 0.821 g/cm³, total porosity of 67.22%, closed porosity of 55.27% and thermal conductivity of 0.08 W/(m·K). Micro-CT result shows that the pores with an average size of 267.05 μm are isolated. Pore wall thickness conforms to normal distribution, and it ranges from 18 to 42 μm. The superior property makes it promising high-strength and lightweight material in application fields, including thermal insulation materials and lightweight building materials.     

不同级配对微表处混和料性能的影响

微表处技术是一种性能优良的路面养护技术。首先检验了微表处用原材料的技术指标,在满足规范的要求下选择了三种不同级配,并对三种不同级配的微表处混和料的使用性能进行了比较。     

A simple mathematical analysis on the effect of sand in Cr(VI) reduction using zero valent iron

A simple mathematical model was proposed to analyze the enhancement of Cr(VI) reduction when sand materials are added to the zero valent iron (ZVI). Natural decay of Cr(VI) in a control experiment was analyzed by using a zero-order decay reaction. Adsorption kinetics of Cr(VI) to sand was modeled as a first-order reversible process, and the reduction rate by ZVI was treated as a first-order reaction. Natural decay of Cr(VI) was also included in other experiments, i.e., the adsorption to sand, the reduction by ZVI, and both adsorption and reduction when sand and ZVI are present together. The model parameters were estimated by fitting the solution of each model to the corresponding experimental data. To observe the effect of sand addition to ZVI, both adsorption and reduction rate models were considered simultaneously including the natural decay. The solution of the combined model was fitted to the experimental data to determine the first-order adsorption and reduction rate constants when sand as well as ZVI is present. The first-order reduction rate constant in the presence of sand was about 35 times higher than that with ZVI only.     

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白马庙气田蓬莱镇气藏储层致密 ,孔隙结构复杂 ,非均质性强 ,单井产能低 ,研究储层特征和受控因素 ,加强储层改造方是气藏效益开发的出路。储层精细研究揭示 ,气井产能受沉积相和构造条件控制 ;高、中产井与大而厚、物性好的河口坝、河道砂坝沉积微相有关 ,纵向上具很强的层段性 ,主产层集中在Ⅳ～③、Ⅲ～③两套砂组 ,其钻探成功率分别达 82 %和 10 0 % ;平面上多分布于主体构造和东南鼻状突起 ,二者高、中产能井分别占 30 %和 70 %。在深入的地质研究和储层压裂评层选井的基础上 ,采用多层打开、分层压裂、多层合采的方法可提高气井产能 ,并形成了一套行之有效的压裂评层选井的综合配套技术。采用该技术优选出 19口井 ,已实施 5口井全获成功 ,气产量成倍或十几倍增加 ,其中白浅 4 5井气无阻流量高达 18× 10 4m3 /d ,白浅 38井投产 16 5d净增产值 10 0余万元     

Critical Shear Stress of Bimodal Sediment in Sand-Gravel Rivers

A new model for the critical shear stress and the transport of graded sediment is presented. The model is based on the size distribution of the bed surface and can be used to compute sediment transport rates in numerical simulations with an active layer model. This model makes a distinction between unimodal and bimodal sediments. It is assumed that all size fractions of unimodal sediments have the same critical shear stress while there is selective transport for the gravel fractions of bimodal sediments. A recently published laboratory transport data set is used to calibrate our model.     

The Application of Ozone for Water Treatment In The United Kingdom — Current Practive and Recent Research

Only two water works in the UK apply ozone at present as part of their treatment, onefor taste and odor control and theother forcolor removal. Forthetwo applicationus ozone was the most economical option at thetime theplants were installed andozone has been successful for the purpose for which it was designed.     

Effect of Compressive Load on Uplift Capacity of Model Piles

Thirty six tests on model tubular steel piles embedded in sand were carried out in the laboratory to assess the effects of compressive load on uplift capacity of piles considering various parameters. The model piles were of 25 mm outside diameter and 2 mm wall thickness. The soil–pile friction angles were 21 and 29° in loose and dense conditions of sand. The piles were embedded in sand for embedment length/diameter ratios of 8,16, and 24 inside a model tank. They were subjected to a static compressive load of 0, 25, 50, 75, and 100% of their ultimate capacity in compression and subjected to pull out loading tests. The experimental results indicated that the presence of the compressive load on the pile decreases the net uplift capacity of a pile and the decrease depends on the magnitude of the compressive load. A logical approach, based on the experimental results, has been suggested to predict the net uplift capacity of a pile considering the presence of compressive load.     

高密度钻井液随钻堵漏技术研究

地层和油气层分布的特点，使塔里木盆地易发生高密度条件下的井漏。多种堵漏处理措施，如降排量、降密度、静止堵漏、随钻堵漏、桥接堵漏、注水泥堵漏等都没有很好地解决这类漏失问题。根据井漏及堵漏情况，开发出了高密度条件下使用的随钻封堵护壁剂。该堵漏剂主要以改性纤维作为骨架材料，改性沥青和天然有机高分子作为填充材料，以弱交联聚合物为变形填充材料，并辅以有机硅为粘结护壁材料，是一种具有物理化学堵漏功能的新型随钻堵漏剂。经流变性、砂床滤失性、润滑性、油层保护性等性能评价，表明该处理剂加入后，对钻井液流变性影响小、可辅助降低API滤失量和润滑系教、能碴著降低砂床滤失鼍。同时还具有一定的保护油气层的功能。     

Evaluating Liquefaction Strength of Partially Saturated Sand

A method is presented for evaluating the liquefaction strength of partially saturated sand using the compression wave velocity (P-wave velocity), a new indicator of saturation. Based on laboratory test results, an empirical correlation that relates the liquefaction strength with the pore pressure coefficient B is firstly proposed. The strength is defined as the cyclic stress ratio required to cause liquefaction at a specified number of cycles. With the aid of a theoretical relation between B and the P-wave velocity, an explicit correlation of more interest is then established between the liquefaction strength of sand and its P-wave velocity. A comparison of the predictions using this explicit correlation with laboratory measurements shows a satisfactory agreement. The significance of this method lies in that it makes it possible to evaluate the liquefaction strength of sand as affected by saturation through the measurement of P-wave velocity, which can be made not only in the laboratory but particularly in the field.