全文获取类型
收费全文 | 359篇 |
免费 | 2篇 |
国内免费 | 1篇 |
专业分类
电工技术 | 1篇 |
综合类 | 5篇 |
化学工业 | 101篇 |
金属工艺 | 7篇 |
能源动力 | 225篇 |
轻工业 | 1篇 |
石油天然气 | 8篇 |
一般工业技术 | 6篇 |
冶金工业 | 6篇 |
原子能技术 | 1篇 |
自动化技术 | 1篇 |
出版年
2023年 | 11篇 |
2022年 | 20篇 |
2021年 | 22篇 |
2020年 | 28篇 |
2019年 | 20篇 |
2018年 | 20篇 |
2017年 | 14篇 |
2016年 | 3篇 |
2015年 | 1篇 |
2014年 | 27篇 |
2013年 | 28篇 |
2012年 | 21篇 |
2011年 | 24篇 |
2010年 | 12篇 |
2009年 | 20篇 |
2008年 | 13篇 |
2007年 | 15篇 |
2006年 | 8篇 |
2005年 | 6篇 |
2004年 | 2篇 |
2003年 | 8篇 |
2002年 | 3篇 |
2001年 | 4篇 |
2000年 | 4篇 |
1999年 | 3篇 |
1998年 | 6篇 |
1997年 | 5篇 |
1996年 | 3篇 |
1995年 | 2篇 |
1994年 | 4篇 |
1993年 | 3篇 |
1992年 | 1篇 |
1985年 | 1篇 |
排序方式: 共有362条查询结果,搜索用时 213 毫秒
1.
C. Athanassiou G. Pekridis N. Kaklidis K. Kalimeri S. Vartzoka G. Marnellos 《International Journal of Hydrogen Energy》2007
In the present work, the prospects and trends of solid electrolyte membrane reactors (SEMRs) towards hydrogen production, are discussed. Initially, an overview of the principles, the properties and the techniques related to the usage of the SEMRs, are presented. In the following, a literature survey covering earlier and recent developments of the various methods (e.g. reforming or partial oxidation or dehydrogenation of hydrocarbons, steam electrolysis) employed in the SEMRs for the production of hydrogen, is performed. Finally, the current status of this research field is analyzed and future research topics are proposed. 相似文献
2.
Min-Seok Park Vladislav P. Vislovskiy Jong-San Chang Yong-Gun Shul Jin S. Yoo Sang-Eon Park 《Catalysis Today》2003,87(1-4):205-212
Alumina-supported vanadium oxide, VOx/Al2O3, and binary vanadium–antimony oxides, VSbOx/Al2O3, have been tested in the ethylbenzene dehydrogenation with carbon dioxide and characterized by SBET, X-ray diffraction, X-ray photoelectron spectroscopy, hydrogen temperature-programmed reduction and CO2 pulse methods. VSbOx/Al2O3 exhibited enhanced catalytic activity and especially on-stream stability compared to VOx/Al2O3 catalyst. Incorporation of antimony into VOx/Al2O3 increased dispersion of active VOx species, enhanced redox properties of the systems and formed a new mixed vanadium–antimony oxide phase in the most catalytically efficient V0.43Sb0.57Ox/Al2O3 system. 相似文献
3.
4.
新型多效能复合式橡胶防老剂FNPPD的制备 总被引:1,自引:0,他引:1
介绍了一种新型多效复合式橡胶防老剂FNPPD及其制备。其中包括该剂主要成分668防老剂(N-苯基N′-另辛基对苯二胺)的加氢法合成;合成668的原料之一2-辛酮的制备方法,以及668与酮胺类化合物复合为FNPPD防老剂的工艺过程。生产FNPPD具有可观的经济效益和市场前景。 相似文献
5.
The continuous production of hydrogen from cyclohexanes is achieved effectively using Pt/ACF (ACF = activated carbon fiber) catalysts in a fixed-bed flow reactor. The Pt catalysts are more effective than a Pd/ACF catalyst for the reaction. Besides cyclohexane, methylcyclohexane, 1,4-dimethylcyclohexane, and p-menthane can also be employed as hydrogen source in the reaction system. 相似文献
6.
乙苯脱氢氧化制苯乙烯工艺过程分析 总被引:2,自引:0,他引:2
对乙苯脱氢氧化工艺过程进行了热力学分析,表明氧化烧氢具有提高平衡转化率和能量合理利用的优点。通过一维拟均相模型模拟计算,比较了乙苯脱氢与乙苯脱氢氧化的反应效果,并由实验得到了验证。同时还讨论了乙苯实验转化率提高不多的原因。 相似文献
7.
1 前言在化学化工领域中利用膜材料的选择性渗透和催化作用来改善反应性能正越来越受到人们的重视。与传统的颗粒状催化剂-固定床反应器体系相比较,膜催化反应器在质量传递、热量传递和活化反应物方面有较大的差异。例如,用传统的固定床反应器由于受热力 相似文献
8.
Linsheng Wang Longxiang Tao Maosong Xie Guifen Xu Jiasheng Huang Yide Xu 《Catalysis Letters》1993,21(1-2):35-41
The dehydrogenation and aromatization of methane on modified ZSM-5 zeolite catalysts has been studied under non-oxidizing conditions with a fixed bed continuous-flow reactor and with a temperature programmed reactor. The results show that benzene is the only hydrocarbon product of the catalytic conversion of methane at high temperature (973 K). The catalytic activity of ZSM-5 is greatly improved by incorporating a metal cation (Mo or Zn). H2 and ethene have been directly detected in the products with a mass spectrometer during TPAR. A carbenium ion mechanism for the activation of methane is suggested. 相似文献
9.
Shrikrishina D. Sartale Huang-Wei Shiu Wen-Hua Wen Meng-Fan Luo Y. C. Lin Yao-Jane Hsu 《Catalysis Letters》2007,119(1-2):95-100
Using a scanning-tunneling microscope, reflection high-energy electron diffraction and photoelectron spectra with synchrotron
radiation, we investigated the temperature dependence of the dehydrogenation of cyclohexene (C6H10) adsorbed on Pt nanoclusters supported on an ultra-thin film of Al2O3/NiAl(100). The Pt clusters, grown by vapor deposition, are structurally ordered and exhibit a mean diameter 2.2 nm and height
0.4 nm. The progress of dehydrogenation was monitored through the temporal variation of C 1s photoelectron spectra; analysis
of these features revealed that the dehydrogenation of cyclohexene with increasing sample temperature occurs as a sequential
process beginning around 150 K, a temperature significantly less than that for Pt single-crystal surfaces. The dehydrogenation
behavior, particularly the decomposition into elemental carbon, is found to vary with Pt coverage. 相似文献
10.
Jung-Il?Yang Jong-Nam?KimEmail author Soon-Haeng?Cho K.?R.?Krishnamurthy 《Korean Journal of Chemical Engineering》2004,21(2):381-384
LiCl/YSZ is found to be a very effective catalyst for the oxidative dehydrogenation of ethane. LiCl supported on YSZ-MgO composite
shows increase in catalytic activity and ethylene selectivity. Addition of Mn and Sn as promoters to this system leads to
85% ethane conversion, 77% ethylene selectivity and 65% ethylene yield at 662 °C. Use of Li2O in the place of LiCl results in lower ethylene yields. Further modification is needed to improve the catalyst stability. 相似文献